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Licensed Unlicensed Requires Authentication Published by De Gruyter July 31, 2017

Synthesis of a Conducting Nanocomposite by Intercalative Copolymerisation of Furan and Aniline in Montmorillonite

  • O. Saiah , A. Hachemaoui and A. Yahiaoui

Abstract

Herein, we describe the synthesis of polyfuran, polyaniline, and their copolymer nanocomposites by in-situ oxidative polymerisation of corresponding monomers in the presence of montmorillonite, using ammonium persulfate as an oxidant. The obtained nanocomposites were characterised by Fourier-transform infrared spectroscopy, X-ray diffraction analysis, and UV-vis spectroscopy.


*Correspondence address, Mail address: Ahmed Yahiaoui, Mascara University, Laboratory of Organic, Macromolecular and Materials Chemistry, Faculty of Sciences, BP 763, Mascara 29000, Algeria, E-mail:

References

Anunziata, O. A., Costa, M. B. G. and Sanchez, R. D., “Preparation and Characterization of Polyaniline-Containing Na-Almcm-41 as Composite Material with Semiconductor Behavior”, J. Colloid. Interface. Sci., 292, 509–516 (2005) PMid:16054156; 10.1016/j.jcis.2005.06.002Search in Google Scholar

Asmat, S., Husain, Q. and Azam, A., “Lipase Immobilization on Facile Synthesized Polyaniline-Coated Silver-Functionalized Grapgene Oxide Nanocomposites as Noval Biocatalysts: Stability and Activity Insights”, RSC. Adv., 7, 5019–5029 (2017)Search in Google Scholar

Gonzalez-Tejera, M. J., Sanchez De La Blanca, E. and Carrillo, I., “Polyfuran Conducting Polymers: Synthesis, Properties, and Applications”, Synth. Met., 158, 165–189 (2008) 10.1016/j.synthmet.2007.12.009Search in Google Scholar

Hachemaoui, A., Yahiaoui, A. and Belbachir, M., “Synthesis and Characterization of Water Soluble Poly(n-acetyl) Iminoethylene and Poly(ethyleneimine) by Ion-Exchanged Clay Montmorillonite”, J. Appl. Polym. Sci., 102, 3741–3750 (2006) 10.1002/app.24660Search in Google Scholar

Huang, M. R., Ding, Y. B., Li, X. G., Liu, Y., Xi, K., Gao, C. L. and Kumar, R. V., “Synthesis of Semiconducting Polymer Microparticles as Solid Ionophore with Abundant Complexing Sites for Long-Life Pb(II) Sensors”, ACS Appl. Mater. Interfaces, 6, 22096–22107 (2014) PMid:25403150; 10.1021/am505463fSearch in Google Scholar

Lee, D., Lee, S. H., Char, K. and Kim, J., “Expansion Distribution of Basal Spacing of the Silicate Layers in Polyaniline/Na+-Montmorillonite Nanocomposites Monitored with X-Ray Diffraction”, Macromol. Rapid. Comm., 21, 1136–1139 (2000) 10.1002/1521-3927(20001101)21:16<1136::AID-MARC1136>3.0.CO;2-SSearch in Google Scholar

Li, X. G., Kang, Y. and Huang, M. R., “Optimization of Polymerization Conditions of Furan with Aniline for Variable Conducting Polymers”, J. Com. Chem., 8, 670–678 (2006) 10.1021/cc060014mSearch in Google Scholar

Li, X. G., Wang, H. Y. and Huang, M. R., “Synthesis, Film-Forming, and Electronic Properties of O-Phenylenediamine Copolymers Displaying an Uncommon Tricolor”, Macromolecules, 40, 1489–1496 (2007) 10.1021/ma062463gSearch in Google Scholar

Li, X. G., Huang, M. R., Zeng, J. F. and Zhu, M. F., “The Preparation of Polyaniline Waterborne Latex Nanoparticles and their Films with Anti-Corrosivity and Semi-Conductivity”, Colloids Surf., 248, 111–120 (2004) 10.1016/j.colsurfa.2004.08.077Search in Google Scholar

Li, X. G., Huang, M. R., Lu, Y. Q. and Zhu, M. F., “Synthesis and Properties of Processible Copolymer Microparticles from Chloroanilines and Aniline”, J. Mater. Chem., 15, 1343–1352 (2005) 10.1039/b412587hSearch in Google Scholar

Li, X. G., Feng, H. and Huang, M. R., “Strong Adsorbability of Mercury Ions on Aniline/Sulfoanisidine Copolymer Nanosorbents”, Chem. Eur. J., 15, 4573–4581 (2009) PMid:19296485; 10.1002/chem.200802431Search in Google Scholar

Li, X. G., Feng, H., Huang, M. R., Gu, G. L. and Moloney, M. G., “Ultrasensitive Pb(II) Potentio-Metric Sensor Based on Copolyaniline Nanoparticles in a Plasticizer Free Membrane with a Long Life Time”, Anal. Chem., 84, 134–140 (2012) PMid:22098529; 10.1021/ac2028886Search in Google Scholar

Li, X. G., Li, A. and Huang, M. R., “Facile High-Yield Synthesis of Polyaniline Nanosticks with Intrinsic Stability and Electrical Conductivity”, Chem. Eur. J., 14, 10309–10317 (2008) PMid:18830982; 10.1002/chem.200801025Search in Google Scholar

Li, X. G., Kang, Y. and Huang, M. R., “Optimization of Polymerization Conditions of Furan with Aniline for Variable Conducting Polymers”, J. Com. Chem., 8, 670–678 (2006) 10.1021/cc060014mSearch in Google Scholar

Samrana, K., Shahzada, A., Jiri, P., Josef, P. and Yogesh, M. J., “Polyaniline/Sodium Montmorillonite Clay Nanocomposites: Effect of Clay Concentration on Thermal, Structural, and Electrical Properties”, J. Mater. Sci., 47, 420–428 (2012) 10.1007/s10853-011-5815-ySearch in Google Scholar

Sen, S., Bardakcı, B., Yavuz, A. G. and Gok, A. U., “Polyfuran/Zeolite LTA Composites and Adsorption Properties”, Eur. Polym. J., 44, 2708–2717 (2008) 10.1016/j.eurpolymj.2008.05.018Search in Google Scholar

Shilabin, A. G., Entezami, A. A., “Electrochemical Behaviour of Conducting Polyfuran Derivatives Containing Pyrrole, Thiophene and Ethylenic Spacers”, Eur. Polym. J., 36, 2005–2020 (2000) 10.1016/S0014-3057(99)00262-1Search in Google Scholar

Wan, X. B., Zhang, W., Jin, S., Xue, G., You, Q. D. and Che, B., “The Electrochemical Copolymerization of Pyrrole and Furan in a Novel Binary Solvent System”, J. Electroanal. Chem., 470, 23–30 (1999) 10.1016/S0022-0728(99)00205-3Search in Google Scholar

Yahiaoui, A., Belbachir, M., “Ring-Opening Polymerization of Styrene Oxide with Maghnite-H+ As Ecocatalyst”, J. Appl. Polym. Sci., 100, 1681–1687 (2006) 10.1002/app.22946Search in Google Scholar

Yahiaoui, A., Belbachir, M. and Hachemaoui, A., “Cationic Polymerization of 1,2-Epoxy -Propane by an Acid Exchanged Montmorillonite Clay in the Presence of Ethylene Glycol”, Int. J. Mol. Sci., 4, 572–585 (2003) 10.3390/i4110572Search in Google Scholar

Received: 2017-01-09
Accepted: 2017-05-09
Published Online: 2017-07-31
Published in Print: 2017-08-11

© 2017, Carl Hanser Verlag, Munich

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