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Publication Date:
August 2008
ISSN:
1437-434X
DOI:
10.1515/HF.2008.110

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Holzforschung

International Journal of the Biology, Chemistry, Physics, and Technology of Wood

Editor-in-Chief: Faix, Oskar

Editorial Board Member: Daniel, Geoffrey / Militz, Holger / Rosenau, Thomas / Salmen, Lennart / Sixta, Herbert / Vuorinen, Tapani / Argyropoulos, Dimitris S. / Balakshin, Yu / Barnett, J. R. / Berry, Richard / Burgert, Ingo / Evans, Robert / Evtuguin, Dmitry V. / Frazier, Charles E. / Fukushima, Kazuhiko / Gellerstedt, Göran / Gindl-Altmutter, Wolfgang / Glasser, W. G. / Heitner, Cyril / Holmbom, Bjarne / Isogai, Akira / Kadla, John F. / Kleen, Marjatta / Koch, Gerald / Lachenal, Dominique / Mansfield, Shawn D. / Morrell, J.J. / Niemz, Peter / Pizzi, Antonio / Ragauskas, Arthur J. / Ralph, John / Rice, Robert W. / Salin, Jarl-Gunnar / Schmitt, Uwe / Schultz, Tor P. / Schwanninger, Manfred / Sipilä, Jussi / Tamminen, Tarja / Viikari, Liisa / Welling, Johannes / Willför, Stefan / Yoshihara, Hiroshi

8 Issues per year

Increased IMPACT FACTOR 2011: 1.748
5-year IMPACT FACTOR: 1.838
Rank 2 out of 21 in category Materials Science, Paper & Wood and 10 out of 59 in category Forestry in the 2011 Thomson Reuters Journal Citation Report/Science Edition.

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Issues

Towards novel wood-based materials: Chemical bonds between lignin-like model molecules and poly(furfuryl alcohol) studied by NMR

Lars Nordstierna1 / Stig Lande2 / Mats Westin3 / Olov Karlsson4 / István Furó5

1Industrial NMR Centre and Division of Physical Chemistry, Department of Chemistry, Royal Institute of Technology, Stockholm, Sweden and SP Technical Research Institute of Sweden, Borås, Sweden

2Kebony ASA, Porsgrunn, Norway

3SP Technical Research Institute of Sweden, Borås, Sweden

4Division of Wood Physics, Luleå University of Technology, Skellefteå, Sweden

5Industrial NMR Centre and Division of Physical Chemistry, Department of Chemistry, Royal Institute of Technology, Stockholm, Sweden

Corresponding author. SP Technical Research Institute of Sweden, Borås, SE-50115 Sweden

Citation Information: Holzforschung. Volume 62, Issue 6, Pages 709–713, ISSN (Online) 1437-434X, ISSN (Print) 0018-3830, DOI: 10.1515/HF.2008.110, August 2008

Publication History:
Received:
2008-03-28
Accepted:
2008-06-23
Published Online:
2008-08-13

Abstract

Wood modification with furfuryl alcohol is a non-toxic alternative to conventional preservation treatments. A process in which furfuryl alcohol polymerises in situ was previously proposed for chemical modification of wood. In the present work, liquid model systems were investigated using compounds that resemble repeating units of lignin to verify whether chemical bonds form between the furfuryl alcohol polymer and wood. Using different NMR spectroscopic techniques we confirmed that these model compounds do form covalent bonds with the polymerising polymer. The results indicate that the furan polymer grafts to lignin, supporting observations in similar studies performed with genuine wood materials.

Keywords: 2D correlation NMR; furfurylation; HMBC; HMQC; lignin; polymerization; preservation; renewable material; wood modification

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