Strukturverfeinerung am Talk Mg3[(OH)2Si4O10] : Zeitschrift für Kristallographie - Crystalline Materials

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Zeitschrift für Kristallographie - Crystalline Materials

Editor-in-Chief: Pöttgen, Rainer

Ed. by Antipov, Evgeny / Bismayer, Ulrich / Boldyreva, Elena V. / Huppertz, Hubert / Petrícek, Václav / Tiekink, E. R. T.


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Strukturverfeinerung am Talk Mg3[(OH)2Si4O10]

B. Perdikatsis / H. Burzlaff

Citation Information: Zeitschrift für Kristallographie - Crystalline Materials. Volume 156, Issue 3-4, Pages 177–186, ISSN (Online) 2196-7105, ISSN (Print) 2194-4946, DOI: 10.1524/zkri.1981.156.3-4.177, September 2010

Publication History

Published Online:
2010-09-16

Abstract

Because of discrepancies in the literature a redetermination of the structure of talc Mg3[(OH)2Si4O10] is reported. Space group of talc is P[unk] with lattice parameters a0 = 529.1(3) pm, b0 = 946.0(5) pm, c0 = 529.0(3)pm, α = 98.68(5)°, β = 119.90(5)° and γ = 85.27(5)°, Z = 2. Transformation by a′ = −c,b′ = 2a + c, c′ = −b leads to a pseudomonoclinic C-centred unit cell with layers of connected [SiO4]-tetrahedra parallel to (001). Two layers with opposite orientation provide for octahedral coordination polyhedra around Mg atoms.

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