Skip to content
Licensed Unlicensed Requires Authentication Published by De Gruyter September 28, 2018

Selectivity Analysis for Networks Comprising Consecutive Reactions of Second and First Order

Dmitry Yu. Murzin EMAIL logo , Irina L. Simakova and Johan Wärnå

Abstract

Coupling of second and first order reactions in one pot fashion through a cascade process is an often encountered process. Consecutive reactions of this type are considered and selectivity analysis is performed demonstrating dependence of selectivity pattern on reaction parameters.

References

Arnaut, L., S. Formosinho, and H. Burrows. 2006. Chemical Kinetics. Elsevier: Amsterdam.Search in Google Scholar

Bähn, S., S. Imm, L. Neubert, M. Zhang, H. Neumann, and M. Beller. 2011. “The Catalytic Amination of Alcohols.” ChemCatChem 3: 1853 –64.10.1002/cctc.201100255Search in Google Scholar

Blackmond, D. G. 2015. “Kinetic Profiling of Catalytic Organic Reactions as a Mechanistic Tool.” Journal of American Chemical Society 137: 10852–66.10.1021/jacs.5b05841Search in Google Scholar

Bruggink, A., R. Schoevaart, and T. Kieboom. 2003. “Concepts of Nature in Organic Synthesis: Cascade Catalysis and Multistep Conversions in Concert.” Organic Process Research and Development 7: 622–40.10.1021/op0340311Search in Google Scholar

Chieregato, A., V. J. Ochoa, C. Bandinelli, G. Fornasari, F. Cavani, and M. Mella. 2015. “On the Chemistry of Ethanol on Basic Oxides: Revising Mechanisms and Intermediates in the Lebedev and Guerbet Reaction.” ChemSusChem 8: 377–88.10.1002/cssc.201402632Search in Google Scholar

Demidova, Yu. S., I. L. Simakova, J. Wärnå, A. Simakov, and D. Yu. Murzin. 2014. “Kinetic Modeling of One-Pot Myrtenol Amination over Au/ZrO2.” Chemical Engineering Journal 238: 164–71.10.1016/j.cej.2013.09.007Search in Google Scholar

Fogler, H. S. 1998. Elements of Chemical Reaction Engineering, 3d ed. Prentice Hall: NJ.Search in Google Scholar

Froment, G., and K. Bischoff. 1990. Chemical Reactor Analysis and Design, 2d ed. Wiley: NY.Search in Google Scholar

Gabriels, D., W. Y. Hernandez, B. Sels, P. Van der Voort, and A. Verberckmoes. 2015. “Review of Catalytic Systems and Thermodynamics for the Guerbet Condensation Reaction and Challenges for Biomass Valorization.” Catalysis Science and Technology 5: 3876–902.10.1039/C5CY00359HSearch in Google Scholar

Helfferich, F. G. 2001. “Kinetics of Homogeneous Multistep Reactions.” In Comprehensive Chemical Kinetics, edited by R. G. Compton and G. Hancock, vol. 38, 1–508. Elsevier: Amsterdam.10.1016/S0069-8040(01)80021-2Search in Google Scholar

Kiss, V., and K. Osz. 2017. “Double Exponential Evaluation under Non-Pseudo –First Order Conditions. A Mixed Second-Order Process Followed by A First-Order Reaction.” International Journal of Chemical Kinetics 49: 602–10.10.1002/kin.21100Search in Google Scholar

Laidler, K. J. 1987. Chemical Kinetics. Pearson Education: NY.Search in Google Scholar

Lente, G. 2015. “Kinetics of Irreversible Consecutive Processes with First Order Second Steps: Analytical Solutions.” Journal of Mathematical Chemistry 53: 1172–83.10.1007/s10910-015-0477-7Search in Google Scholar

Levenspiel, O. 1998. Chemical Reaction Engineering, 3rd ed. Weinheim: Wiley.10.1007/978-1-4899-0104-0_1Search in Google Scholar

Murzin, D. Yu., and T. Salmi. 2016. Catalytic Kinetics, Chemistry and Engineering, 2d ed. Elsevier: Amsterdam.10.1016/B978-0-444-63753-6.00006-3Search in Google Scholar

Nieminen, V., M. Kangas, T. Salmi, and D. Yu. Murzin. 2005. “Kinetic Study of N-Butane Isomerization of Pt-H-mordenite.” Industrial and Engineering Chemistry Research 44: 471–84.10.1021/ie049544qSearch in Google Scholar

Obora, Y. 2014. “Recent Advances in N-Alkylation Reactions Using Alcohols with Hydrogen Borrowing Methodologies.” ACS Catalysis 4: 3972–81.10.1021/cs501269dSearch in Google Scholar

Panchenko, V. N., E. A. Paukshtis, D. Yu. Murzin, and I. L. Simakova. 2017. “Solid Base Assisted N-Pentanol Coupling over VIII Group Metals: Elucidation of the Guerbet Reaction Mechanism by DRIFTS.” Industrial and Engineering Chemistry Research 56: 13310−13321.10.1021/acs.iecr.7b01853Search in Google Scholar

Patel, A. D., S. Telalović, J. H. Bitter, E. Worrell, and M. K. Patel. 2015. “Analysis of Sustainability Metrics and Application to the Catalytic Production of Higher Alcohols from Ethanol.” Catalysis Today 239: 56–79.10.1016/j.cattod.2014.03.070Search in Google Scholar

Salmi, T. O., J.-P. Mikkola, and J. Wärnå. 2010. Chemical Reaction Engineering and Reactor Technology. CRC Press: Boca Raton.10.1201/9781439894859Search in Google Scholar

Schueth, F., M. D. Ward, and J. M. Buriak. 2018. “Common Pitfalls of Catalysis Manuscripts Submitted to Chemistry of Materials.” Chemistry of Materials 30: 3599−3600.10.1021/acs.chemmater.8b01831Search in Google Scholar

Shimizu, K.-I. 2015. “Heterogeneous Catalysis for the Direct Synthesis of Chemicals by Borrowing Hydrogen Methodology.” Catalysis Science and Technology 5: 1412–27.10.1039/C4CY01170HSearch in Google Scholar

Sidorenko, A. Yu., A. V. Kravtsova, J. Wärnå, A. Aho, I. Heinmaa, V. Il'ima, K. P. Volcho, et al. 2018. “Preparation of octahydro-2H-chromen-4-ol with Analgesic Activity from Isopulegol and Thiophene-2-Carbaldehyde in the Presence of Acid-Modified Clays.” Molecular Catalysis 453: 139–48.10.1016/j.mcat.2018.05.007Search in Google Scholar

Received: 2018-06-29
Accepted: 2018-09-18
Published Online: 2018-09-28

© 2019 Walter de Gruyter GmbH, Berlin/Boston

Downloaded on 4.12.2022 from frontend.live.degruyter.dgbricks.com/document/doi/10.1515/ijcre-2018-0161/html
Scroll Up Arrow