Superstructure formation in Sc5Cu2In4

Nataliya L. Gulay 1 , Rolf-Dieter Hoffmann 2 , Vasyl‘ I. Zaremba 3 , Yaroslav M. Kalychak 1 , and Rainer Pöttgen 2
  • 1 Department of Analytical Chemistry, Ivan Franko National University of Lviv, Kyryla i Mefodiya Street 6, 79005, Lviv, Ukraine
  • 2 Institut für Anorganische und Analytische Chemie, Universität Münster, Corrensstrasse 30, 48149, Münster, Germany
  • 3 Department of Inorganic Chemistry, Ivan Franko National University of Lviv, Kyryla i Mephodiya Street 6, 79005, Lviv, Ukraine
Nataliya L. Gulay
  • Department of Analytical Chemistry, Ivan Franko National University of Lviv, Kyryla i Mefodiya Street 6, 79005, Lviv, Ukraine
  • Search for other articles:
  • degruyter.comGoogle Scholar
, Rolf-Dieter Hoffmann
  • Institut für Anorganische und Analytische Chemie, Universität Münster, Corrensstrasse 30, 48149, Münster, Germany
  • Search for other articles:
  • degruyter.comGoogle Scholar
, Vasyl‘ I. Zaremba
  • Department of Inorganic Chemistry, Ivan Franko National University of Lviv, Kyryla i Mephodiya Street 6, 79005, Lviv, Ukraine
  • Search for other articles:
  • degruyter.comGoogle Scholar
, Yaroslav M. Kalychak
  • Department of Analytical Chemistry, Ivan Franko National University of Lviv, Kyryla i Mefodiya Street 6, 79005, Lviv, Ukraine
  • Search for other articles:
  • degruyter.comGoogle Scholar
and Rainer Pöttgen
  • Corresponding author
  • Institut für Anorganische und Analytische Chemie, Universität Münster, Corrensstrasse 30, 48149, Münster, Germany
  • Email
  • Search for other articles:
  • degruyter.comGoogle Scholar

Abstract

Polycrystalline Sc5Cu2In4 was synthesized by induction melting of the elements and small single crystals were obtained by a slow cooling sequence. Sc5Cu2In4 is the first coinage metal representative in the family of the so-called 5-2-4 intermetallics. The Zr5Ir2In4 type structure of Sc5Cu2In4 was refined from single crystal X-ray diffractometer data: Pnma, a = 1716.75(6), b = 677.94(12), c = 760.69(2) pm, wR2 = 0.0531, 1932 F2 values and 58 variables. Sc5Cu2In4 adopts a superstructure of the Lu5Ni2In4 type (doubling of the b axis and klassengleiche symmetry reduction from Pbam to Pnma), caused by dislocation of the copper atoms (puckering effect). Geometrically, Sc5Cu2In4 is a 4:1 intergrowth structure of distorted AlB2 and CsCl related slabs.

  • 1.

    Zaremba, V. I., Kalychak, Y. M., Zavalii, P. Y., Bruskov, V. A. Krystallografija 1991, 36, 1415.

  • 2.

    Parthé, E., Gelato, L., Chabot, B., Penzo, M., Cenzual, K., Gladyshevskii, R. TYPIX–Standardized Data and Crystal Chemical Characterization of Inorganic Structure Types. Gmelin Handbook of Inorganic and Organometallic Chemistry, 8th ed.; Springer: Berlin, 1993.

  • 3.

    Solokha, P., De Negri, S., Saccone, A., Pavlyuk, V., Marciniak, B., Tedenac, J.-C. Acta Crystallogr. 2007, C63, i13. https://doi.org/10.1107/s0108270107001503.

  • 4.

    Sojka, L., Demchyna, M., Belan, B., Manyako, M., Kalychak, Y. Intermetallics 2014, 49, 14. https://doi.org/10.1016/j.intermet.2014.01.003.

    • Crossref
    • Export Citation
  • 5.

    Villars, P., Cenzual, K. Pearson’s crystal data: crystal structure database for inorganic compounds (release 2019/20), ASM International®: Materials Park, Ohio (USA), 2019. https://doi.org/10.5860/choice.45-3800.

  • 6.

    Lukachuk, M., Pöttgen, R. Z. Naturforsch. 2002, 57b, 1353. https://doi.org/10.1515/znb-2002-1203.

  • 7.

    Lukachuk, M., Hoffmann, R.-D., Pöttgen, R. Monatsh. Chem. 2005, 136, 127. https://doi.org/10.1007/s00706-004-0229-z.

    • Crossref
    • Export Citation
  • 8.

    Lukachuk, M., Heying, B., Rodewald, U. C., Pöttgen, R. Heteroatom Chem. 2005, 16, 364. https://doi.org/10.1002/hc.20106.

    • Crossref
    • Export Citation
  • 9.

    Tursina, A. I., Kurenbaeva, Z. M., Shtepa, D. V., Nesterenko, S. N., Noël, H. Acta Crystallogr. 2006, E62, i80. https://doi.org/10.1107/s1600536806007264.

  • 10.

    Zaremba, R., Rodewald, U. C., Pöttgen, R. Monatsh. Chem. 2007, 138, 819. https://doi.org/10.1007/s00706-007-0702-6.

    • Crossref
    • Export Citation
  • 11.

    Soika, L. D., Daszkiewicz, M., Belan, B. D., Manyako, M. B., Davydov, V. M., Akselrud, L. G., Kalychak, Y. M. Ukr. Khim. Zh. 2008, 74, 90.

  • 12.

    Tyvanchuk, Y. B., Rodewald, U. C., Kalychak, Y. M., Pöttgen, R. J. Solid State Chem. 2008, 181, 878. https://doi.org/10.1016/j.jssc.2008.01.035.

    • Crossref
    • Export Citation
  • 13.

    Zaremba, R., Hermes, W., Eul, M., Pöttgen, R. Z. Naturforsch. 2008, 63b, 1447. https://doi.org/10.1515/znb-2008-1219.

  • 14.

    Tyvanchuk, Y. B., Baran, S., Duraj, R., Kalychak, Y. M., Przewoznik, J., Szytuła, A. J. Alloys Compd. 2014, 587, 573. https://doi.org/10.1016/j.jallcom.2013.10.084.

    • Crossref
    • Export Citation
  • 15.

    Szytuła, A., Baran, S., Kaczorowski, D., Sikora, W., Hoser, A. J. Alloys Compd. 2014, 617, 149.

    • Crossref
    • Export Citation
  • 16.

    Tyvanchuk, Y., Gulay, N., Bigun, I., Galadzhun, Y., Kalychak, Y. Z. Naturforsch. 2015, 70b, 283. https://doi.org/10.1515/znb-2014-0216.

  • 17.

    Gulay, N. L., Daszkiewicz, M., Tyvanchuk, Y. B., Kalychak, Y. M., Kaczorowski, D. J. Alloys Compd. 2018, 750, 92. https://doi.org/10.1016/j.jallcom.2018.03.360.

    • Crossref
    • Export Citation
  • 18.

    Tyvanchuk, Y. B., Penc, B., Szytuła, A., Zarzycki, A. Acta Phys. Polon. A 2010, 117, 599. https://doi.org/10.12693/aphyspola.117.599.

    • Crossref
    • Export Citation
  • 19.

    Gondek, Ł., Przewoźnik, J., Czub, J., Tyvanchuk, Y., Szytuła, A., Arurlaj, A. Intermetallics 2012, 21, 10. https://doi.org/10.1016/j.intermet.2011.09.007.

    • Crossref
    • Export Citation
  • 20.

    Provino, A., Mudryk, Y., Paudyal, D., Smetana, V., Manfrinetti, P. J. Appl. Phys. 2012, 111, 07E122.

  • 21.

    Ritter, C., Provino, A., Manfrinetti, P., Pecharsky, V. K., Gschneidner, K. A.Jr., Dhar, S. K. J. Phys.: Condens. Matter 2015, 27, 476001. https://doi.org/10.1088/0953-8984/27/47/476001.

    • PubMed
    • Export Citation
  • 22.

    Zhang, Z., Dong, X., Wang, Q., Li, L. Intermetallics 2018, 100, 136. https://doi.org/10.1016/j.intermet.2018.06.012.

    • Crossref
    • Export Citation
  • 23.

    Gulay, N. L., Tyvanchuk, Y. B., Kalychak, Y. M., Kaczorowski, D. J. Alloys Compd. 2018, 731, 222. https://doi.org/10.1016/j.jallcom.2017.10.023.

    • Crossref
    • Export Citation
  • 24.

    Gulay, N., Tyvanchuk, Y., Daszkiewicz, M., Makhovych, B. S., Kalychak, Y. Z. Naturforsch. 2019, 74b, 289. https://doi.org/10.1515/znb-2018-0275.

  • 25.

    Gulay, N. L., Tyvanchuk, Y. B., Daszkiewicz, M., Kaczorowski, D., Kalychak, Y. M. J. Alloys Compd. 2020, 815, 152660. https://doi.org/10.1016/j.jallcom.2019.152660.

  • 26.

    Pöttgen, R., Gulden, T., Simon, A. GIT Labor-Fachzeitschrift 1999, 43, 133.

  • 27.

    Pöttgen, R., Lang, A., Hoffmann, R.-D., Künnen, B., Kotzyba, G., Müllmann, R., Mosel, B. D., Rosenhahn, C. Z. Kristallogr. 1999, 214, 143. https://doi.org/10.1524/zkri.1999.214.3.143.

  • 28.

    Yvon, K., Jeitschko, W., Parthé, E. J. Appl. Crystallogr. 1977, 10, 73. https://doi.org/10.1107/s0021889877012898.

    • Crossref
    • Export Citation
  • 29.

    Petříček, V., Dušek, M., Palatinus, L. Z. Kristallogr. 2014, 229, 345.

  • 30.

    Emsley, J. The Elements; Oxford University Press: Oxford, 1999.

  • 31.

    Palenzona, A., Manfrinetti, P., Palenzona, R. J. Alloys Compd. 1996, 243, 182. https://doi.org/10.1016/s0925-8388(96)02402-4.

    • Crossref
    • Export Citation
  • 32.

    Dwight, A. E., Downey, J. W., Conner, R. A.Jr. Acta Crystallogr. 1967, 22, 745. https://doi.org/10.1107/s0365110x6700146x.

    • Crossref
    • Export Citation
  • 33.

    Hulliger, F. J. Alloys Compd. 1996, 232, 160. https://doi.org/10.1016/0925-8388(95)01925-1.

    • Crossref
    • Export Citation
  • 34.

    Pöttgen, R. Z. Naturforsch. 1994, 49b, 1309.

  • 35.

    Gravereau, P., Mirambet, F., Chevalier, B., Weill, F., Fournès, L., Laffargue, D., Bourée, F., Etourneau, J. J. Mater. Chem. 1994, 4, 1893. https://doi.org/10.1039/jm9940401893.

    • Crossref
    • Export Citation
  • 36.

    Donohue, J. The Structures of the Elements; Wiley: New York (U.S.A.), 1974.

  • 37.

    Lukachuk, M., Pöttgen, R. Z. Kristallogr. 2003, 218, 767. https://doi.org/10.1524/zkri.218.12.767.20545.

  • 38.

    Zumdick, M. F., Pöttgen, R. Z. Kristallogr. 1999, 214, 90. https://doi.org/10.1524/zkri.1999.214.2.90.

  • 39.

    Sebastian, C. P., Zhang, L., Fehse, C., Hoffmann, R.-D., Eckert, H., Pöttgen, R. Inorg. Chem. 2007, 46, 771. https://doi.org/10.1021/ic061691o.

    • Crossref
    • PubMed
    • Export Citation
Purchase article
Get instant unlimited access to the article.
$42.00
Log in
Already have access? Please log in.


or
Log in with your institution

Journal + Issues

Search