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Zeitschrift für Kristallographie - Crystalline Materials

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Ed. by Antipov, Evgeny / Bismayer, Ulrich / Boldyreva, Elena V. / Huppertz, Hubert / Petrícek, Václav / Tiekink, E. R. T.


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The crystal structure of keatite, a new form of silica

Joseph Shropshire / Paul P. Keat / Philip A. Vaughan

Citation Information: Zeitschrift für Kristallographie. Volume 112, Issue 1-6, Pages 409–413, ISSN (Online) 0044-2968, ISSN (Print) 1433-7266, DOI: 10.1524/zkri.1959.112.1-6.409, July 2010

Publication History

Published Online:
2010-07-28

Abstract

Keatite (silica K) is tetragonal, space group P4121 (or P4321), a = 7.46 Å, c = 8.61 Å, and Z = 12 SiO2 per unit cell. Intensity measurements were made of the hk0 and hhl intensities and the structure was solved from Patterson and Fourier syntheses. The structure contains four-fold spirals of SiO4 tetrahedra which share corners. These spirals are linked together by additional tetrahedra, each of which shares its corners with tetrahedra in four different spirals.

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