Skip to content
Licensed Unlicensed Requires Authentication Published by De Gruyter August 25, 2017

Pore analysis of thermally compressed Scots pine (Pinus sylvestris L.) by mercury intrusion porosimetry

  • Lili Li , Ximing Wang EMAIL logo , Yan Yan and Lijuan Ping
From the journal Holzforschung

Abstract

In focus of the present study was the mercury intrusion porosimetry (MIP) of heartwood (hW) and sapwood (sW) of Scots pine, which were modified by compression alone (C) and combination of C and heat treatment (CHT). The untreated sW has a more uniform pore distribution than that of hW as presented in logarithmic differential curves. Expectedly, the total pore volumes of CHThW and CHTsW are significantly decreased. Compared to the HT temperature (180–220°C), the exposure time (2–5 h) has a weaker effect on the pore structures of the CHT woods. Furthermore, the intrusion volume of CHThW decreased compared with compressed alone samples. However, an inverse result was apparent for CHTsW.

Acknowledgements

The authors gratefully acknowledge the financial support from National Majority R & D Program of China (2016YFD0600701), the Innovation Team of Desert Shrub Fibrosis and Energy Utilization Technology of the Inner Mongolia Autonomous Region, of Inner Mongolia Agricultural University, the Disposal and Recycling Technology Development, and Industrialization of Industrial Solid Waste (Inner Mongolia Autonomous Region).

References

Ahmed, S.A., Hansson, L., Moren, T. (2013) Distribution of preservatives in thermally modified Scots pine and Norway spruce sapwood. Wood Sci. Technol. 47:499–513.10.1007/s00226-012-0509-4Search in Google Scholar

Awoyemi, L., Jones, I.P. (2011) Anatomical explanations for the changes in properties of western red cedar (Thuja plicata) wood during heat treatment. Wood Sci. Technol. 45:261–267.10.1007/s00226-010-0315-9Search in Google Scholar

Bauch, J., Berndt, H. (1973) Variability of the chemical composition of pit membranes in bordered pits of gymnosperms. Wood Sci. Technol. 7:6–19.10.1007/BF00353374Search in Google Scholar

Boonstra, M.J., Tjeerdsma, B. (2006) Chemical analysis of heat treated softwoods. Holz Roh Werkst. 64:204–211.10.1007/s00107-005-0078-4Search in Google Scholar

Boonstra, M.J., Rijsdijk, J.F., Sander, C., Kegel, E., Tjeerdsma, B., Militz, H., Van Acker, J., Stevens, M. (2006) Microsstructural and physical aspects of heat treated wood. Part 1. Softwoods. Maderas-Cience Technol. 8:193–208.Search in Google Scholar

Brito, J.O., Silva, F.G., Leao, M.M., Almeida, G. (2008) Chemical composition changes in eucalyptus and pinus woods submitted to heat treatment. Bioresources Technol. 99: 8545–8548.10.1016/j.biortech.2008.03.069Search in Google Scholar PubMed

Burmester, A. Formbeständigkeit von Holz gegenüber Feuchtigkeit – Grundlagen und Vergütungsverfahren. Bundesanstalt für Materialprüfung (BAM), Germany, 1970. p. 188.Search in Google Scholar

Ding, W.-D., Koubaa, A., Chaala, A., Belem, T., Krause, C. (2008) Relationship between wood porosity, wood density and methylmethacrylate impregnation rate. Wood Mater. Sci. Eng. 3:62–70.10.1080/17480270802607947Search in Google Scholar

Dogu, D., Tirak, K., Candan, Z., Unsal, O. (2010) Anatomical investigation of thermally compressed wood panels. Bioresources 5:2640–2663.Search in Google Scholar

Esteves, B., Velez Marques, A., Domingos, I., Pereira, H. (2013) Chemical changes of heat treated pine and eucalypt wood monitored by FTIR. Maderas-Cienc Tecnal. 15:245–258.10.4067/S0718-221X2013005000020Search in Google Scholar

Giudicianni, P., Cardone, G., Ragucci, R. (2013) Cellulose, hemicellulose and lignin slow steam pyrolysis: thermal decomposition of biomass components mixtures. J. Anal. Appl. Pyrolysis. 100:213–222.10.1016/j.jaap.2012.12.026Search in Google Scholar

He, S., Lin, L., Fu, F., Zhou, Y., Fan, M. (2014) Microwave treatment for enhancing the liquid permeability of Chinese Fir. Bioresources 9:1924–1938.10.15376/biores.9.2.1924-1938Search in Google Scholar

Hillis, W.E. (1968) Chemical aspects of heartwood formation. Wood Sci. Technol. 2:241–259.10.1007/BF00350271Search in Google Scholar

Li, L., Wang, X., Wu, F. (2016) Chemical analysis of densification, drying, and heat treatment of Scots pine (Pinus sylvestris L.) through a hot-pressing process. Bioresources 11:3856–3874.10.15376/biores.11.2.3856-3874Search in Google Scholar

Metsä-Kortelainen, S. (2011) Differences between sapwood and heartwood of thermally modified Norway Spruce (Picea abies) and Scots Pine (Pinus sylvestris) under water and decay exposure. Chemical technology. PhD thesis, Aalto University, Finland, 65 pp.Search in Google Scholar

Metsä-Kortelainen, S., Antikainen, T., Viitaniemi, P. (2006) The water absorption of sapwood and heartwood of Scots pine and Norway spruce heat-treated at 170°C, 190°C, 210°C and 230°C. Holz Roh Werkst. 64:192–197.10.1007/s00107-005-0063-ySearch in Google Scholar

Navi, P., Sandberg, D. Thermo-hydro-mechanical Processing of Wood. CRC Press, Boca Raton, USA, 2012.10.1201/b10143Search in Google Scholar

Pfriem, A., Zauer, M., Wagenführ, A. (2009) Alteration of the pore structure of spruce (Picea abies (L.) Karst.) and maple (Acer pseudoplatanus L.) due to thermal treatment as determined by helium pycnometry and mercury intrusion porosimetry. Holzforschung 63:94–98.10.1515/HF.2009.027Search in Google Scholar

Ploetze, M., Niemz, P. (2011) Porosity and pore size distribution of different wood types as determined by mercury intrusion porosimetry. Eur. J. Wood Wood Prod. 69:649–657.10.1007/s00107-010-0504-0Search in Google Scholar

Scholz, G., Zauer, M., Van den Bulcke, J., Van Loo, D., Pfriem, A., Van Acker, J., Militz, H. (2010) Investigation on wax-impregnated wood. Part 2: Study of void spaces filled with air by He pycnometry, Hg intrusion porosimetry, and 3D X-ray imaging. Holzforschung 64:587–593.10.1515/hf.2010.090Search in Google Scholar

Siau, J.F. Transport Processes in Wood. Springer, Berlin, Heidelberg, New York, 1984. p. 245.10.1007/978-3-642-69213-0Search in Google Scholar

Song, K., Yin, Y., Salmen, L., Xiao, F., Jiang, X. (2014) Changes in the properties of wood cell walls during the transformation from sapwood to heartwood. J. Mater. Sci. 49:1734–1742.10.1007/s10853-013-7860-1Search in Google Scholar

Wang, D., Peng, L., Zhu, G., Fu, F., Zhou, Y., Song, B. (2014) Improving the sound absorption capacity of wood by microwave treatment. Bioresources 9:7504–7518.10.15376/biores.9.4.7504-7518Search in Google Scholar

Zauer, M., Pfriem, A., Wagenführ, A. (2013) Toward improved understanding of the cell-wall density and porosity of wood determined by gas pycnometry. Wood Sci. Technol. 47:1197–1211.10.1007/s00226-013-0568-1Search in Google Scholar

Zhang, H.-B., Yang, M.-X., Tu, R., Gao, L., Zhao, Z.-W. (2008) Fungal communities in decaying sapwood and heartwood of a conifer Keteleeria evelyniana. Curr. Microbiol. 56:358–362.10.1007/s00284-007-9092-6Search in Google Scholar PubMed

Zimmer, K., Treu, A., McCulloh, K.A. (2014) Anatomical differences in the structural elements of fluid passage of Scots pine sapwood with contrasting treatability. Wood Sci. Technol. 48:435–447.10.1007/s00226-014-0619-2Search in Google Scholar

Received: 2017-5-18
Accepted: 2017-7-26
Published Online: 2017-8-25
Published in Print: 2017-12-20

©2018 Walter de Gruyter GmbH, Berlin/Boston

Downloaded on 28.11.2023 from https://www.degruyter.com/document/doi/10.1515/hf-2017-0083/pdf
Scroll to top button