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Publication Date:
October 2010
ISSN:
2191-0316
DOI:
10.1515/corrrev.2008.51

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Editor-in-Chief: Latanision, Ronald M. / Eliaz, Noam

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Catalytic Aspects of Oxygen Reduction in Metal Corrosion

S. Szabó1 / I. Bakos1

1Institute of Materials and Environmental Chemistry, Chemical Research Center, Hungarian Academy of Sciences, H-1525 Budapest, P.O. Box 17 (Hungary)

c1Corresponding author: e-mail: , Fax: 36/1 325 77 50

Citation Information: Corrosion Reviews. Volume 26, Issue 1, Pages 51–71, ISSN (Online) 2191-0316, ISSN (Print) 0334-6005, DOI: 10.1515/corrrev.2008.51, October 2010

Publication History:
Published Online:
2010-10-22

ABSTRACT

The most important cathodic process of metal corrosion is oxygen reduction. This process, however, is a complicated multistep catalytic process. A well known catalytic oxygen activator is the acidic Fe3+/Fe2+ redox system. In the case of rusting iron the Fe2+ ion containing lepidocrocite is the catalytic activator of oxygen. There are many metal complexes capable of oxygen activation. They can help increasing metal corrosion rate.

Keywords:: Oxygen; catalytic; activation; lepidocrocite; metal complexes

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