In this work the epoxidation of methallyl alcohol (MAA) with 30 wt% H2O2 over the Ti-MWW catalyst has been studied. The significant parameters for the MAA epoxidation were established as temperature (20-120°C), the molar ratio of MAA/H2O2 (1:1-5:1), methanol (solvent) concentration (5-90 wt%), Ti-MWW catalyst concentration (0-5.0 wt%), reaction time (5-300 min) and intensity of stirring (0-500 rpm). The process of MAA epoxidation was carried out the most effective at temperature of 100°C, the molar ratio of MAA/H2O2=1:1, methanol concentration of 40 wt%, the catalyst concentration of 2 wt%, the reaction time of 15 min and with the stirring intensity over 350 rpm. These the best technological parameters (mild and relatively safe) allow to obtain the selectivity of transformation to 2MG 37 mol%, the MAA conversion 52 mol%, and the selectivity of transformation to organic compounds in relation to H2O2 consumed 48 mol%.
New Journal at De Gruyter!
Ed. by de Lasa, Hugo / Xu, Charles
1 Issue per year
Increased IMPACT FACTOR 2011: 0.790
Issues
Volume 11 (2013)
Volume 10 (2012)
Volume 9 (2011)
Volume 8 (2010)
Volume 7 (2009)
Volume 6 (2008)
Volume 5 (2007)
Volume 4 (2006)
Volume 3 (2005)
Volume 2 (2004)
Volume 1 (2002)
Most Downloaded Articles
- Micro- and Macromechanics of Hopper Discharge of Ultrafine Cohesive Powder by Tomas, Jürgen and Kache, Guido
- Effect of Chitosan Addition on NiMo/Al2O3 Catalysts for Dibenzothiophene Hydrodesulfurization by Ríos-Caloch, Guillermina/ Santes, Víctor/ Escobar, José/ Valle-Orta, Maiby/ Barrera, María C. and Hernández-Barrera, Melissa
- Fischer Tropsch Synthesis: The Promoter Effects, Operating Conditions, and Reactor Synthesis by Sarkari, Majid/ Fazlollahi, Farhad and Atashi, Hossein
- A Trickle Fixed-Bed Recycle Reactor Model for the Fischer-Tropsch Synthesis by Brunner, Kyle M./ Duncan, Joshua C./ Harrison, Luke D./ Pratt, Kyle E./ Peguin, Robson P. S./ Bartholomew, Calvin H. and Hecker, William C.
- A Comprehensive Review of Just Suspended Speed in Liquid-Solid and Gas-Liquid-Solid Stirred Tank Reactors by Jafari, Rouzbeh/ Chaouki, Jamal and Tanguy, Philippe A.
Clean Synthesis of 2-Methylglycidol over a Novel Titanosilica Catalyst - Ti-MWW under Autogenic Pressure
1West Pomeranian University of Technology, Szczecin, fajdeka@wp.pl
2West Pomeranian University of Technology, Szczecin, agnieszka.wroblewska@zut.edu.pl
3West Pomeranian University of Technology, Szczecin, eugeniusz.milchert@zut.edu.pl
Citation Information: International Journal of Chemical Reactor Engineering. Volume 10, Issue 1, Pages –, ISSN (Online) 1542-6580, DOI: 10.1515/1542-6580.2898, February 2012
Publication History:
- Published Online:
- 2012-02-03
Keywords: Ti-MWW; hydrogen peroxide; 2-methylglycidol; epoxidation
Comments (0)