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Pure and Applied Chemistry

The Scientific Journal of IUPAC

Ed. by Burrows, Hugh / Weir, Ron / Stohner, Jürgen

12 Issues per year


IMPACT FACTOR 2013: 3.112
Rank 41 out of 148 in category Multidisciplinary Chemistry in the 2013 Thomson Reuters Journal Citation Report/Science Edition

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Development of efficient processes under flow conditions based on catalysts immobilized onto monolithic supported ionic liquid-like phases

M. Isabel Burguete1 / Eduardo García-Verdugo1 / Naima Karbass1 / Santiago V. Luis1 / Victor Sans1 / Maia Sokolova1

1Department of Inorganic and Organic Chemistry, A.U. for Advanced Organic Materials, University Jaume I/CSIC, Avda. Sos Baynat s/n. E-12071 Castellón, Spain

Citation Information: Pure and Applied Chemistry. Volume 81, Issue 11, Pages 1991–2000, ISSN (Online) 1365-3075, ISSN (Print) 0033-4545, DOI: 10.1351/PAC-CON-08-11-02, October 2009

Publication History

Published Online:
2009-10-15

The introduction of imidazolium subunits into polystyrene-divinylbenzene (PS-DVB) polymers enables the preparation of a variety of catalytic systems. Those include the stabilization of catalytically active Pd nanoparticles (PdNPs), immobilized enzymes, and basic catalysts. The use of monolithic supports having the appropriate morphological properties is greatly advantageous for the development of efficient catalytic processes under flow conditions based on those systems. On the other hand, the combination of those supported catalytic systems and flow conditions can be further implemented, in terms of green chemistry, by the substitution of the use of traditional solvents by environmentally friendly conditions such as the use of supercritical fluids (SCFs).

Keywords: flow chemistry; functional polymers; green chemistry; Heck reaction; ionic liquids; supercritical liquids; supported biocatalysts; supported catalysts

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