Chlorine-free alternatives to the synthesis of ionic liquids for biomass processing

Gabriela Gurau; Hui Wang; Yun Qiao; Xingmei Lu; Suojiang Zhang; Robin D. Rogers

doi:10.1351/PAC-CON-11-11-10

Publicly Available Published by De Gruyter February 10, 2012

Chlorine-free alternatives to the synthesis of ionic liquids for biomass processing

Gabriela Gurau , Hui Wang , Yun Qiao , Xingmei Lu , Suojiang Zhang and Robin D. Rogers

From the journal Pure and Applied Chemistry

https://doi.org/10.1351/PAC-CON-11-11-10

Ionic liquids (ILs) are desirable for use in a large number of applications because of their unique properties; however, compositions comprising only a single IL are expensive to synthesize and difficult to purify, and the widely used chloride-based ILs can be toxic and corrosive. Therefore, there is a need for new IL compositions that minimize common disadvantages encountered with single IL composition and synthetic methods which avoid halide intermediates. In this study, IL mixtures, which are chloride-free, were synthesized by a one-pot process, and the mixtures were used to dissolve biopolymers. The synthesized IL mixtures show high capability to dissolve the two exemplary biopolymers, cellulose and chitin.

Keywords: cellulose; chitin; dissolution; halide-free synthesis; ionic liquids; one-pot synthesis

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Online erschienen: 2012-2-10

Erschienen im Druck: 2012-2-10

Chlorine-free alternatives to the synthesis of ionic liquids for biomass processing

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