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Publicly Available Published by De Gruyter January 13, 2011

Synthetic studies toward the spiroimine unit of the spirolides

Stéphanie M. Guéret and Margaret A. Brimble

Synthetic studies toward the spiroimine unit of the spirolide family of shellfish biotoxins are described. Several strategies for introduction of the C7, C29, and C32 stereocenters of the A,E-ring system of the spirolides are described, such as spironitrone formation, Birch reductive alkylation, and asymmetric Diels–Alder cycloadditions.


Conference

International Conference on Organic Synthesis (ICOS-18), International Conference on Organic Synthesis, ICOS, Organic Synthesis, 18th, Bergen, Norway, 2010-08-01–2010-08-06


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Online erschienen: 2011-1-13
Erschienen im Druck: 2011-1-13

© 2013 Walter de Gruyter GmbH, Berlin/Boston

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