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Licensed Unlicensed Requires Authentication Published by De Gruyter January 22, 2016

Geopolymers as potential new binder class for the wood based composite industry

  • Ali Shalbafan EMAIL logo , Johannes Welling and Joachim Hasch
From the journal Holzforschung

Abstract

Geopolymer binders are an emerging class of mineral polymer that can be manufactured from natural raw materials and industrial byproducts containing high amounts of silica (Si) and alumina (Al) in mineral compositions. Various ratios of materials used for manufacturing geopolymer binder have been tested to evaluate the bonding performance of geopolymers with wood by means of tests performed on an automated bonding evaluation system (ABES). Tests with a binder based on sodium silicate water glass (Na 50T) are partly promising, which resulted only 10% lower shear strength than that based on urea formaldehyde. The binder characteristics were significantly influenced by changing the ratio of SiO2:M2O (M=Na or K) and the ratio solid content to chemical base in the water glass. Expectedly, increasing press temperatures and pressing times showed a positive correlation with the curing performance of geopolymer binder. It was also demonstrated that the binder properties can be changed in wide ranges to obtain binders which fulfill the minimum requirements set by industrial users.


Corresponding author: Ali Shalbafan, Department of Wood and Paper Science and Technology, Faculty of Natural Resources and Marine Sciences, Tarbiat Modares University, Noor, Iran, Phone: +98 912 253 8764, e-mail:

Acknowledgments

The work presented was sponsored by the Swiss Krono Group. The financial support received is gratefully acknowledged. The authors would also gratefully acknowledge the Wöllner GmbH and Ferropem companies for supplying materials.

References

Alomayri, T., Shaikh, F.U.A., Low, I.M. (2013) Characterisation of cotton fibre-reinforced geopolymer composites. Compos. Part. B-Eng. 50:1–6.10.1016/j.compositesb.2013.01.013Search in Google Scholar

Ambroise, J., Maximilien, S., Pera, J. (1994) Properties of metakaolin blended cements. Adv. Cem. Based. Mater. 1:161–168.10.1016/1065-7355(94)90007-8Search in Google Scholar

Asadi, M., Nemati, A., Naghizadeh, R., Arzani, K., Fahim, J. (2013) Effect of temperature and activator molar of Na2O to SiO2 in the process of synthesis and microstructure of cement geopolymer. Adv. Mat. Res. 1:3–9.Search in Google Scholar

Bing-hui, M., Zhu, H., Xue-min, C., Yan, H., Si-yu, G. (2014) Effect of curing temperature on geopolymerization of metakaolin-based geopolymers. Appl. Clay. Sci. 99:144–148.10.1016/j.clay.2014.06.024Search in Google Scholar

Chen, R., Ahmari, S., Zhang, L. (2014) Utilization of sweet sorghum fiber to reinforce fly ash-based geopolymer. J. Mater. Sci. 49:2548–2558.10.1007/s10853-013-7950-0Search in Google Scholar

Cheng, T.W., Chiu, J.P. (2003) Fire-resistant geopolymer produced by granulated blast furnace slag. Miner. Eng. 16:205–210.10.1016/S0892-6875(03)00008-6Search in Google Scholar

Davidovits, J. (2002) 30 Years of successes and Failures in geopolymer applications. Market trends and potential breakthroughs. Geopolymer Conference, Melbourne, Australia.Search in Google Scholar

Davidovits, J. (2013). Geopolemer cement, a review. Technical paper. Institute of Geopolymere. p. 11.Search in Google Scholar

Dunky M. (1997) Analysis of formaldehyde condensation resins for the wood based panels industry: status and new challenges. In: Proceedings of the 7th European Panels Products Symposium. Eds. Hague, Loxton, Bolton, Mott. Liandudno, North Wales, UK. p. 217.Search in Google Scholar

Ferra, J.M.M., Ohlmeyer, M., Mendes, A.M., Costa, M.R.N., Carvalho, L.H., Magalhaes, F.D. (2011) Evaluation of urea-formaldehyde adhesives performance by recently developed mechanical tests. Int. J. Adhes. Adhes. 31:127–134.10.1016/j.ijadhadh.2010.11.013Search in Google Scholar

Gouny, F., Fouchal, F., Maillard, P. Rossignol, S. (2012) A geopolymer mortar for wood and earth structures. Constr. Build. Mater. 36:188–195.10.1016/j.conbuildmat.2012.04.009Search in Google Scholar

Gouny, F., Fouchal, F., Maillard, P. Rossignol, S. (2014) Study of the effect of siliceous species in the formation of a geopolymer binder: understanding the reaction mechanisms among the binder, wood, and earth brick. Ind. Eng. Chem. Res. 53: 3559–3569.10.1021/ie403670cSearch in Google Scholar

Heah, C.Y., Kamarudin, H., Mustafa Al Bakri, A.M., Bnhussain, M., Luqman, M., Khairul Nizar, I., Ruzaidi, C.M., Liew, Y.M. (2012) Study on solids-to-liquid and alkaline activator ratios on kaolin-based geopolymer. Cons. Build. Mater. 35:912–922.10.1016/j.conbuildmat.2012.04.102Search in Google Scholar

Heinemann, C. Characterization of the curing process of adhesives in wood- particle matrices by evaluation of mechanical and chemical kinetics. Ph.D Dissertation, Hamburg: Institute for Wood Technology, University of Hamburg, 2004.Search in Google Scholar

Humphrey, P.E. Device to test adhesive bonds. United States Patent, US005176028A. The State of Oregon Acting by and through the Oregon State Board of Higher Education on behalf of Oregon State University, Eugne, OR, USA, 1993.Search in Google Scholar

Packham, D.E. Handbook of Adhesion. John Wiley & Sons, Ltd., West Sussex, UK, 2005.10.1002/0470014229Search in Google Scholar

Pizzi, A. (2014) Synthetic adhesives for wood panels. Rev. Adhes. Adhes. 2:85–126.10.7569/RAA.2013.097317Search in Google Scholar

Pizzi, A., Mittal, K.L. Handbook of Adhesive Technology. Marcel Dekker AG, Basel, Switzerland, 2003.10.1201/9780203912225Search in Google Scholar

Provis, J.L., van Deventer, J.S.J. Geopolymers; Structures, Processing, Properties and Industrial Applications. Woodhead Publishing Limited, Oxford Cambridge, New Delhi, 2009.Search in Google Scholar

Prud’homme, E., Michaud, P., Peyratout, C., Smith, A., Rossignol, S., Joussein, E., Sauvat, N. (2010) Geomaterial foam to reinforce wood. Strategic materials and computational design: ceramic engineering and science proceedings, 10.1002/9780470944103.ch1, 31:1–8.Search in Google Scholar

Rashad, A.M. (2013a). A comprehensive overview about the influence of different additives on the properties of alkali-activated slag – a guide for civil engineer. Constr. Build. Mater. 47:29–55.10.1016/j.conbuildmat.2013.04.011Search in Google Scholar

Rashad, A.M. (2013b). Alkali-activated metakaolin: a short guid for civil engineer – an overview. Constr. Build. Mater. 41:751–765.10.1016/j.conbuildmat.2012.12.030Search in Google Scholar

Sarmin, S.N., Welling J., Krause, A., Shalbafan, A. (2014) Investigating the possibility of geopolymer to produce inorganic-bonded wood composites for multifunctional construction material–a review. BioResources. 9:7941–7950.10.15376/biores.9.4.SarminSearch in Google Scholar

Soleimani, M.A., Naghizadeh, R., Mirhabibi, A.R., Golestanifard, F. (2012) Effect of calcination temperature of the kaolin and molar Na2O/Si2O activator ratio on physical and microstructural properties of metakaolin based geopolymers. Iran J. Mater. Sci. Eng. 9:43–51.Search in Google Scholar

Xu, H., van Deventer, J.S.J. (2000) The geopolymerisation of alumino-silicate minerals. Int. J. Miner. Process. 59:247–266.10.1016/S0301-7516(99)00074-5Search in Google Scholar

Yunsheng, Z.H., Wei, S., Zongjin, L. (2010) Composition design and microstructural characterization of calcined kaolin-based geopolymer cement. Appl. Clay. Sci. 47:271–275.10.1016/j.clay.2009.11.002Search in Google Scholar

Received: 2015-9-30
Accepted: 2015-12-10
Published Online: 2016-1-22
Published in Print: 2016-8-1

©2016 Walter de Gruyter GmbH, Berlin/Boston

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