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Zeitschrift für Naturforschung B

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Structure and Properties of 2,3,3,3-Tetrafluoropropene (HFO-1234yf)

Michael Feller1 / Karin Lux1 / Christian Hohenstein1 / 1

1Department of Chemistry, Ludwig-Maximilian University of Munich, Butenandtstr. 5 – 13, Germany

Citation Information: Zeitschrift für Naturforschung B. Volume 69, Issue 4, Pages 379–387, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: 10.5560/znb.2014-4017, June 2014

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The novel refrigerant 2,3,3,3-tetrafluoropropene (HFO-1234yf) is discussed as a replacement for 1,1,1,2-tetrafluoroethane (R-134a) due to its low global warming potential. Although it may therefore have great potential for use on a large scale, no structural data and only a fewvibrational data of the compound are known.We describe low-temperature X-ray structure analysis, vibrational spectra and combustion properties of 2,3,3,3-tetrafluoropropene. The experimental data are compared with the results of theoretical calculations. Furthermore the basic combustion properties have been investigated.

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Structure and Properties of 2,3,3,3-Tetrafluoropropene (HFO-1234yf)

Keywords: X-Ray Diffraction; Vibrational Spectroscopy; Quantum Chemical Calculation; Combustion Experiments

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