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Zeitschrift für Kristallographie - Crystalline Materials

Ed. by Antipov, Evgeny / Bismayer, Ulrich / Huppertz, Hubert / Petrícek, Václav / Pöttgen, Rainer / Schmahl, Wolfgang / Tiekink, E. R. T. / Zou, Xiaodong

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The chromium position in ruby

S. C. Moss / R. E. Newnham

Citation Information: Zeitschrift für Kristallographie. Volume 120, Issue 4-5, Pages 359–363, ISSN (Online) 0044-2968, ISSN (Print) 1433-7266, DOI: 10.1524/zkri.1964.120.4-5.359, July 2010

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The chromium position in highly doped ruby has been determined from 00·l intensity data. Cr occupies a site 0.06 Å from the normal Al position. Contrary to recent crystal-field calculations, the shift is towards the nearest Al neighbor, increasing the smaller metal–oxygen distances.

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