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Publicly Available Published by De Gruyter April 4, 2011

Superelectrophilic chemistry in the gas phase

  • Jana Roithová

Superelectrophilic chemistry in the gas phase is driven by the high intrinsic reactivity of dications. The formation of new doubly charged products proceeds via highly internally excited intermediates. Conditions for the formation of the doubly charged intermediates and a “cooling principle” in the reactivity of dications are explained. The reactivity is demonstrated with several examples.


International Conference on Physical Organic Chemistry (ICPOC-20), International Conference on Physical Organic Chemistry, ICPOC, Physical Organic Chemistry, 20th, Busan, Korea, 2010-08-22–2010-08-27


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Online erschienen: 2011-4-4
Erschienen im Druck: 2011-4-4

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