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Publication Date:
November 2009
ISSN:
1437-434X
DOI:
10.1515/HF.2009.126

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Holzforschung

International Journal of the Biology, Chemistry, Physics, and Technology of Wood

Editor-in-Chief: Faix, Oskar

Editorial Board Member: Daniel, Geoffrey / Militz, Holger / Rosenau, Thomas / Salmen, Lennart / Sixta, Herbert / Vuorinen, Tapani / Argyropoulos, Dimitris S. / Balakshin, Yu / Barnett, J. R. / Berry, Richard / Burgert, Ingo / Evans, Robert / Evtuguin, Dmitry V. / Frazier, Charles E. / Fukushima, Kazuhiko / Gellerstedt, Göran / Gindl-Altmutter, Wolfgang / Glasser, W. G. / Heitner, Cyril / Holmbom, Bjarne / Isogai, Akira / Kadla, John F. / Kleen, Marjatta / Koch, Gerald / Lachenal, Dominique / Mansfield, Shawn D. / Morrell, J.J. / Niemz, Peter / Pizzi, Antonio / Ragauskas, Arthur J. / Ralph, John / Rice, Robert W. / Salin, Jarl-Gunnar / Schmitt, Uwe / Schultz, Tor P. / Schwanninger, Manfred / Sipilä, Jussi / Tamminen, Tarja / Viikari, Liisa / Welling, Johannes / Willför, Stefan / Yoshihara, Hiroshi

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Interfacial properties of polyelectrolyte complexes incorporating kraft lignin 10th EWLP, Stockholm, Sweden, August 25–28, 2008

Galia Shulga1 / Vadims Shakels1 / Olga Aniskevicha1 / Julia Zakharova2 / Sanita Skudra1

1Latvian State Institute of Wood Chemistry, Riga, Latvia

2M.V. Lomonosov Moscow State University, Department of High Molecular Compounds, Vorobjovy Gory, Moscow, Russia

Corresponding author. Latvian State Institute of Wood Chemistry, 27 Dzerbenes St., Riga, LV 1006, Latvia

Citation Information: Holzforschung. Volume 63, Issue 6, Pages 711–714, ISSN (Online) 1437-434X, ISSN (Print) 0018-3830, DOI: 10.1515/HF.2009.126, November 2009

Publication History:
Received:
2008-11-30
Accepted:
2009-07-27
Published Online:
2009-11-15

Abstract

Surface tension of kraft lignin (KL) and KL/poly(N,N-dimethylaminoethyl methacrylate) mixtures, with different composition at the air-water interface depending on pH and temperature, was measured. It was found that the surface activity of both KL and the reaction mixtures grows with decreasing pH and increasing temperature. At the same time, the surface activity of the KL/poly(N,N-dimethylaminoethyl methacrylate) reaction mixture, irrespective of its composition under the same environment conditions, considerably exceeds the surface activity of KL, indicating the synergetic effect governed by the peculiarities of the polymeric structure of the formed soluble particles of the polyelectrolyte complex.

Keywords: kraft lignin; polyelectrolyte complex; surface tension; synergetic effect

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