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Licensed Unlicensed Requires Authentication Published online by De Gruyter May 27, 2022

Two-stage adsorber optimization of NaOH-prewashed oil palm empty fruit bunch activated carbon for methylene blue removal

Tivya Sarawanan, Noor Sabariah Mahat, Nurfarhain Mohamed Rusli and Muhammad Abbas Ahmad Zaini

Abstract

The objective of the present work was to evaluate the performance of two-stage adsorber of activated carbon from oil palm empty fruit bunch for methylene blue removal. The model was developed to predict optimum adsorbent mass and time at a specified volumes and concentrations of dye solution. Results show that the adsorbent mass can be reduced by 6.67%. Operating time taken to attain the equilibrium in a two-stage adsorber has dramatically decreased from 22 h to 0.52 h. In the performance evaluation, the adsorbent mass in stage-1 is higher than in stage-2, which lessen the workload to achieve equilibrium. A two-stage adsorber aids to optimize the mass and contact time for different percentage of dye removal that economically feasible for industrial applications.


Corresponding author: Muhammad Abbas Ahmad Zaini, School of Chemical & Energy Engineering, Faculty of Engineering, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Skudai, Johor, Malaysia; and Centre of Lipids Engineering & Applied Research (CLEAR), Ibnu-Sina Institute for Scientific & Industrial Research, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Skudai, Johor, Malaysia, E-mail:

Funding source: UTM ICONIC

Award Identifier / Grant number: 09G54

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: The project presented in this article is supported by UTM ICONIC Fund No. 09G54.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

References

1. Yao, Y, Xu, F, Chen, M, Xu, Z, Zhu, Z. Adsorption behavior of methylene blue on carbon nanotubes. Bioresour Technol 2010;101:3040–6. https://doi.org/10.1016/j.biortech.2009.12.042.Search in Google Scholar PubMed

2. Al-Ghouti, MA, Khraisheh, MA, Allen, SJ, Ahmad, MN. The removal of dyes from textile wastewater: a study of the physical characteristics and adsorption mechanisms of diatomaceous earth. J Environ Manag 2003;69:229–38. https://doi.org/10.1016/j.jenvman.2003.09.005.Search in Google Scholar PubMed

3. Torres-Perez, J, Huang, Y, Bazargan, A, Khoshand, A, McKay, G. Two-stage optimization of Allura direct red dye removal by treated peanut hull waste. SN Appl Sci 2020;2:475. https://doi.org/10.1007/s42452-020-2196-3.Search in Google Scholar

4. Spagnoli, AA, Giannakoudakis, DA, Bashkova, S. Adsorption of methylene blue on cashew nut shell based carbons activated with zinc chloride: the role of surface and structural parameters. J Mol Liq 2017;229:465–71. https://doi.org/10.1016/j.molliq.2016.12.106.Search in Google Scholar

5. Wirasnita, R, Hadibarata, T, Mohd Yusoff, AR, Mat Lazim, Z. Preparation and characterization of activated carbon from oil palm empty fruit bunch wastes using zinc chloride. J. Teknol 2015;74:77–81. https://doi.org/10.11113/jt.v74.4876.Search in Google Scholar

6. Zhang, X, Cheng, L, Wu, X, Tang, Y, Wu, Y. Activated carbon coated palygorskite as adsorbent by activation and its adsorption for methylene blue. J Environ Sci 2015;33:97–105. https://doi.org/10.1016/j.jes.2015.01.014.Search in Google Scholar PubMed

7. Yan, KZ, Ahmad Zaini, MA, Arsad, A, Nasri, NS. Rubber seed shell based activated carbon by physical activation for phenol removal. Chem Eng Trans 2019;72:151–6.Search in Google Scholar

8. Safa, Y, Bhatti, HN. Kinetic and thermodynamic modeling for the removal of Direct Red-31 and Direct Orange-26 dyes from aqueous solutions by rice husk. Desalination 2011;272:313–22. https://doi.org/10.1016/j.desal.2011.01.040.Search in Google Scholar

9. García, JR, Sedran, U, Zaini, MAA, Zakaria, ZA. Preparation, characterization, and dye removal study of activated carbon prepared from palm kernel shell. Environ Sci Pollut Control Ser 2017;25:5076–85. https://doi.org/10.1007/s11356-017-8975-8.Search in Google Scholar PubMed

10. Zubir, MHM, Zaini, MAA. Twigs-derived activated carbons via H3PO4/ZnCl2 composite activation for methylene blue and Congo red dyes removal. Sci Rep 2020;10:14050. https://doi.org/10.1038/s41598-020-71034-6.Search in Google Scholar PubMed PubMed Central

11. Hameed, B, Mahmoud, D, Ahmad, A. Equilibrium modeling and kinetic studies on the adsorption of basic dye by a low-cost adsorbent: coconut (Cocos nucifera) bunch waste. J Hazard Mater 2008;158:65–72. https://doi.org/10.1016/j.jhazmat.2008.01.034.Search in Google Scholar PubMed

12. Alam, MZ, Muyibi, SA, Mansor, MF, Wahid, R. Activated carbons derived from oil palm empty-fruit bunches: application to environmental problems. J Environ Sci 2007;19:103–8. https://doi.org/10.1016/s1001-0742(07)60017-5.Search in Google Scholar

13. Ooi, CH, Ang, CL, Yeoh, FY. The properties of activated carbon fiber derived from direct activation from oil palm empty fruit bunch fiber. Adv Mater Res 2013;686:109–17. https://doi.org/10.4028/www.scientific.net/amr.686.109.Search in Google Scholar

14. Sakamoto, T, Zaini, MAA, Amano, Y, Machida, M. Preparation and characterization of activated carbons produced from oil palm empty fruit bunches. TANSO 2019;286:9–13. https://doi.org/10.7209/tanso.2019.9.Search in Google Scholar

15. Li, Q, Yue, Q, Su, Y, Gao, B. Equilibrium and a two-stage batch adsorber design for reactive or disperse dye removal to minimize adsorbent amount. Biores Technol 2011;02:5290–6. https://doi.org/10.1016/j.biortech.2010.11.032.Search in Google Scholar PubMed

16. Palanisami, H, Azmi, MRM, Zaini, MAA. Coffee residue-based activated carbons for phenol removal. Water Pract Technol 2021;16:793–80.10.2166/wpt.2021.034Search in Google Scholar

17. Anuar, MAK, Mahat, NS, Rusli, NM, Alam, MNHZ, Zaini, MAA. Insight into the optimization of mass and contact time in two-stage adsorber design for malachite green removal by coconut shell activated carbon. Int J Bio Renew Energy 2021;10:1–8.Search in Google Scholar

18. Bamatraf, SMS, Zaini, MAA. Optimization in a two-stage sorption of malachite green by date palm residue carbon. In: 2021 International congress of advanced technology and engineering (ICOTEN); 2021:1–5 pp.10.1109/ICOTEN52080.2021.9493441Search in Google Scholar

19. Ho, Y, McKay, G. A two-stage batch sorption optimized design for dye removal to minimize contact time. Process Saf Environ Protect 1998;76:313–8. https://doi.org/10.1205/095758298529678.Search in Google Scholar

20. Oladipo, AA, Gazi, M. Two-stage batch sorber design and optimization of biosorption conditions by Taguchi methodology for the removal of acid red 25 onto magnetic biomass. Kor J Chem Eng 2015;32:1864–78. https://doi.org/10.1007/s11814-015-0001-6.Search in Google Scholar

21. Markandeya Singh, A, Shukla, S, Mohan, D, Singh, N, Bhargava, D, Shukla, R, et al.. Adsorptive capacity of sawdust for the adsorption of MB dye and designing of two-stage batch adsorber. Cogent Environ Sci 2015;1:1075856. https://doi.org/10.1080/23311843.2015.1075856.Search in Google Scholar

22. Özacar, M, Şengil, A. A two-stage batch adsorber design for methylene blue removal to minimize contact time. J Environ Manag 2005;80:372–9.10.1016/j.jenvman.2005.10.004Search in Google Scholar PubMed

23. Özacar, M, Şengi, A. Two-stage batch sorber design using second-order kinetic model for the sorption of metal complex dyes onto pine sawdust. Biochem Eng J 2004;21:39–45.10.1016/j.bej.2004.05.003Search in Google Scholar

Received: 2022-02-15
Accepted: 2022-05-14
Published Online: 2022-05-27

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