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The Scientific Journal of IUPAC

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Polyaniline: The infrared spectroscopy of conducting polymer nanotubes (IUPAC Technical Report)

Miroslava Trchová1 / Jaroslav Stejskal1

1Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, 162 06 Prague 6, Czech Republic

Project Year: 2006, Project Code: 2006-018-2-400

Citation Information: Pure and Applied Chemistry. Volume 83, Issue 10, Pages 1803–1817, ISSN (Online) 1365-3075, ISSN (Print) 0033-4545, DOI: 10.1351/PAC-REP-10-02-01, June 2011

Publication History

Published Online:
2011-06-10

Polyaniline (PANI), a conducting polymer, was prepared by the oxidation of aniline with ammonium peroxydisulfate in various aqueous media. When the polymerization was carried out in the solution of strong (sulfuric) acid, a granular morphology of PANI was obtained. In the solutions of weak (acetic or succinic) acids or in water, PANI nanotubes were produced. The oxidation of aniline under alkaline conditions yielded aniline oligomers. Fourier transform infrared (FTIR) spectra of the oxidation products differ. A group of participants from 11 institutions in different countries recorded the FTIR spectra of PANI bases prepared from the samples obtained in the solutions of strong and weak acids and in alkaline medium within the framework of an IUPAC project. The aim of the project was to identify the differences in molecular structure of PANI and aniline oligomers and to relate them to supramolecular morphology, viz. the nanotube formation. The assignment of FTIR bands of aniline oxidation products is reported.

Keywords: aniline oligomers; Fourier transform infrared (FTIR) spectroscopy; IUPAC Polymer Division; nanotubes; polyaniline

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