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Journal of Non-Equilibrium Thermodynamics

Founded by Keller, Jürgen U.

Editor-in-Chief: Hoffmann, Karl Heinz

Managing Editor: Wagner, Katharina

Ed. by Michaelides, Efstathios E. / Rubi, J. Miguel

Editorial Board Member: Ahlborn, Boye / Andresen, Bjarne / Bedeaux, Dick / Bejan, Adrian / Brüggemann, Dieter / Buchholz, Rainer / Dinkelacker, Friedrich / Do, Duong / Fox, Ronald F. / Groll, Manfred / Gross, Joachim / Kalliadasis, Serafim / Kjelstrup, S. / Kizilova, Natalya / Kollmann, W. / Lebon, Georgy / Maugin, G. A. / Muschik, Wolfgang / Papenfuss, Christina / Raffa, Robert B. / Ricard, Jacques / Scholl, Stephan / Sieniutycz, Stanislaw / Stark, Holger / Steinchen, Annie / Velarde, M.G. / Verhas, Jozsef / Stockar, Urs / Winter, Roland / Zaman, Muhammad

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IMPACT FACTOR 2013: 0.805

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GENERIC Compliance of a Temporary Network Model with Sliplinks, Chain-Length Fluctuations, Segment-Connectivity and Constraint Release

J. D. Schieber

Citation Information: Journal of Non-Equilibrium Thermodynamics. Volume 28, Issue 2, Pages 179–188, ISSN (Print) 0340-0204, DOI: 10.1515/JNETDY.2003.010, June 2005

Publication History

Published Online:
2005-06-01

Abstract

It is shown that a recently proposed sliplink theory for polymer melts is consistent with the two-generator, non-equilibrium thermodynamics formalism, GENERIC. The model was previously developed using the free energy as a generator for the dynamics. Its primary novelty is that it uses the monomeric density as a dynamic variable instead of as a parameter. By placing it in the GENERIC framework, I also derive an appropriate energy equation necessary for performing non-isothermal flow calculations. Using the algorithm already proposed and the results given here, it is possible to simulate the complete non-isothermal flow of linear, entangled polymeric fluids in complex geometries.

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