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Licensed Unlicensed Requires Authentication Published by De Gruyter May 26, 2017

Performance of waterborne copper/organic wood preservatives in an AWPA E14 soft-rot laboratory soil bed test using modified soil

  • Darrel Nicholas EMAIL logo
From the journal Holzforschung

Abstract

Soil chemistry is known to have a major effect on the degradation of treated wood by basidiomycete fungi in laboratory and exterior ground-contact exposures. However, this topic received little attention from a soft-rot (SR) decay perspective. In the present paper, laboratory SR tests were performed with two different types of forest soils, which were also modified. Test samples, made of Pinus glabra (Walt.) (pine) were treated with four commercial copper/organic waterborne preservatives. In addition, soluble or particulate copper and the organic co-biocides quarternary ammonia compound or tebuconazole, were individually examined. After 19 months of soil bed exposure, moderate to severe degradation was observed in all treated samples in both soils. Surprisingly, microscopic examination showed minimal SR decay. Samples in the neutral soil had extensive tunneling bacterial deterioration and the best performance was observed with both copper/quaternary commercial formulations. Samples in the acidic soil appeared to have some white-rot and bacterial deterioration and all four commercial copper/organic formulations showed good statistically equivalent efficacy. For samples treated with only copper, the particulate copper samples performed statistically equivalent or slightly better than amine copper, while samples treated with only the organic quarternary or tebuconazole performed poorly in both soils.

Acknowledgments

Approved for publication as FWRC Paper No. SB 868.

References

Amburgey, T.L. (1978) Soil effect on soil-block wood decay tests. Mater. Organismen 13:245–251.Search in Google Scholar

American Wood Protection Association. Book of Standards. AWPA, Birmingham, AL, 2012.Search in Google Scholar

Duncan, C.G. (1965) Determining resistance to sort rot fungi. U.S. Forest Service Research Paper FPL 48.Search in Google Scholar

Ge, X., Wang, L., Hou, J., Rong, B., Yue, X., Zhang, S. (2017) The effects of brown-rot decay on select wood properties of poplar (Populus cathayana Rehd.) and its mechanism of action. Holzforschung 71:355–362.10.1515/hf-2016-0150Search in Google Scholar

Janzen, S., Nicholas, D.D. (2016) Relation of transverse compression properties and the degree of brown rot biodeterioration of Pinus glabra in the soil block test. Holzforschung 70: 1067–1071.10.1515/hf-2016-0004Search in Google Scholar

Jin, L., Walcheski, P., Preston, A. (2008) Laboratory studies on copper availability in wood treated with soluble amine copper and micronized copper systems. IRG/WP/30489. The International Research Group on Wood Protection. Stockholm.Search in Google Scholar

Little, N.S., Schultz, T.P, Nicholas, D.D. (2010) Effect of different soils and pH amendments on brown-rot decay activity in a soil block test. Holzforschung 64:667–671.10.1515/hf.2010.081Search in Google Scholar

McKaig, P.A. (1984) Developments in unsterile soil soft-rot testing. IRG/WP/2210. The International Research Group on Wood Protection. Stockholm.Search in Google Scholar

Ribera, J., Schubert, M., Fink, S., Cartabia, M., Schwarze, F.W.M.R. (2017) Premature failure of utility poles in Switzerland and Germany related to wood decay basidiomycetes. Holzforschung 71:241–247.10.1515/hf-2016-0134Search in Google Scholar

Schmitt, S., Zhang, J., Shields, S., Schultz, T. (2014) Copper-based wood preservative systems used for residential applications in North America and Europe. In: Deterioration and Protection of Sustainable Biomaterials. Eds. Schultz, T.P., Goodell, B., Nicholas, D.D. ACS Symposium Series 1158, ACS, Washington, DC. pp. 217–225.10.1021/bk-2014-1158.ch012Search in Google Scholar

Schultz, T.P., Nicholas, D.D., Preston, A.P. (2014) Wood protection trends in North America. In: Deterioration and Protection of Sustainable Biomaterials. Eds. Schultz, T.P., Goodell, B., Nicholas, D.D. ACS Symposium Series 1158, ACS, Washington, DC. pp. 351–361.10.1021/bk-2014-1158.ch021Search in Google Scholar

Smith, R.S., Gjovik, L.R. (1972) Interlaboratory testing of wood preservatives using ASTM D1413-61. Wood Fiber 4:170–178.Search in Google Scholar

Sterling, R., Temiz, A. (2014) Fungicides and insecticides used in wood preservation. In: Deterioration and Protection of Sustainable Biomaterials. Eds. Schultz, T.P., Goodell, B., Nicholas, D.D. ACS Symposium Series 1158, ACS, Washington, DC. pp. 185–201.10.1021/bk-2014-1158.ch010Search in Google Scholar

Wakeling, R., Morris, P. (2014) Wood deterioration: ground contact hazards. In: Deterioration and Protection of Sustainable Biomaterials. Eds. Schultz, T.P., Goodell, B., Nicholas, D.D. ACS Symposium Series 1158, ACS, Washington, DC. pp. 131–146.10.1021/bk-2014-1158.ch007Search in Google Scholar

Xue, W., Kennepohl, P., Ruddick, J.N.R. (2012) Investigation of copper solubilisation and reaction in micronized copper treated wood by electron paramagnetic resonance (EPR) spectroscopy. Holzforschung 66:889–895.10.1515/hf.2011.188Search in Google Scholar

Zhang, J., Horton, J. (2016) Release of copper from pressure treated wood. IRG/WP/20584. The International Research Group on Wood Protection. Stockholm.Search in Google Scholar

Received: 2016-12-20
Accepted: 2017-4-19
Published Online: 2017-5-26
Published in Print: 2017-8-28

©2017 Walter de Gruyter GmbH, Berlin/Boston

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