D.A. Armstrong, R.E. Huie, W.H. Koppenol, S.V. Lymar, G. Merényi, P. Neta, B. Ruscic, D. M. Stanbury, S. Steenken, and P. Wardman
Pure and Applied Chemistry 2015
Volume 87, Issue 11-12, pp. 1139-1150
Recommendations are made for standard potentials involving select inorganic radicals in aqueous solution at 25 °C. These recommendations are based on a critical and thorough literature review and also by performing derivations from various literature reports. The recommended data are summarized in tables of standard potentials, Gibbs energies of formation, radical pKa’s, and hemicolligation equilibrium constants. In all cases, current best estimates of the uncertainties are provided. An extensive set of Data Sheets is appended that provide original literature references, summarize the experimental results, and describe the decisions and procedures leading to each of the recommendations.
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