Abstract
This report provides an overview of the transport of solutes via macropores focusing on the practical relevance of the phenomenon. After a description of matrix flow and preferential flow in soil, information related to macropores, including their formation and measurement techniques, is briefly presented. Then, the influence of experimental conditions and of environmental and agricultural factors and pesticide properties is discussed, based on a statistical evaluation of all published studies offering sufficient quantitative information. Most of the analyzed parameters do not significantly influence the experimental pesticide losses. The groundwater ubiquity score (GUS) index turned out to be the most important compound property to describe substance losses through macropore flow. In a third section, tools for modeling pesticide transport through macropores are presented and critically evaluated. Results of the computer model MACRO, which is also used in the EU pesticide registration process, are compared with experimental losses. For five out of seven investigated pesticides (A-D, F), the simulated losses are in agreement with the experimental data. However, for two compounds with very low KOC values, MACRO overestimated the losses. Finally, the significance of pesticide transport via macropores for contamination of ground and surface water is assessed. Losses caused by macropore transport may considerably exceed losses caused by matrix transport at a specific site. Therefore, a site-specific assessment of pesticide leaching is needed.
Project Year: 1995, Project Code: 630/24/95
References
1. P. Schachtschabel, H.-P. Blume, G. Brummer, K.-H. Hartge, U. Schwertmann. Lehrbuch der Bodenkunde, 12th ed., F. E. Verlag, Stuttgart (1989).Search in Google Scholar
2. doi:10.1016/S0038-0717(96)00182-4, F. Binet, V. Hallaire, P. Curmi. Soil Biol. Biochem. 29, 577 (1997).Search in Google Scholar
3. doi:10.1097/00010694-199908000-00004, R. C. Schwartz, K. J. Mc Innes, A. S. R. Juo, C. E. Cervantes. Soil Sci. 164, 561 (1999).Search in Google Scholar
4. K. Beven, P. Germann. Water Resour. Res. 18, 1311 (1982).Search in Google Scholar
5. doi:10.1111/j.1365-2389.1979.tb00997.x, P. Bullock, A. J. Thomasson. J. Soil Sci. 30, 391 (1979).Search in Google Scholar
6. J. Webster. North Westland, Master's thesis, University of Canterbury, New Zealand (1974).Search in Google Scholar
7. H. P. Cresswell, D. J. Painter, K. C. Cameron. Soil Sci. Soc. Am. J. 57, 816 (1993).Search in Google Scholar
8. D. W. Ranken. Master's thesis, Oregon State University, Corvallis (1974).Search in Google Scholar
9. R. J. Luxmoore. Soil Sci. Soc. Am. J. 45, 671 (1981).10.2136/sssaj1981.03615995004500030051xSearch in Google Scholar
10. doi:10.1111/j.1365-2389.1981.tb01682.x, K. Beven, P. Germann. J. Soil Sci. 32, 15 (1981).Search in Google Scholar
11. (a) R. Brewer. Fabric and Mineral Analysis of Soils, John Wiley, New York (1964);10.1097/00010694-196507000-00024Search in Google Scholar
11. (b) doi:10.1016/0013-7952(79)90065-6, M. J. Reeves. Eng. Geol. 14, 231 (1981).Search in Google Scholar
12. B. Bejat, E. Perfeet, V. L. Quisenberry, M. S. Coyne, G. R. Haszler. Soil Sci. Soc. Am. J. 64, 818 (2000).Search in Google Scholar
13. W. Kordel, H. Kloppel, M. Klein, P. Dreher. UBA Report, FKZ: 126 05 204 (2003).Search in Google Scholar
14. J. Vanderborgh, A. Timmermann, J. Feyen. Soil Sci. Soc. Am. J. 64, 1305 (2000).Search in Google Scholar
15. doi:10.1111/j.1365-2389.1981.tb01681.x, P. Germann, K. Beven. J. Soil Sci. 32, 1 (1981).Search in Google Scholar
16. D. E. Hill, J.-Y. Parlange. Soil Sci. Soc. Am. Proc. 36, 697 (1972).Search in Google Scholar
17. P. A. C. Raats. Soil Sci. Soc. Am. Proc. 37, 681 (1973).10.2136/sssaj1973.03615995003700050017xSearch in Google Scholar
18. J. S. Selker, T. S. Steenhuis, J.-Y. Parlange. Soil Sci. Soc. Am. J. 56, 1346 (1992).Search in Google Scholar
19. doi:10.1029/95WR01649, Y. Liu, J.-Y. Parlange, T. S. Steenhuis. Water Resour. Res. 31, 2263 (1995).Search in Google Scholar
20. E. L. Mac Coy, C. W. Boast, C. W. Stehouwer, E. J. Kladivko. In Soil Processes and Water Quality. Adv. Soil Sci., R. Lai, B. A. Stewart (Eds.), pp. 303-348, Lewis Publications, Ann Arbor, MI (1994).Search in Google Scholar
21. doi:10.1016/0016-7061(90)90006-U, K.-J. S. Kung. Geoderma 46, 51 (1990).Search in Google Scholar
22. doi:10.1016/0016-7061(90)90007-V, K.-J. S. Kung. Geoderma 46, 59 (1990).Search in Google Scholar
23. doi:10.1029/93WR00772, A. R. Dexter. Water Resour. Res. 29, 1859 (1993).Search in Google Scholar
24. doi:10.1097/00010694-197503000-00010, W. Ehlers. Soil Sci. 119, 242 (1975).Search in Google Scholar
25. A. R. Mitchell, T. R. Ellsworth, B. Meek. Soil Sci. Plant Anal. 26, 2655 (1995).Search in Google Scholar
26. doi:10.1016/0929-1393(95)00062-3, P. M. Fraser, P. H. Williams, R. J. Haynes. Appl. Soil Ecol. 3, 49 (1995).Search in Google Scholar
27. doi:10.1016/S0929-1393(00)00132-3, C. Emmerling. Appl. Soil Ecol. 17, 91 (2000).Search in Google Scholar
28. doi:10.1016/S0167-1987(00)00173-2, K. Y. Chan. Soil Tillage Res. 57, 179 (2001).Search in Google Scholar
29. doi:10.1071/SR9920493, M. R. Carter, P. M. Mele. Aust. J. Soil Res. 30, 493 (1992).Search in Google Scholar
30. A. J. Franzluebbers, F. M. Hans, D. A. Zuberer. Soil Sci. Soc. Am. J. 58, 1639 (1994).Search in Google Scholar
31. doi:10.1071/EA9900365, P. J. Haines, N. C. Uren. Aust. J. Exp. Agric. 30, 365 (1990).Search in Google Scholar
32. R. Lal, A. A. Mahboubi, N. R. Fomsey. Soil Sci. Soc. Am. J. 58, 517 (1994).Search in Google Scholar
33. doi:10.1111/j.1365-2389.1989.tb01297.x, K. R. J. Smettern, B. E. Clothier. J. Soil Sci. 40, 563 (1989).Search in Google Scholar
34. K. M. Perroux, I. White. Soil Sci. Soc. Am. J. 52, 1205 (1988).Search in Google Scholar
35. J. L. Thony, G. Vachaud, B. E. Clothier R. Angulo-Jaramillo. Soil Technol. 4, 111 (1991).Search in Google Scholar
36. M. D. Ankeny, M. Ahmed, T. C. Kaspar, R. Horton. Soil Sci. Am. J. 55, 467 (1991).Search in Google Scholar
37. I. White, M. J. Sully. Water Resour. Res. 23, 1514 (1987).Search in Google Scholar
38. B. E. Clothier, M. B. Kirkham, J. E. McLean. Soil Sci. Am. J. 56, 733 (1992).Search in Google Scholar
39. doi:10.1071/SR9950397, B. E. Clothier, L. Heng, G. N. Magesan, I. Vogeler. Aust. J. Soil Res. 33, 397 (1995).Search in Google Scholar
40. D. B. Jaynes, S. D. Logsdon, R. Horton. Soil Sci. Soc. Am. J. 59, 352 (1995).Search in Google Scholar
41. doi:10.1016/S0167-1987(97)00021-4, P. A. Olsen. Soil Tillage Res. 44, 1 (1997).Search in Google Scholar
42. A. L. Armstrong, P. B. Leeds-Harrisson, G. L. Harris, J. A. Catt. Soil Use Manage. 15, 2406 (1999).Search in Google Scholar
43. W. M. Edwards, M. J. Shipitalo, W. A. Dick, L. B. Owens. Soil Sci. Soc. Am. J. 56, 52 (1992).Search in Google Scholar
44. R. G. Stehouwer, A. Dick, S. J. Traina. J. Environ. Qual. 22, 181 (1993).Search in Google Scholar
45. A. P. Mallawatantri, B. G. McConkey, D. J. Mulla. J. Environ. Qual. 25, 227 (1996).Search in Google Scholar
46. M. Burghardt. Feldversuche zur Erfassung des Transportverhaltens vvon gelosten und partikularen Tracern mittels Multitracing-Technik in einem schluffigen Boden. Julich, Forschungszentrum, Zentralbibliothek (2003).Search in Google Scholar
47. R. D. Wauchope, T. M. Buttler, A. G. Hornsby, P. W. M. Augustinjn-Beckers, J. B. Burt. Rev. Environ. Contamin. Toxicol. 123, 1 (1992).Search in Google Scholar
48. R. J. Hance, C. R. Worthing. The Pesticide Manual, 9th ed., British Crop Protection Council, London (1991).Search in Google Scholar
49. E. J. Kladivko, G. E. Van Scoyoc, E. J. Monke, K. M. Oates, W. Pask. J. Environ. Qual. 20, 264 (1991).Search in Google Scholar
50. doi:10.1061/(ASCE)0733-9437(1990)116:1(16), L. M. Southwick, G. H. Willies, R. L. Bengston, T. J. Lormand. J. Irrig. Drainage Eng. 116, 16 (1990).Search in Google Scholar
51. J. D. Gaynor, D. C. MacTavish, W. I. Findlay. J. Environ. Qual. 24, 246 (1995).Search in Google Scholar
52. E. J. Kladivko, J. Grochulska, R. F. Turco, G. E. Van Scoyoc, J. D. Eigel. J. Environ. Qual. 28, 997 (1999).Search in Google Scholar
53. L. F. Bergstrom, N. J. Jarvis. Weed Sci. 41, 251 (1993).Search in Google Scholar
54. (a) doi:10.1002/ps.2780430206, C. D. Brown, R. A. Hodgkinson, D. A. Rose, J. K. Syers, S. J. Wilcockson. Pestic. Sci. 43, 131 (1995);Search in Google Scholar
54. (b) C. D. Brown, D. A. Rose, J. K. Syers, R. A. Hodgkinson. BCPC Monograph 62, 93 (1995).Search in Google Scholar
55. doi:10.1016/S0273-1223(99)00431-X, S. M. Kamra, J. Michaelsen, W. Wichtmann, P. Widmoser. Water Sci. Technol. 40, 61 (1999).Search in Google Scholar
56. doi:10.1002/(SICI)1526-4998(200001)56:1<83::AID-PS98>3.0.CO;2-8, C. D. Brown, J. M. Hollis, R. J. Bettinson, A. Walker. Pest Manag. Sci. 56, 83 (2000).Search in Google Scholar
57. M. J. Shipitalo, W. M. Edwards, W. A. Dick, L. B. Owens. Soil Sci. Soc. Am. J. 54, 1530 (1990).Search in Google Scholar
58. L. M. Southwick, G. H. Willis, D. C Johnson, H. M. Selim. J. Environ. Qual. 24, 684 (1995).Search in Google Scholar
59. doi:10.1111/j.1747-6593.1997.tb00084.x, A. B. Turnbull, R. M. Harrison, R. J. Williams, P. Matthiessen, D. N. Brooke, D. A. Sheahan, M.Mills. J. Chart. Inst. Water Environ. Manage. 11, 24 (1997).Search in Google Scholar
60. doi:10.1897/1552-8618(1989)8[339:GUSASM]2.0.CO;2, D. J. Gustafson. Environ. Toxicol. Chem. 8, 339 (1989).Search in Google Scholar
61. doi:10.1016/S0167-1987(99)00104-X, M. J. Shipitalo, W. A. Dick, W. M. Edwards. Soil Tillage Res. 53, 267 (2000).Search in Google Scholar
62. W. M. Edwards, L. D. Norton, C. E. Redmond. Soil Sci. Soc. Am. J. 52, 483 (1988).Search in Google Scholar
63. M. Flury. J. Environ. Qual. 25, 25 (1996).10.2134/jeq1996.00472425002500010005xSearch in Google Scholar
64. doi:10.1029/94WR00871, M. Flury, H. Fluhler, W. A. Jury, J. Leuenberger. Water Resour. Res. 30, 1941 (1994).Search in Google Scholar
65. M. Th. Van Genuchten. In Hydrological Interactions Between Atmosphere, Soil and Vegetation, pp. 169-183, Proceedings of the Vienna Symposium, August 1991, IAHS Publ. No. 204, Wallingford, Oxfordshire, UK (1991).Search in Google Scholar
66. J. S. Aronofsky, J. P. Heller. AIME Petr. Trans. 210, 345 (1957).Search in Google Scholar
67. J. Skopp, W. R. Gardner. Soil Sci. Soc. Am. J. 56, 1680 (1992).Search in Google Scholar
68. W. M. Edwards, R. R. van der Ploeg, W. Ehlers. Soil Sci. Soc. Am. J. 43, 851 (1979).Search in Google Scholar
69. H. J. Montas, J. D. Eigel, B. A. Engel, K. Haghighi. Trans. ASAE 40, 1245 (1997).10.13031/2013.21382Search in Google Scholar
70. H. J. Montas, J. D. Eigel, B. A. Engel, K. Haghighi. Trans. ASAE 40, 1257 (1997).10.13031/2013.21383Search in Google Scholar
71. J. L. Hutson, R. J. Wagenet. Soil Sci. Soc. Am. J. 59, 743 (1995).Search in Google Scholar
72. doi:10.1016/0022-1694(94)02555-P, J. P. Gwo, P. M. Jardine, G. V. Wilson, G. T. Yeh. J. Hydrol. 164, 21 (1995).Search in Google Scholar
73. doi:10.1016/0016-7061(90)90015-2, T. S. Steenhuis, J.-Y. Parlange, M. S. Andreini. Geoderma 46, 193 (1990).Search in Google Scholar
74. doi:10.1007/BF00479408, S. Koch, H. Fluhler. Water, Air, Soil Pollut. 68, 275 (1993).Search in Google Scholar
75. M. Th. A. van Genuchten. Soil Sci. Soc. of Am. J. 44, 892 (1980).10.2136/sssaj1980.03615995004400050002xSearch in Google Scholar
76. R. H. Brooks, A. T. Corey. Hydrology Paper 3, Colorado State University, Fort Collins, Colorado (1964).Search in Google Scholar
77. Y. Mualem. Water Resour. Res. 12, 513 (1976).10.1029/WR012i003p00513Search in Google Scholar
78. N. J. Jarvis. Report & Dissertation 9, Dept. Soil Sci., Swed. Univ. Agric. Sci. Uppsala (1991).Search in Google Scholar
79. N. J. Jarvis. Report & Dissertation 19, Dept. Soil Sci., Swed. Univ. Agric. Sci. Uppsala (1994).Search in Google Scholar
80. doi:10.1016/0304-3800(94)00163-C, N. J. Jarvis. Ecol. Model. 81, 97 (1995).Search in Google Scholar
81. N. J. Jarvis, M. Stahli, L. Bergstrom, H. Johnsson. J. Environ. Sci. Health, A 29, 1255 (1994).10.1080/10934529409376106Search in Google Scholar
82. N. J. Jarvis, M. Larsson, P. Fogg, A. D. Carter. In: Proc. BCPC Symposium "Pesticide movement to water", A. Walker, R. Allen, S. W. Bailey, A. M. Blair, C. D. Brown, P. Gunther, C. R. Leake, P. H. Nicholls (Eds.), pp. 161-170, Warwick, UK (1995).Search in Google Scholar
83. doi:10.1002/(SICI)1096-9063(199609)48:1<37::AID-PS433>3.0.CO;2-L, L. Bergstrom. Pestic. Sci. 48, 37 (1996).Search in Google Scholar
84. M. Larsson. Diss., Swedish University of Agricultural Sciences, Uppsala (1999).Search in Google Scholar
85. I. Barlund. Diss., Universitat Karlsruhe IHW Publikation 63 (1998).Search in Google Scholar
86. doi:10.1016/S0378-3774(99)00086-4, A. Armstrong, A. Karin, N. Amraoui, B. Diekkruger, N. Jarvis, C. Mouvet, P. Nicholls, C.Wittwer. Agric. Water Manage. 44, 85 (2000).Search in Google Scholar
87. doi:10.1016/0378-3774(94)90054-X, L. Andreu, F. Moreno, N. J. Jarvis, G. Vachaud. Agric. Water Manage. 25, 71 (1994).Search in Google Scholar
88. doi:10.1111/j.1475-2743.1996.tb00530.x, L. Andreu, N. J. Jarvis, F. Moreno, G. Vachaud. Soil Use Manage. 12, 109 (1996).Search in Google Scholar
89. doi:10.1016/0304-3800(94)90046-9, H.-J. Franke, G. Teutsch. Ecol. Model. 75/76, 529 (1994).Search in Google Scholar
90. M. Klein. J. Pesticide Sci. 24, 55 (1999).10.1584/jpestics.24.55Search in Google Scholar
91. doi:10.1029/91WR00588, S. A. Grant, J. D. Jabro, D. D. Fritton, D. E. Baker. Water Resour. Res. 27, 1439 (1991).Search in Google Scholar
92. doi:10.1016/S0378-3774(99)00081-5, M. Vanclooster, J. J. T. I. Boesten, M. Trevisan, C. D. Brown, E. Capri, O. M. Eklo, B.Gottesburen, V. Gouy, A. M. A. van der Linden. Agric. Water Manage. 44, 1 (2000).Search in Google Scholar
93. doi:10.1016/S0378-3774(99)00088-8, A. Tiktak. Agric. Water Manage. 44, 119 (2000).Search in Google Scholar
94. doi:10.1016/S0378-3774(99)00102-X, J. J. T. I. Boesten. Agric. Water Manage. 44, 389 (2000).Search in Google Scholar
95. FOCUS. Report of the FOCUS Groundwater Scenarios Workgroup, EC Document Reference Sanco/321/2000 (2000).Search in Google Scholar
96. doi:10.1351/pac199769071571, W. Kordel, M. Dassenakis, J. Lintelmann, S. Padberg. Pure Appl. Chem. 69, 1571 (1997).Search in Google Scholar
97. Kordel, H. Kloppel, M. Klein, P. Dreher. UBA-Report, FKZ 126 05 204 (2003).Search in Google Scholar
98. doi:10.1002/ps.2780290405, L. F. Bergstrom, A. S. McGibbon, S. R. Day, M. Snel. Pestic. Sci. 29, 405 (1990).Search in Google Scholar
99. doi:10.1897/1552-8618(1991)10[563:LPADOC]2.0.CO;2, L. F. Bergstrom, A. S. McGibbon, S. R. Day, M. Snel. Environ. Toxicol. Chem. 10, 563 (1991).Search in Google Scholar
100. doi:10.1007/BF00212282, J. D. Gaynor, D. C. MacTavish, W. I. Findlay. Arch. Environ. Contam. Toxicol. 23, 240 (1992).Search in Google Scholar
101. doi:10.1111/j.1747-6593.1992.tb00779.x, P. Matthiessen, C. Allchin, R. J. Williams, S. C. Bird, D. Brooke, P. J. Glendinning. J. Inst. Water Environ. Manage. 6, 496 (1992).Search in Google Scholar
102. doi:10.1016/0022-1694(94)90259-3, G. L. Harris, P. H. Nicholls, S. W. Bailey, K. R. Howse, D. J. Mason. J. Hydrol. 159, 235 (1994).Search in Google Scholar
103. (a) doi:10.1016/0022-1694(94)90140-6, A. H. Haria, A. C. Johnson, J. P. Bell, C. H. Batchelor. J. Hydrol. 163, 203 (1994);Search in Google Scholar
103. (b) doi:10.1016/0022-1694(94)90141-4, A. C. Johnson, A. H. Haria, C. L. Bhardwaj, C. Volkner, C. H. Batchelor, A. Walker. J. Hydrol. 163, 217 (1994).Search in Google Scholar
104. K. Jayachandran, T. R. Steinheimer, L. Somasundaram, T. B. Moorman, R. S. Kanwar, J. R. Coats. J. Environ. Qual. 23, 311 (1994).Search in Google Scholar
105. (a) U. Traub-Eberhard, W. Klein, W. Kordel, R. Winkler. Z. Umweltchem. Okotox. 7, 168 (1995);10.1007/BF02939556Search in Google Scholar
105. (b) W. Kordel, I. Ronnefahrt, R. Winkler. Gesunde Pflanzen 49, 163 (1997).Search in Google Scholar
106. doi:10.1029/94WR02852, M. Flury, J. Leuenberger, B. Studer, H. Fluhler. Water Resour. Res. 31, 823 (1995).Search in Google Scholar
107. (a) A. C. Johnson, A. H. Haria, V. L. Cruxton, C. H. Batchelor, R. J. Williams, K. Heppell, T.Burt. BCPC Monograph 62, 105 (1995);Search in Google Scholar
107. (b) doi:10.1002/(SICI)1096-9063(199611)48:3<225::AID-PS462>3.0.CO;2-D, A. C. Johnson, A. H. Haria, C. L. Bhardwaj, R.J.Williams, A. Walker. Pestic. Sci. 48, 225 (1996).Search in Google Scholar
108. doi:10.1021/jf00053a045, A. J. Beck, G. L. Harris, K. R. Howse, A. E. Johnston, K. C. Jones. J. Agric. Food Chem. 43, 1368 (1995).Search in Google Scholar
109. doi:10.1111/j.1747-6593.1995.tb00928.x, R. J. Williams, D. N. Brooke, P. Matthiessen, M. Mills, A. Turnbull, R. M. Harrison. J. Inst. Water Environ. Manage. 9, 72 (1995).Search in Google Scholar
110. L. E. Gentry, M. B. David, K. M. Smith-Starks, D. A. Kovacic. J. Environ. Qual. 29, 232 (2000).Search in Google Scholar
111. doi:10.1016/S0045-6535(00)00089-8, S. Novak, J.-M. Portal, M. Schiavon. Chemosphere 42, 235 (2000).Search in Google Scholar
112. K. G. Villholth, N. J. Jarvis, O. H. Jacobsen, H. de Jonge. J. Environ. Qual. 29, 1298 (2000).Search in Google Scholar
113. E. W. Gatzweiler, B. Schmidt, M. Feyerabend. Hum. Environ. Exposure Xenobiot., Proc. 11th Symp. Pestic. Chem., A. A. M. Del Re (Ed.), 11, 305 (2000).Search in Google Scholar
114. R. L. Jones, G. L. Harris, J. A. Catt, R. H. Bromilow, D. J. Mason, D. J. Arnold. Brighton Crop Prot. Conf. - Weeds 1995, 489 (1995).Search in Google Scholar
115. J. D. Gaynor, C. S. Tan, C. F. Drury, H. Y. F. Ng, T. W. Welacky, I. J. van Weesenbeeck. J. Environ. Qual. 30, 361 (2001).Search in Google Scholar
116. R. E. White, J. S. Dyson, Z. Gerstl, B. Yaron. Soil Sci. Soc. Am. J. 50, 277 (1986).Search in Google Scholar
117. W. A. Jury, H. Elabd, M. Resketo. Water Resour. Res. 22, 749 (1986).Search in Google Scholar
118. doi:10.1021/jf00019a037, L. M. Southwick, G. H. Willis, H. M. Selim. J. Agric. Food Chem. 40, 1264 (1992).Search in Google Scholar
119. doi:10.1016/0022-1694(94)02603-9, J. A. Tindall, W. K. Vencill. J. Hydrol. 166, 37 (1995).Search in Google Scholar
120. J. Elliott, A. J. Cessna, K. B. Best, W. Nicholaichuk, L. C. Tollefson. J. Environ. Qual. 27, 124 (1998).Search in Google Scholar
121. doi:10.1002/(SICI)1096-9063(199803)52:3<241::AID-PS721>3.0.CO;2-1, C. F. Stange, B. Diekkruger, H. Nordmeyer. Pestic. Sci. 52, 241 (1998).Search in Google Scholar
122. doi:10.1016/S0016-7061(97)00120-1, M. E. Close, L. Pang, J. P. C. Watt, K. W. Vincent. Geoderma 84, 45 (1998).Search in Google Scholar
123. J. A. Elliott, A. J. Cessna, W. Nicholaichuk, L. E. Tollefson. J. Environ. Qual. 29, 1650 (2000).Search in Google Scholar
124. IUPAC. Compendium of Chemical Terminology, 2nd ed. (the "Gold Book"), compiled by A. D. McNaught and A. Wilkinson, Blackwell Science, Oxford (1997). XML on-line corrected version: <http://goldbook.iupac.org> (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins.Search in Google Scholar
125. OECD. Chemicals Testing Monographs No. 22: Testing and Assessment: Guidance Document for the Performance of Outdoor Monolith Lysimeter Studies, Organization for Economic Cooperation and Development, Paris.Search in Google Scholar
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