Pure and Applied Chemistry
The Scientific Journal of IUPAC
Ed. by Burrows, Hugh / Weir, Ron / Stohner, Jürgen
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Functionalized main-group organometallics for organic synthesis
1Ludwig-Maximilians-Universität München, Department Chemie, Butenandtstrasse 5-13, Haus F, 81377 München, Germany
IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS-11), International Symposium on Organometallic Chemistry Directed Toward Organic Synthesis, OMCOS, Organometallic Chemistry Directed Toward Organic Synthesis, 11th, Taipei, Taiwan, 2001-07-22–2001-07-26
Citation Information: Pure and Applied Chemistry. Volume 74, Issue 1, Pages 11–17, ISSN (Online) 1365-3075, ISSN (Print) 0033-4545, DOI: 10.1351/pac200274010011, January 2009
- Published Online:
Highly functionalized Grignard-reagents can be easily obtained by an iodinemagnesim exchange reaction and further reacted with various electrophiles. Via a BZn exchange reaction, a formal Michael addition with umpolung of the reactivity can be achieved. Chiral phosphine ligands can be easily synthesized by a 2.3 sigmatropic rearrangement and used successfully in asymmetric synthesis.
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