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Publication Date:
January 2008
ISSN:
1865-8431
DOI:
10.1515/REST.2007.129

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Ed. by Banik, Gerhard / Brückle, Irene

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VolumeIssuePage

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The Influence of Iron Gall Ink on Paper Ageing

Le vieillissement et l'influence des encres ferro-galliques sur le papierDie Wirkung von Eisengallustinten auf die Alterung von Papier
Linda Csefalvayová / Bohuslava Havlínová / Michal Čeppan / Zuzana Jakubíková

1Faculty of Chemical and Food Technology, Slovak University of Technology Bratislava, Radlinského 9, Sk-812 37 Bratislava, Slovak Republic. E-Mail: bohuslava.havlinova@stuba.sk

Citation Information: Restaurator. Volume 28, Issue 2, Pages 129–139, ISSN (Print) 0034-5806, DOI: 10.1515/REST.2007.129, January 2008

Publication History:
Published Online:
2008-01-28

SUMMARIES

Our aim was to investigate the behaviour of iron species (Fe(II), Fe(III) in prepared iron-gall inks deposited on the Whatman paper and their destructive effects on cellulose chains during accelerated ageing at 60°C and 65% relative humidity, constant. The attention was focused to examine the changes of optical, chemical and mechanical properties of paper. Different testing methods, such ascellulose degree of polymerisation, colorimetric tests, bursting strength, pH of aqueous cold extract and techniques (FTIR spectroscopy) were compared in terms of their suitability for monitoring the degradation processes. The catalytic activity of iron ions in cellulose degradation mechanisms was experimentally verified and the relationship between the acid-catalysed hydrolysis and metal-catalysed oxidation of cellulose was demonstrated.

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