In this study, we synthesized and characterized zeolite-encapsulated Fe(III) complexes containing piperazine-derived ligands. The catalytic activity of these complexes was tested in the partial oxidation of methane to methanol using O2 as a low-pressure oxidant. Values for methane conversion of up to 1.2% with methanol selectivity of up to 6.7% were obtained. The experimental data were compared with thermodynamic simulation results for the reaction that takes place as a basic principle, the minimization of Gibbs free energy.
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Theoretical and Empirical Studies on the Catalytic Partial Oxidation of Methane Promoted by FeY and Fe(piperazine)Y Complexes (Y = Y-zeolite)
Marcio Eduardo Berezuk1 / Carla C. R. S. Rossi2 / Nakédia M. F. Carvalho3 / Pedro Augusto Arroyo4 / Cláudio Dariva5 / Adolfo Horn6 / Lúcio Cardozo-Filho6
1Universidade Estadual de Maringá, mberezuk@yahoo.com.br
2Universidade Estadual de Maringá, carlacrs@hotmail.com
3Universidade Federal do Rio de Janeiro, nakedita@yahoo.com.br
4Universidade Estadual de Maringá, arroyo@deq.uem.br
5Universidade Tiradentes, claudio.dariva@yahoo.com.br
6Universidade Estadual do Norte Fluminense, adolfohorn@pq.cnpq.br
7Universidade Estadual de Maringá, cardozo@deq.uem.br
Citation Information: International Journal of Chemical Reactor Engineering. Volume 9, Issue 1, Pages –, ISSN (Online) 1542-6580, DOI: 10.2202/1542-6580.2381, November 2011
Publication History:
- Published Online:
- 2011-11-14
Keywords: methane oxidation; encapsulated Fe(III) complexes; ship-in-a-bottle; Gibbs free energy; iron
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