Abstract
Impregnation of wood with paraffin wax emulsion (PWE) is a common eco-friendly approach for improving water repellency. In this study, loblolly pine (Pinus taeda) and Scots pine (Pinus sylvesteris) samples were impregnated with PWEs with different solid contents and particle sizes, and the influence of the impregnation parameters on wax penetration and distribution in treated wood was elucidated by time domain nuclear magnetic resonance (TD-NMR). A good linear correlation (R2=0.981) between wax content determined by TD-NMR and weight percent gain (WPG) of the impregnated wood was established. According to wax loading and distribution data, loblolly pine has a much better permeability than Scots pine. With decreasing solid content and particle size, the penetration of PWE increases in both species. The water contact angles (CA) on the surface at different depths of wood were also determined, and the CA results were consistent with the wax distribution found by the TD-NMR analysis.
Acknowledgment
The authors are grateful for the support of the Fundamental Research Funds for the Central Universities in China (BLX2015-11 and 2015ZCQ-CL-01).
References
Ahmed, S.A., Hansson, L., Morén, T. (2013) Distribution of preservatives in thermally modified Scots pine and Norway spruce sapwood. Wood Sci. Techn. 47:499–513.10.1007/s00226-012-0509-4Search in Google Scholar
Avramidis, G., Scholz, G., Nothnick, E., Militz, H., Viöl, W., Wolkenhauer, A. (2010) Improved bondability of wax-treated wood following plasma treatment. Wood Sci. Techn. 45:359–368.10.1007/s00226-010-0327-5Search in Google Scholar
Bauch, J., Berndt, H. (1973) Variability of the chemical composition of pit membranes in bordered pits of gymnosperms. Wood Sci. Techn. 7:6–19.10.1007/BF00353374Search in Google Scholar
Borgin, K. (1961) The effect of water repellents on the dimensional stability of wood. Norsk Skogindustri 11:507–521.Search in Google Scholar
Brich, M., Kozhin, V. (2001) Modeling of impregnation of wood with protective solutions and emulsions. J. Eng. Mater. Technol. 74:104–111.Search in Google Scholar
Brischke, C., Melcher, E. (2015) Performance of wax-impregnated timber out of ground contact: results from long-term field testing. Wood Sci. Techn. 49:189–204.10.1007/s00226-014-0692-6Search in Google Scholar
Dvinskikh, S.V., Henriksson, M., Berglund, L.A., Furó, I. (2011) A multinuclear magnetic resonance imaging (MRI) study of wood with adsorbed water: estimating bound water concentration and local wood density. Holzforschung 65:103–107.10.1515/hf.2010.121Search in Google Scholar
Esteves, B., Nunes, L., Domingos, I., Pereira, H. (2014) Improvement of termite resistance, dimensional stability and mechanical properties of pine wood by paraffin impregnation. Eur. J. Wood Wood Prod. 72:609–615.10.1007/s00107-014-0823-7Search in Google Scholar
Fredriksson, M., Thygesen, L.G. (2017) The states of water in Norway spruce (Picea abies (L.) Karst.) studied by low-field nuclear magnetic resonance (LFNMR) relaxometry: assignment of free-water populations based on quantitative wood anatomy. Holzforschung 71:77–90.10.1515/hf-2016-0044Search in Google Scholar
Grigsby, W., Thumm, A. (2011a) The interactions between wax and UF resin in medium density fibreboard. Eur. J. Wood Wood Prod. 70:507–517.10.1007/s00107-011-0580-9Search in Google Scholar
Grigsby, W.J., Thumm, A. (2011b) Resin and wax distribution and mobility during medium density fibreboard manufacture. Eur. J. Wood Wood Prod. 70:337–348.10.1007/s00107-011-0560-0Search in Google Scholar
Hoffmeyer, P., Engelund, E.T., Thygesen, L.G. (2011) Equilibrium moisture content (EMC) in Norway spruce during the first and second desorptions. Holzforschung 65:875–882.10.1515/HF.2011.112Search in Google Scholar
Humar, M., Kržišnik, D., Lesar, B., Thaler, N., Ugovšek, A., Zupančič, K., Žlahtič, M. (2017) Thermal modification of wax-impregnated wood to enhance its physical, mechanical, and biological properties. Holzforschung 71:57–64.10.1515/hf-2016-0063Search in Google Scholar
Hyvönen, A., Piltonen, P., Niinimäki, J. (2005) Tall oil/water – emulsions as water repellents for Scots pine sapwood. Eur. J. Wood Wood Prod. 64:68–73.10.1007/s00107-005-0040-5Search in Google Scholar
Javed, M.A., Kekkonen, P.M., Ahola, S., Telkki, V.-V. (2015) Magnetic resonance imaging study of water absorption in thermally modified pine wood. Holzforschung 69:899–907.10.1515/hf-2014-0183Search in Google Scholar
Jin, Y., Zheng, X., Chi, Y., Ni, M. (2013) Rapid, accurate measurement of the oil and water contents of oil sludge using low-field NMR. Ind. Eng. Chem. Res. 52:2228–2233.10.1021/ie303143gSearch in Google Scholar
Kogbara, R.B., Iyengar, S.R., Grasley, Z.C., Masad, E.A., Zollinger, D.G. (2015) Non-destructive evaluation of concrete mixtures for direct LNG containment. Mater. Des. 82:260–272.10.1016/j.matdes.2015.05.084Search in Google Scholar
Lesar, B., Pavlič, M., Petrič, M., Škapin, A.S., Humar, M. (2011a) Wax treatment of wood slows photodegradation. Polym. Degrad. Stab. 96:1271–1278.10.1016/j.polymdegradstab.2011.04.006Search in Google Scholar
Lesar, B., Straže, A., Humar, M. (2011b) Sorption properties of wood impregnated with aqueous solution of boric acid and montan wax emulsion. J. Appl. Polym. Sci. 120:1337–1345.10.1002/app.33196Search in Google Scholar
Li, X., Wang, X., Zhang, M. (2016) Molecular dynamics of water in wood studied by fast field cycling nuclear magnetic resonance relaxometry. BioResources 11:1882–1891.10.15376/biores.11.1.1882-1891Search in Google Scholar
Matsumura, J., Booker, R.E., Ridoutt, B.G., Donaldson, L.A., Mikajiri, N., Matsunaga, H., Oda, K. (1999) Impregnation of radiata pine wood by vacuum treatment II: effect of pre-steaming on wood structure and resin content. J. Wood. Sci. 45:456–462.10.1007/BF00538953Search in Google Scholar
Meder, R., Franich, R., Callaghan, P.T., Behr, V.C. (2015) A comparative study of dewatering of Pinus radiata sapwood using supercritical CO2 and conventional forced air-drying via in situ magnetic resonance microimaging (MRI). Holzforschung 69:1137–1142.10.1515/hf-2014-0134Search in Google Scholar
Nussbaum, R.M., Sutcliffe, E. J., Hellgren, A.-C. (1998) Microautoradiographic studies of the penetration of alkyd, alkyd emulsion and linseed oil coatings into wood. J. Coat. Technol. 70:49–57.10.1007/BF02697811Search in Google Scholar
Rowell, R.M., Banks, W. B. (1985) Water repellancy and dimensional stability of wood. Technical Report FPL 50. United States Department of Agriculture.10.2737/FPL-GTR-50Search in Google Scholar
Scholz, G., Krause, A., Militz, H. (2010a) Exploratory study on the impregnation of Scots pine sapwood (Pinus sylvestris L.) and European beech (Fagus sylvatica L.) with different hot melting waxes. Wood Sci. Techn. 44:379–388.10.1007/s00226-010-0353-3Search in Google Scholar
Scholz, G., Militz, H., Gascón-Garrido, P., Ibiza-Palacios, M.S., Oliver-Villanueva, J.V., Peters, B.C., Fitzgerald, C.J. (2010b) Improved termite resistance of wood by wax impregnation. Int. Biodeterior. Biodegrad. 64:688–693.10.1016/j.ibiod.2010.05.012Search in Google Scholar
Scholz, G., Van den Bulcke, J., Boone, M., Zauer, M., Bäucker, E., Van Acker, J., Militz, H. (2010c) Investigation on wax-impregnated wood. Part 1: Microscopic observations and 2D X-ray imaging of distinct wax types. Holzforschung 64:581–586.10.1515/hf.2010.091Search in Google Scholar
Scholz, G., Zauer, M., Van den Bulcke, J., Van Loo, D., Pfriem, A., Van Acker, J., Militz, H. (2010d) Investigation on wax-impregnated wood. Part 2: Study of void spaces filled with air by He pycnometry, Hg intrusion porosimetry, and 3D X-ray imaging. Holzforschung 64:587–593.10.1515/hf.2010.090Search in Google Scholar
Telkki, V.-V., Yliniemi, M., Jokisaari, J. (2013) Moisture in softwoods: fiber saturation point, hydroxyl site content, and the amount of micropores as determined from NMR relaxation time distributions. Holzforschung 67:291–300.10.1515/hf-2012-0057Search in Google Scholar
Thomas, R. J. (1969) The ultrastructure of loblolly pinebordered pit membranes as revealed by specialized drying techniques. Wood Fiber Sci. 1:110–123.Search in Google Scholar
Tondi, G., Thevenon, M., Mies, B., Standfest, G., Petutschnigg, A., Wieland, S. (2013) Impregnation of Scots pine and beech with tannin solutions: effect of viscosity and wood anatomy in wood infiltration. Wood Sci. Techn. 47:615–626.10.1007/s00226-012-0524-5Search in Google Scholar PubMed PubMed Central
Uphill, S. J., Cosgrove, T., Briscoe, W. H. (2014) Flow of nanofluids through porous media: preserving timber with colloid science. Colloids Surf. A 460:38–50.10.1016/j.colsurfa.2014.05.008Search in Google Scholar
Wang, W., Zhu, Y., Cao, J., Guo, X. (2015) Thermal modification of southern pinecombined with wax emulsion preimpregnation: effect on hydrophobicity and dimensional stability. Holzforschung 69:405–413.10.1515/hf-2014-0106Search in Google Scholar
Yu, L., Tang, Z., Wei, D., Zhu, L., Zhu, J., Ma, X. (2016) Evaluation of the dimensional stability and leaching performance of ACQ/wax treated southern pine. Bioresources 11:10201–10212.10.15376/biores.11.4.10201-10212Search in Google Scholar
Žlahtič, M., Mikac, U., Serša, I., Merela, M., Humar, M. (2017). Distribution and penetration of tung oil in wood studied by magnetic resonance microscopy. Ind. Crops Prod. 96:149–157.10.1016/j.indcrop.2016.11.049Search in Google Scholar
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