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Zeitschrift für Kristallographie - Crystalline Materials

Ed. by Antipov, Evgeny / Bismayer, Ulrich / Boldyreva, Elena V. / Huppertz, Hubert / Petrícek, Václav / Pöttgen, Rainer / Schmahl, Wolfgang / Tiekink, E. R. T. / Zou, Xiaodong

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A refinement of the crystal structure of luzonite, Cu3AsS41

F. Marumo / W. Nowacki

Citation Information: Zeitschrift für Kristallographie. Volume 124, Issue 1-2, Pages 1–8, ISSN (Online) 0044-2968, ISSN (Print) 1433-7266, DOI: 10.1524/zkri.1967.124.1-2.1, July 2010

Publication History

Published Online:
2010-07-28

Abstract

The crystal structure of luzonite has been refined by means of three-dimensional least-squares methods, utilizing 121 reflection data obtained photographically with Cu radiation. The chemical composition determined with an x-ray microanalyser is Cu3(As0.64Sb0.36)S4. The lattice constants are a = 5.332 ± 0.005 Å, c = 10.570 ± 0.01 Å, and the space group is D2d11I[unk]2m. The structure is of the zincblende type, having a small deviation from the ideal structure. The interatomic distances are (As,Sb)–S = 2.265, Cu(1)–S = 2.304 and Cu(2)–S = 2.337 Å.

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Micron and Microscopica Acta, 1992, Volume 23, Number 1-2, Page 207
[3]
Z.M Saleh, G.A Williams, and P.C Taylor
Journal of Non-Crystalline Solids, 1989, Volume 114, Page 58
[4]
J.A. Henao, G. Díaz de Delgado, J.M. Delgado, F.J. Castrillo, and O. Odreman
Materials Research Bulletin, 1994, Volume 29, Number 11, Page 1121
[5]
T. Balić-Žunić, S. Šćavničar, and P. Engel
Zeitschrift für Kristallographie, 1982, Volume 160, Number 1-2, Page 109
[7]
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Physical Review B, 1987, Volume 36, Number 6, Page 3199
[8]
A. A. Mbaye, D. M. Wood, and Alex Zunger
Physical Review B, 1988, Volume 37, Number 6, Page 3008

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