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Publication Date:
November 2007
ISSN:
1542-6580
DOI:
10.2202/1542-6580.1479

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Selecting Robust Kinetic Models on Noisy Data Using the Bootstrap

Cayle J Sharrock1 / Roelof Coetzer2

1University of Cape Town, cayle.sharrock@gmail.com

2Sasol Technology R&D, roelof.coetzer@sasol.com

Citation Information: International Journal of Chemical Reactor Engineering. Volume 5, Issue 1, Pages –, ISSN (Online) 1542-6580, DOI: 10.2202/1542-6580.1479, November 2007

Publication History:
Published Online:
2007-11-19

A systematic approach to identifying a robust kinetic model fitted on noisy data is presented. The bootstrap coupled with Monte-Carlo simulations and exploratory data analysis techniques are employed to evaluate candidate model formulations to given sets of experimental data. The approach is applied in an industrial case study in determining the most practical rate expression for the water-gas shift reaction over a cobalt Fischer-Tropsch catalyst.

Keywords: kinetic modelling; bootstrap; water-gas shift; fischer-tropsch

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