Abstract
A high-resolution VUV laser absorption spectroscopy is used to investigate the photon-induced ion-pair formation in D2 in the spectral region from 140117.4 to 140732.0 cm−1. We report determination of photoionization efficiency in ortho-para D2 in supersonic molecular beam with energy resolution of 0.1 cm−1. The assignment of the superexcited D2 Rydberg states is done based on the quantum defect theory.
[1] R. L. Plazman, Radiat. Res. 17, 419 (1962) http://dx.doi.org/10.2307/357110410.2307/3571104Search in Google Scholar
[2] K. -L. Han, G.-Z. He, J Photoch. Photobio. C 8, 55 (2007) http://dx.doi.org/10.1016/j.jphotochemrev.2007.03.00210.1016/j.jphotochemrev.2007.03.002Search in Google Scholar
[3] G. -J. Zhao, K.-L. Han, Accounts Chem. Res. 45, 404 (2012) http://dx.doi.org/10.1021/ar200135h10.1021/ar200135hSearch in Google Scholar
[4] V. H. Dibeler, R. M. Reese, M. Krauss, J. Chem. Phys. 42, 2045 (1965) http://dx.doi.org/10.1063/1.169624510.1063/1.1696245Search in Google Scholar
[5] C. N. R. Rao, A. Srinivasan, K. Jagannathan, M. S. Hegde, J. Sci. Ind. Res. India 39, 212 (1980) Search in Google Scholar
[6] W. A. Chupka, P. M. Dehmer, W. T. Jivery, J. Chem. Phys. 63, 3929 (1975) http://dx.doi.org/10.1063/1.43183310.1063/1.431833Search in Google Scholar
[7] P. M. Dehmer, W. A. Chupka, J. Chem. Phys. 65, 2243 (1976) http://dx.doi.org/10.1063/1.43338310.1063/1.433383Search in Google Scholar
[8] U. Fano, J. Opt. Soc. Am. 65, 979 (1975) http://dx.doi.org/10.1364/JOSA.65.00097910.1364/JOSA.65.000979Search in Google Scholar
[9] M. J. Seaton, Rep. Prog. Phys. 46, 167 (1983) http://dx.doi.org/10.1088/0034-4885/46/2/00210.1088/0034-4885/46/2/002Search in Google Scholar
[10] C. H. Greene, Ch. Jungen, Adv. Atom. Mol. Phys. 21, 51 (1985) http://dx.doi.org/10.1016/S0065-2199(08)60141-410.1016/S0065-2199(08)60141-4Search in Google Scholar
[11] C. M. Lee, Phys. Rev. A 16, 109 (1977) http://dx.doi.org/10.1103/PhysRevA.16.10910.1103/PhysRevA.16.109Search in Google Scholar
[12] Ch. Jungen, D. M. Raoult, Faraday Discuss. 71, 253 (1981) http://dx.doi.org/10.1039/dc981710025310.1039/dc9817100253Search in Google Scholar
[13] M. Raoult, Ch. Jungen, J. Chem. Phys. 74, 3388 (1981) http://dx.doi.org/10.1063/1.44149210.1063/1.441492Search in Google Scholar
[14] P. Borrell, P. M. Guyon, M. GlassMaujean, J. Chem. Phys. 66, 818 (1977) http://dx.doi.org/10.1063/1.43396010.1063/1.433960Search in Google Scholar
[15] J. Liu et al., J. Chem. Phys. 130, 174306 (2009) http://dx.doi.org/10.1063/1.312044310.1063/1.3120443Search in Google Scholar PubMed
[16] J. Liu, D. Sprecher, C. Jungen, W. Ubachs, F. Merkt, J. Chem. Phys. 132, 154301 (2010) http://dx.doi.org/10.1063/1.337442610.1063/1.3374426Search in Google Scholar PubMed
[17] K. Piszczatowski et al., J. Chem. Theory Comput. 5, 3039 (2009) http://dx.doi.org/10.1021/ct900391p10.1021/ct900391pSearch in Google Scholar PubMed
[18] A. T. J. B. Eppink, D. H. Parker, Rev. Sci. Instrum. 68, 3477 (1997) http://dx.doi.org/10.1063/1.114831010.1063/1.1148310Search in Google Scholar
[19] A. G. Suits, O. S. Vasyutinskii, Chem. Rev. 108, 3706 (2008) http://dx.doi.org/10.1021/cr040085c10.1021/cr040085cSearch in Google Scholar PubMed
[20] A. G. Smolin et al., J. Chem. Phys. 124, 094305 (2006) http://dx.doi.org/10.1063/1.216814910.1063/1.2168149Search in Google Scholar PubMed
[21] Y. Mo, J. Yang, C. Chen, J. Chem. Phys. 120, 1263 (2004) http://dx.doi.org/10.1063/1.163355110.1063/1.1633551Search in Google Scholar PubMed
[22] J. Yang, Y. S. Hao, J. Li, C. Zhou, Y. Mo, J. Chem. Phys. 122, 134308 (2005) http://dx.doi.org/10.1063/1.186733210.1063/1.1867332Search in Google Scholar
[23] Y. S. Hao, C. Zhou, Y. Mo, J. Phys. Chem. A 111, 10887 (2007) http://dx.doi.org/10.1021/jp074780a10.1021/jp074780aSearch in Google Scholar
[24] X. Gao, W. H. Zhang, Y. Mo, J. M. Li, Phys. Rev. A 82, 031401 (2010) http://dx.doi.org/10.1103/PhysRevA.82.03140110.1103/PhysRevA.82.031401Search in Google Scholar
[25] G. Knopp et al., J. Raman Spectrosc. 34, 989 (2003) http://dx.doi.org/10.1002/jrs.109110.1002/jrs.1091Search in Google Scholar
[26] O. Atabek, Dan Dill, Ch. Jungen, Phys. Rev. Lett. 33, 123 (1974) http://dx.doi.org/10.1103/PhysRevLett.33.12310.1103/PhysRevLett.33.123Search in Google Scholar
[27] G. Herzberg, Molecular Spectra and Molecular Structure, Vol. 1 (D. van Nostrand, Toronto-London-New York, 1950) Search in Google Scholar
[28] R. E. Moss, J. Chem. Soc. Faraday T. 89, 3851 (1993) http://dx.doi.org/10.1039/ft993890385110.1039/FT9938903851Search in Google Scholar
[29] P. J. Mohr, B. N. Taylor, D. B. Newell, Rev. Mod. Phys. 80, 633 (2008) http://dx.doi.org/10.1103/RevModPhys.80.63310.1103/RevModPhys.80.633Search in Google Scholar
[30] G. Herzberg, Ch. Jungen, J. Mol. Spectrosc. 41, 425 (1972) http://dx.doi.org/10.1016/0022-2852(72)90064-110.1016/0022-2852(72)90064-1Search in Google Scholar
[31] G. Herzberg, J. Mol. Spectrosc. 33, 147 (1970) http://dx.doi.org/10.1016/0022-2852(70)90060-310.1016/0022-2852(70)90060-3Search in Google Scholar
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