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Zeitschrift für Kristallographie - Crystalline Materials

Editor-in-Chief: Pöttgen, Rainer

Ed. by Antipov, Evgeny / Bismayer, Ulrich / Boldyreva, Elena V. / Huppertz, Hubert / Petrícek, Václav / Tiekink, E. R. T.


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Coexistence of hydrogen and polyanions in multinary main group element hydrides

Ulrich Häussermann*

* Correspondence address: Arizona State University, U.S.A.,

Citation Information: Zeitschrift für Kristallographie International journal for structural, physical, and chemical aspects of crystalline materials. Volume 223, Issue 10, Pages 628–635, ISSN (Print) 0044-2968, DOI: 10.1524/zkri.2008.1016, September 2009

Publication History

Published Online:
2009-09-25

Abstract

Multinary hydrides based on mixtures of s- and p-block metals are often not fully hydrogenated, but possess a polymeric anion which is formed by the p-block component upon reduction by the s-block metals. Hydrogen may occur hydridic and exclusively coordinated by s-block metal ions (Zintl phase hydrides), or be incorporated in the polymeric anion where it acts as a covalently bonded terminating ligand (polyanionic hydrides). The current state of Zintl phase hydrides and polyanionic hydrides is reviewed with an emphasis on crystal structures and bonding principles.

Keywords: Zintl phases; Polar intermetallic compounds; Main group metal hydrides; Polyanionic hydrides

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[1]
Jonas Ångström, Robert Johansson, Tapati Sarkar, Magnus H. Sørby, Claudia Zlotea, Mikael S. Andersson, Per Nordblad, Ralph H. Scheicher, Ulrich Häussermann, and Martin Sahlberg
Inorganic Chemistry, 2015
[2]
Nathalie Kunkel, Christian Reichert, Michael Springborg, Dirk Wallacher, and Holger Kohlmann
Journal of Solid State Chemistry, 2015, Volume 221, Page 318
[3]
Trevor V. Blankenship, Xiaoping Wang, Christina Hoffmann, and Susan E. Latturner
Inorganic Chemistry, 2014, Volume 53, Number 19, Page 10620
[4]
Verina F. Kranak, Daryn E. Benson, Lukas Wollmann, Milad Mesgar, Samrand Shafeie, Jekabs Grins, and Ulrich Häussermann
Inorganic Chemistry, 2015, Volume 54, Number 3, Page 756
[5]
Patrick Wenderoth and Holger Kohlmann
Inorganic Chemistry, 2013, Volume 52, Number 18, Page 10525
[6]
Henrik Fahlquist and Dag Noréus
Inorganic Chemistry, 2013, Volume 52, Number 12, Page 7125
[7]
Patrick Wenderoth and Holger Kohlmann
Zeitschrift für anorganische und allgemeine Chemie, 2012, Volume 638, Number 10, Page 1604
[8]
Verina F. Kranak, Michael J. Evans, Luke L. Daemen, Thomas Proffen, Myeong H. Lee, Otto F. Sankey, and Ulrich Häussermann
Solid State Sciences, 2009, Volume 11, Number 11, Page 1847
[9]
Michael J. Evans, Myeong H. Lee, Gregory P. Holland, Luke L. Daemen, Otto F. Sankey, and Ulrich Häussermann
Journal of Solid State Chemistry, 2009, Volume 182, Number 8, Page 2068
[10]
David A. Lang and Susan E. Latturner
European Journal of Inorganic Chemistry, 2011, Volume 2011, Number 26, Page 4006
[11]
David A. Lang, Julia V. Zaikina, Derek D. Lovingood, Thomas E. Gedris, and Susan E. Latturner
Journal of the American Chemical Society, 2010, Volume 132, Number 49, Page 17523
[12]
Markus Armbruster, Michael Wörle, Frank Krumeich, and Reinhard Nesper
Zeitschrift für anorganische und allgemeine Chemie, 2009, Volume 635, Number 12, Page 1758

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