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Publication Date:
June 2005
ISSN:
1437-434X
DOI:
10.1515/HF.2000.025

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Holzforschung

International Journal of the Biology, Chemistry, Physics, and Technology of Wood

Editor-in-Chief: Faix, Oskar

Editorial Board Member: Daniel, Geoffrey / Militz, Holger / Rosenau, Thomas / Salmen, Lennart / Sixta, Herbert / Vuorinen, Tapani / Argyropoulos, Dimitris S. / Balakshin, Yu / Barnett, J. R. / Berry, Richard / Burgert, Ingo / Evans, Robert / Evtuguin, Dmitry V. / Frazier, Charles E. / Fukushima, Kazuhiko / Gellerstedt, Göran / Gindl-Altmutter, Wolfgang / Glasser, W. G. / Heitner, Cyril / Holmbom, Bjarne / Isogai, Akira / Kadla, John F. / Kleen, Marjatta / Koch, Gerald / Lachenal, Dominique / Mansfield, Shawn D. / Morrell, J.J. / Niemz, Peter / Pizzi, Antonio / Ragauskas, Arthur J. / Ralph, John / Rice, Robert W. / Salin, Jarl-Gunnar / Schmitt, Uwe / Schultz, Tor P. / Schwanninger, Manfred / Sipilä, Jussi / Tamminen, Tarja / Viikari, Liisa / Welling, Johannes / Willför, Stefan / Yoshihara, Hiroshi

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Increased IMPACT FACTOR 2011: 1.748
5-year IMPACT FACTOR: 1.838
Rank 2 out of 21 in category Materials Science, Paper & Wood and 10 out of 59 in category Forestry in the 2011 Thomson Reuters Journal Citation Report/Science Edition.

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A Comparative Study on Reactions of Hydrogen Peroxide and Peracetic Acid with Lignin Chromophores. Part 1. The Reaction of Coniferaldehyde Model Compounds

George X. Pan / Liam Spencer / Gordon J. Leary

Citation Information: Holzforschung. Volume 54, Issue 2, Pages 144–152, ISSN (Print) 0018-3830, DOI: 10.1515/HF.2000.025, June 2005

Publication History:
Published Online:
2005-06-01

Summary

The reactions of chromophoric model compounds of the coniferaldehyde type with hydrogen peroxide and peracetic acid have been investigated in relation to lignin-retaining bleaching. Analysis of the main reaction products indicated that the side chain of coniferaldehyde could cleave either between the α, β double bond or between the β, γ bond. Comparison of possible reaction pathways to the formation of oxidation products from hydrogen peroxide and peracetic acid suggested that peracetic acid is more effective than hydrogen peroxide. Advantages of peracetic acid over hydrogen peroxide include a faster rate of reaction, more efficient utilization of the bleaching agent and less likelihood of producing new chromophores.

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