Laser electrodispersion (LED) of metals is a promising technique for the preparation of heterogeneous catalysts as an alternative to wet impregnation of supports with the corresponding salt solutions. The LED technique can be used to deposit highly active chloride- and nitrate-free metal nanoparticles onto carbon or oxide supports. We report preparation and properties of new Ni-, Pd-, and Au-containing alumina-supported catalysts with low metal loadings (10–3–10–4 % mass) and their comparison with the previously studied carbon (Sibunit) supported systems. The catalysts demonstrate high stability and extremely high specific catalytic activity (by 2–3 orders of magnitude higher than for traditional catalysts) in the gas-phase hydrodechlorination (HDC) of chlorobenzene (CB).
References
1 G. Ertl, H. Knözinger, F. Schüth, J. Weitkamp (Eds.). Handbook of Heterogeneous Catalysis, Vol. 1, 2nd ed., p. 4270, John Wiley (2008).10.1002/9783527610044Search in Google Scholar
2 Y. J. Huang, J. A. Schwarz. Appl. Catal.30, 255 (1987).Search in Google Scholar
3 10.1116/1.591393, V. M. Kozhevin, D. A. Yavsin, V. M. Kouznetsov, V. M. Busov, V. M. Mikushkin, S. Yu. Nikonov, S. A. Gurevich, A. Kolobov. J. Vac. Sci. Technol., B18, 1402 (2000).Search in Google Scholar
4 S. A. Gurevich, V. M. Kozhevin, I. N. Yassievich, D. A. Yavsin, T. N. Rostovshchikova, V. V. Smirnov. Thin Films and Nanostructures: Physico-Chemical Phenomena in Thin Films and at Solid Surfaces, L. I. Trakhtenberg, S. H. Lin, O. J. Ilegbusi (Eds.), Elsevier, Amsterdam, 34, 726 (2007).Search in Google Scholar
5 10.1016/S0167-2991(10)75038-2, T. N. Rostovshchikova, S. A. Nikolaev, E. S. Lokteva, S. A. Gurevich, V. M. Kozhevin, D. A. Yavsin, A. V. Ankudinov. Stud. Surf. Sci. Catal.175, 263 (2010).Search in Google Scholar
6 10.1016/j.cattod.2005.06.034, T. N. Rostovshchikova, V. V. Smirnov, S. A. Gurevich, V. M. Kozhevin, D. A. Yavsin, S. M. Nevskaya, S. A. Nikolaev, E. S. Lokteva. Catal. Today105, 344 (2005).Search in Google Scholar
7 10.1134/S0023158408050212, E. S. Lokteva, T. N. Rostovshchikova, S. A. Kachevskii, E. V. Golubina, V. V. Smirnov, A. Yu. Stakheev, N. S. Telegina, S. A. Gurevich, V. M. Kozhevin, D. A. Yavsin. Kinet. Catal.49, 748 (2008).Search in Google Scholar
8 V. Lunin, V. Smirnov, E. Lokteva, T. Rostovshikova, S. Kachevsky. In: The Role of Ecological Chemistry in Pollution Research and Sustainable Development. Proceedings of the NATO Advanced Research Workshop, Chisinau, Moldova, A. M. Bahadir, G. Duca (Eds.), pp. 221–232, Springer, Amsterdam (2008).Search in Google Scholar
9 T. N. Rostovshchikova, V. V. Smirnov, V. M. Kozhevin, D. A. Yavsin, M. A. Zabelin, I. N. Yassievich, S. A. Gurevich. Appl. Catal., A296, 70 (2005).10.1016/j.apcata.2005.08.032Search in Google Scholar
10 10.1016/j.cattod.2003.11.004, T. Mori, T. Yasuoka, Y. Morikawa. Catal. Today88, 111 (2004).Search in Google Scholar
11 E. Diaz, L. Faba, S. Ordonez. Appl. Catal., B104, 415 (2011).Search in Google Scholar
12 J. W. Bae, I. G. Kim, J. S. Lee, K. H. Lee, E. J. Jang. Appl. Catal., A240, 129 (2003).10.1016/S0926-860X(02)00420-9Search in Google Scholar
13 10.1007/BF02128102, Y. I. Yermakov, V. F. Surovikin, G. V. Plaksin, V. A. Semikolenov, V. A. Lokholobov, A. L. Chuvilin, S. V. Bogdanov. React. Kinet. Catal. Lett.33, 435 (1987).Search in Google Scholar
14 10.1021/ja01145a126, E. P. Barret, L. G. Joyner, P. P. Halenda. J. Am. Chem. Soc.73, 373 (1951).Search in Google Scholar
15 10.1016/j.jcat.2005.01.015, E. Heracleous, A. F. Lee, K. Wilson, A. A. Lemonidou. J. Catal.231, 159 (2005).Search in Google Scholar
16 10.1016/j.jcat.2010.05.020, M. Garcia-Dieguez, E. Finocchio, M. F. Larrabia, L. J. Slemany, G. Busca. J. Catal.274, 11 (2010).Search in Google Scholar
17 NIST X-Ray Photoelectron Spectroscopy Database, Version 3.5, National Institute of Standards and Technology. Gaithersberg, MD (2003). <http://srdata.nist.gov/xps/>.Search in Google Scholar
18 10.1016/j.susc.2005.05.021, I. Lopez-Salido, D. Ch. Lim, Y. D. Kim. Surf. Sci.588, 6 (2005).Search in Google Scholar
19 10.1016/j.mencom.2009.05.006, E. V. Golubina, S. A. Kachevsky, E. S. Lokteva, V. V. Lunin, P. Canton, P. Tundo. Mendeleev Commun.19, 133 (2009).Search in Google Scholar
20 10.1006/jcat.2002.3655, L. M. Gomez-Sainero, X. L. Seoane, J. L. G. Fierro, A. Arcoya. J. Catal.209, 279 (2002).Search in Google Scholar
21 10.1016/j.jcat.2004.01.033, R. Zanella, C. Louis, S. Giorgio, R. Touroude. J. Catal.223, 328 (2004).Search in Google Scholar
22 10.1016/j.cej.2010.06.002, M. A. Alvarez-Montero, L. M. Gomez-Sainero, J. Juan-Juan, A. Linares-Solano, J. J. Rodriguez. Chem. Eng. J.162, 599 (2010).Search in Google Scholar
23 10.1039/a904170b, N. Lingaiah, Md. A. Uddin, A. Muto, Y. Sakata. Chem. Commun. 1657 (1999).Search in Google Scholar
24 10.1006/jcat.1999.2632, M. A. Aramendia, V. Borau, I. M. Garcia, C. Jimenez, A. Marinas, J. M. Marinas, F. J. Urbano. J. Catal.187, 392 (1999).Search in Google Scholar
25 H. Karhu, A. Kalantar, I. J. Väyrynen, T. Salmi, D. Yu. Murzin. Appl. Catal., A247, 283 (2003).10.1016/S0926-860X(03)00098-XSearch in Google Scholar
26 10.1016/j.supflu.2011.05.018, E. S. Lokteva, A. E. Lazhko, E. V. Golubina, V. V. Timofeev, A. V. Naumkin, T. V. Yagodovskaya, S. N. Gaidamaka, V. V. Lunin. J. Supercrit. Fluids58, 263 (2011).Search in Google Scholar
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