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Publicly Available Published by De Gruyter January 18, 2012

Laser electrodispersion as a new chlorine-free method for the production of highly effective metal-containing supported catalysts

Ekaterina S. Lokteva, Anton A. Peristyy, Natalia E. Kavalerskaya, Elena V. Golubina, Lada V. Yashina, Tatiana N. Rostovshchikova, Sergey A. Gurevich, Vladimir M. Kozhevin, Denis A. Yavsin and Valery V. Lunin

Laser electrodispersion (LED) of metals is a promising technique for the preparation of heterogeneous catalysts as an alternative to wet impregnation of supports with the corresponding salt solutions. The LED technique can be used to deposit highly active chloride- and nitrate-free metal nanoparticles onto carbon or oxide supports. We report preparation and properties of new Ni-, Pd-, and Au-containing alumina-supported catalysts with low metal loadings (10–3–10–4 % mass) and their comparison with the previously studied carbon (Sibunit) supported systems. The catalysts demonstrate high stability and extremely high specific catalytic activity (by 2–3 orders of magnitude higher than for traditional catalysts) in the gas-phase hydrodechlorination (HDC) of chlorobenzene (CB).

References

1 G. Ertl, H. Knözinger, F. Schüth, J. Weitkamp (Eds.). Handbook of Heterogeneous Catalysis, Vol. 1, 2nd ed., p. 4270, John Wiley (2008).Search in Google Scholar

2 Y. J. Huang, J. A. Schwarz. Appl. Catal.30, 255 (1987).Search in Google Scholar

3 10.1116/1.591393, V. M. Kozhevin, D. A. Yavsin, V. M. Kouznetsov, V. M. Busov, V. M. Mikushkin, S. Yu. Nikonov, S. A. Gurevich, A. Kolobov. J. Vac. Sci. Technol., B18, 1402 (2000).Search in Google Scholar

4 S. A. Gurevich, V. M. Kozhevin, I. N. Yassievich, D. A. Yavsin, T. N. Rostovshchikova, V. V. Smirnov. Thin Films and Nanostructures: Physico-Chemical Phenomena in Thin Films and at Solid Surfaces, L. I. Trakhtenberg, S. H. Lin, O. J. Ilegbusi (Eds.), Elsevier, Amsterdam, 34, 726 (2007).Search in Google Scholar

5 10.1016/S0167-2991(10)75038-2, T. N. Rostovshchikova, S. A. Nikolaev, E. S. Lokteva, S. A. Gurevich, V. M. Kozhevin, D. A. Yavsin, A. V. Ankudinov. Stud. Surf. Sci. Catal.175, 263 (2010).Search in Google Scholar

6 10.1016/j.cattod.2005.06.034, T. N. Rostovshchikova, V. V. Smirnov, S. A. Gurevich, V. M. Kozhevin, D. A. Yavsin, S. M. Nevskaya, S. A. Nikolaev, E. S. Lokteva. Catal. Today105, 344 (2005).Search in Google Scholar

7 10.1134/S0023158408050212, E. S. Lokteva, T. N. Rostovshchikova, S. A. Kachevskii, E. V. Golubina, V. V. Smirnov, A. Yu. Stakheev, N. S. Telegina, S. A. Gurevich, V. M. Kozhevin, D. A. Yavsin. Kinet. Catal.49, 748 (2008).Search in Google Scholar

8 V. Lunin, V. Smirnov, E. Lokteva, T. Rostovshikova, S. Kachevsky. In: The Role of Ecological Chemistry in Pollution Research and Sustainable Development. Proceedings of the NATO Advanced Research Workshop, Chisinau, Moldova, A. M. Bahadir, G. Duca (Eds.), pp. 221–232, Springer, Amsterdam (2008).Search in Google Scholar

9 T. N. Rostovshchikova, V. V. Smirnov, V. M. Kozhevin, D. A. Yavsin, M. A. Zabelin, I. N. Yassievich, S. A. Gurevich. Appl. Catal., A296, 70 (2005).10.1016/j.apcata.2005.08.032Search in Google Scholar

10 10.1016/j.cattod.2003.11.004, T. Mori, T. Yasuoka, Y. Morikawa. Catal. Today88, 111 (2004).Search in Google Scholar

11 E. Diaz, L. Faba, S. Ordonez. Appl. Catal., B104, 415 (2011).Search in Google Scholar

12 J. W. Bae, I. G. Kim, J. S. Lee, K. H. Lee, E. J. Jang. Appl. Catal., A240, 129 (2003).10.1016/S0926-860X(02)00420-9Search in Google Scholar

13 10.1007/BF02128102, Y. I. Yermakov, V. F. Surovikin, G. V. Plaksin, V. A. Semikolenov, V. A. Lokholobov, A. L. Chuvilin, S. V. Bogdanov. React. Kinet. Catal. Lett.33, 435 (1987).Search in Google Scholar

14 10.1021/ja01145a126, E. P. Barret, L. G. Joyner, P. P. Halenda. J. Am. Chem. Soc.73, 373 (1951).Search in Google Scholar

15 10.1016/j.jcat.2005.01.015, E. Heracleous, A. F. Lee, K. Wilson, A. A. Lemonidou. J. Catal.231, 159 (2005).Search in Google Scholar

16 10.1016/j.jcat.2010.05.020, M. Garcia-Dieguez, E. Finocchio, M. F. Larrabia, L. J. Slemany, G. Busca. J. Catal.274, 11 (2010).Search in Google Scholar

17 NIST X-Ray Photoelectron Spectroscopy Database, Version 3.5, National Institute of Standards and Technology. Gaithersberg, MD (2003). <http://srdata.nist.gov/xps/>.Search in Google Scholar

18 10.1016/j.susc.2005.05.021, I. Lopez-Salido, D. Ch. Lim, Y. D. Kim. Surf. Sci.588, 6 (2005).Search in Google Scholar

19 10.1016/j.mencom.2009.05.006, E. V. Golubina, S. A. Kachevsky, E. S. Lokteva, V. V. Lunin, P. Canton, P. Tundo. Mendeleev Commun.19, 133 (2009).Search in Google Scholar

20 10.1006/jcat.2002.3655, L. M. Gomez-Sainero, X. L. Seoane, J. L. G. Fierro, A. Arcoya. J. Catal.209, 279 (2002).Search in Google Scholar

21 10.1016/j.jcat.2004.01.033, R. Zanella, C. Louis, S. Giorgio, R. Touroude. J. Catal.223, 328 (2004).Search in Google Scholar

22 10.1016/j.cej.2010.06.002, M. A. Alvarez-Montero, L. M. Gomez-Sainero, J. Juan-Juan, A. Linares-Solano, J. J. Rodriguez. Chem. Eng. J.162, 599 (2010).Search in Google Scholar

23 10.1039/a904170b, N. Lingaiah, Md. A. Uddin, A. Muto, Y. Sakata. Chem. Commun. 1657 (1999).Search in Google Scholar

24 10.1006/jcat.1999.2632, M. A. Aramendia, V. Borau, I. M. Garcia, C. Jimenez, A. Marinas, J. M. Marinas, F. J. Urbano. J. Catal.187, 392 (1999).Search in Google Scholar

25 H. Karhu, A. Kalantar, I. J. Väyrynen, T. Salmi, D. Yu. Murzin. Appl. Catal., A247, 283 (2003).10.1016/S0926-860X(03)00098-XSearch in Google Scholar

26 10.1016/j.supflu.2011.05.018, E. S. Lokteva, A. E. Lazhko, E. V. Golubina, V. V. Timofeev, A. V. Naumkin, T. V. Yagodovskaya, S. N. Gaidamaka, V. V. Lunin. J. Supercrit. Fluids58, 263 (2011).Search in Google Scholar

Online erschienen: 2012-1-18
Erschienen im Druck: 2012-1-18

© 2013 Walter de Gruyter GmbH, Berlin/Boston

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