A systematic approach to identifying a robust kinetic model fitted on noisy data is presented. The bootstrap coupled with Monte-Carlo simulations and exploratory data analysis techniques are employed to evaluate candidate model formulations to given sets of experimental data. The approach is applied in an industrial case study in determining the most practical rate expression for the water-gas shift reaction over a cobalt Fischer-Tropsch catalyst.

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Selecting Robust Kinetic Models on Noisy Data Using the Bootstrap
1University of Cape Town, cayle.sharrock@gmail.com
2Sasol Technology R&D, roelof.coetzer@sasol.com
Citation Information: International Journal of Chemical Reactor Engineering. Volume 5, Issue 1, Pages –, ISSN (Online) 1542-6580, DOI: 10.2202/1542-6580.1479, November 2007
Publication History:
- Published Online:
- 2007-11-19
Keywords: kinetic modelling; bootstrap; water-gas shift; fischer-tropsch


















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