Skip to content
Licensed Unlicensed Requires Authentication Published by De Gruyter May 12, 2021

Thermodynamic assessment of the Sb–S and In–S binary systems

  • Chuang Shi , Na Li and Weibin Zhang EMAIL logo

Abstract

The Sb–S and In–S binary systems were assessed thermodynamically using the CALculation of PHase Diagrams (CAL-PHAD) approach based on the experiment data in the literature. Both phase diagrams revealed a congruent melting compound and liquid immiscibility. Therefore, associate species, Sb2S3 and In2S3, were introduced into the associate model to describe the liquid phase during optimization. The binary intermediate compounds, Sb2S3, InS(α, β), and In6S7, were treated as stoichiometric phases. Considering the wide composition range, In2S3(α, β, γ), were modeled using the sublattice model. A set of self-consistent thermodynamic parameters representing most of the reliable thermodynamic properties and phase diagram information were derived.


Professor Dr. Weibin Zhang Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education) Shandong University Jinan 250061 P. R. China Tel.: +86 0531-88392315 Fax: +86 0531-88392315

References

[1] R. Kondrotas, C. Chen, J. Tang: Joule 2 (2018) 857. DOI:10.1016/j.joule.2018.04.00310.1016/j.joule.2018.04.003Search in Google Scholar

[2] J. Zhang, H. Wang, X. Yuan, G. Zeng, W. Tu, S. Wang: J. Photochem. Photobiol., C 38 (2019) 1. DOI:10.1016/j.jphotochemrev.2018.11.00110.1016/j.jphotochemrev.2018.11.001Search in Google Scholar

[3] S. Lugo, I. López, Y. Peñaa, M. Calixto, T. Hernández, S. Messina, D. Avellaneda: Thin Solid Films 569 (2014) 76. DOI:10.1016/j.tsf.2014.08.04010.1016/j.tsf.2014.08.040Search in Google Scholar

[4] W. Septina, S. Ikeda, Y. Iga, T. Harada, M. Matsumura: Thin Solid Films 550 (2014) 700. DOI:10.1016/j.tsf.2013.11.04610.1016/j.tsf.2013.11.046Search in Google Scholar

[5] J. Zhang, W. Lian, Y. Yin, X. Wang, R. Tang, C. Qian, X. Hao, C. Zhu, T. Chen: Sol. RRL 4 (2020) 2000048. DOI:10.1002/solr.20200004810.1002/solr.202000048Search in Google Scholar

[6] K. Rui, T. Yagioka, S. Adachi, A. Handa, H. Sugimoto: IEEE Photovoltaic Spec. Conf., 43rd (2016) 1287. DOI:10.1109/PVSC.2016.774982210.1109/PVSC.2016.7749822Search in Google Scholar

[7] H. Lukas, S.G. Fries, B. Sundman: Computational thermodynamics. The CALPHAD method, Cambridge University Press, Cambridge (2007). DOI:10.1017/CBO978051180413710.1017/CBO9780511804137Search in Google Scholar

[8] W.S. Kim: J. Alloys Compd. 252 (1997) 0. DOI:10.1016/s0925-8388(96)02709-010.1016/s0925-8388(96)02709-0Search in Google Scholar

[9] H.W. King: Bull. Alloy Phase Diagrams 2 (1981) 401. DOI:10.1007/BF0286830710.1007/BF02868307Search in Google Scholar

[10] I.D. Reid, S.F.J. Cox, U.A. Jayasooriya, U. Zimmermann: Phys. B 374–375 (2006) 408. DOI:10.1016/j.physb.2005.11.11810.1016/j.physb.2005.11.118Search in Google Scholar

[11] B.B. Nayak, H.N. Acharya, G.B. Mitra, B.K. Mathur: Thin Solid Films 105 (1983) 17. DOI:10.1016/0040-6090(83)90326-710.1016/0040-6090(83)90326-7Search in Google Scholar

[12] M. Wolcyrz, R. Kubiak, S. Maciejewski: Phys. Status Solidi B 107 (2006) 245. DOI:10.1002/pssb.222107012510.1002/pssb.2221070125Search in Google Scholar

[13] U. Schwarz, H. Hillebrecht, K. Syassen: Z. Kristallogr. 210 (1995) 494. DOI:10.1524/zkri.1995.210.7.49410.1524/zkri.1995.210.7.494Search in Google Scholar

[14] H.J. Deiseroth, H. Pfeifer, A. Stupperich: Z. Kristallogr. Cryst. Mater. 27 (1993) 45. DOI:10.1524/zkri.1993.207.12.4510.1524/zkri.1993.207.12.45Search in Google Scholar

[15] P. Pistor, J.M.M. Álvarez, M. León, M.D. Michiel, S. Lehmann: Acta Crystallogr. 72 (2016) 410. DOI:10.1107/S205252061600705810.1107/S2052520616007058Search in Google Scholar

[16] A. Likforman, M. Guittard, A. Tomas, J. Flahaut: J. Solid State Chem. 34 (1980) 353. DOI:10.1016/0022-4596(80)90434-X10.1016/0022-4596(80)90434-XSearch in Google Scholar

[17] F.M. Jaeger, H.S.V. Klooster: Z. Anorg. Chem. 78 (1912) 245. DOI:10.1002/zaac.1912078012110.1002/zaac.19120780121Search in Google Scholar

[18] M. Hansen, K. Anderko: Constitution of Binary Alloy, McGraw-Hill, New York (1958) 1305. DOI:10.1149/1.242870010.1149/1.2428700Search in Google Scholar

[19] K.C. Mills: Thermodynamic Data for Inorganic Sulphides, Selenides and Tellurides, Butterworths, London (1974).Search in Google Scholar

[20] Y.H. Lee, K. Itagaki: Nippon Kinzoku Gakkaishi 27 (1986) 987. DOI:10.2320/matertrans1960.27.98710.2320/matertrans1960.27.987Search in Google Scholar

[21] T.B. Massalski, P.R. Subramanian, H. Okamoto, L. Kacprazak: Binary Alloy Phase Diagrams, Vol. 3, ASM International, Materials Park, Ohio (1990).Search in Google Scholar

[22] E.V. Britzke, A.F. Kapustinskii: Anorg. Chem. 205 (1932) 171. DOI:10.1002/zaac.1932205010910.1002/zaac.19322050109Search in Google Scholar

[23] K. Sudo: Bull. Res. Inst. Miner. Dressing Metall., Tohoku Univ. 8 (1952) 117.Search in Google Scholar

[24] T.A. Stolyarova, N.N. Kolpakova: N. N. Dokl. Akad. Nauk SSSR. 243 (1978) 1550.Search in Google Scholar

[25] G.K. Johnson, G.N. Papatheodorou, C.E. Johnson: J. Chem. Thermodyn. 13 (1981) 745. DOI:10.1016/0021-9614(81)90063-X10.1016/0021-9614(81)90063-XSearch in Google Scholar

[26] J. Sestak, V. Sestakova, Z. Zivkovic, D. Zivkovic: Pure Appl. Chem. 67 (1995) 1885. DOI:10.1351/pac19956711188510.1351/pac199567111885Search in Google Scholar

[27] M.F. Stubbs, J.A. Schufle, A.J. Thompson, J.M. Duncan: J. Am. Chem. Soc. 74 (1952) 1441. DOI:10.1021/ja01126a02410.1021/ja01126a024Search in Google Scholar

[28] A.R. Miller: PHD thesis, The vapor pressure of indium sulfides as functions of composition and temperature, California University, USA (1963).Search in Google Scholar

[29] A.R. Miller, A.W. Searcy: J. Phys. Chem. 69 (1965) 3826. DOI:10.1021/j100895a03110.1021/j100895a031Search in Google Scholar

[30] W.J. Duffin, J.H.C. Hogg: Acta Crystallogr. 20 (1966) 566. DOI:10.1107/S0365110X6600126910.1107/S0365110X66001269Search in Google Scholar

[31] H.G. Ansell, R.S. Boorman: Cesk. Pediatr. 118 (1971) 990. DOI:10.1149/1.240792510.1149/1.2407925Search in Google Scholar

[32] T. Gödecke, K. Schubert: Z. Metallkd. 76 (1985) 358.Search in Google Scholar

[33] H. Okamoto, in: C.E.T. White, H. Okamoto (eds.), Phase Diagrams of Indium Alloys and Their Engineering Applications, ASM International, Materials Park, Ohio (1992).Search in Google Scholar

[34] A.Y. Zavrazhnov, A.V. Naumov, P.V. Anorov, E.G. Goncharov, V.S. Pervov: Inorg. Mater. 42 (2006) 1294. DOI:10.1134/s002016850612002810.1134/s0020168506120028Search in Google Scholar

[35] A.Y. Zavrazhnov, A.V. Naumov, A.V. Sergeeva, V.I. Sidei: In-org. Mater. 43 (2007) 1303. DOI:10.1134/S002016850711003910.1134/S0020168507110039Search in Google Scholar

[36] A.Y. Zavrazhnov, I.D. Zartsyn, D.N. Turchen, A.V. Naumov, V.P. Zlomanov: Inorg. Mater. 40 (2004) 101. DOI:10.1007/s10789-005-0056-610.1007/s10789-005-0056-6Search in Google Scholar

[37] A.V. Kosyakov, A.Y. Zavrazhnov, A.V. Naumov: Inorg. Mater. 46 (2010) 343. DOI:10.1134/S002016851004003510.1134/S0020168510040035Search in Google Scholar

[38] A.Y. Zavrazhnov, A.V. Kosyakov, A.V. Naumov, A.V. Sergeeva, S.S. Berezin: Thermochim. Acta. 566 (2013) 169. DOI:10.1016/j.tca.2013.05.03110.1016/j.tca.2013.05.031Search in Google Scholar

[39] S.S. Berezin, M.V. Berezina, A.Y. ZavrazhnoV, A.V. KosyakoV, A.V. Sergeeva, V.I. Sidei: Inorg. Mater. 49 (2013) 555. DOI:10.1134/S002016851306001010.1134/S0020168513060010Search in Google Scholar

[40] P. Wy_zga, Igor Veremchuk, C. Himcinschi, U. Burkhardt, W. Carrillo-Cabrera, M. Bobnar, C. Hennig, A. Leithe-Jasper, J. Kortus, R. Gumeniuk: Dalton Trans. 48 (2019) 8350. DOI:10.1039/C9DT00890J10.1039/C9DT00890JSearch in Google Scholar

[41] A.J. Thompson, M.F. Stubbs, J.A. Schufle: J. Am. Chem. Soc. 76 (1954). DOI:10.1021/ja01631a00610.1021/ja01631a006Search in Google Scholar

[42] R. Colin, J. Drowart: Trans. Faraday Soc. 64 (1968) 2611. DOI:10.1039/tf968640261110.1039/tf9686402611Search in Google Scholar

[43] A.R. Miller, A.W. Searcy: J. Phys. Chem. 67 (1963) 2400. DOI:10.1021/j100805a03410.1021/j100805a034Search in Google Scholar

[44] A.S. Abbasov: PhD thesis, Thermodynamic and Electrical Properties of Some Semiconducting Materials, Extended Abstract of Doctoral (Chem.) Dissertation, Baku (1972).Search in Google Scholar

[45] N. Tatsumi, S. Toyoda, R. Shimpo, Y. Nakamura: J. Japan Inst. Metals. 55 (1991) 945. DOI:10.2320/jinstmet1952.55.9_94510.2320/jinstmet1952.55.9_945Search in Google Scholar

[46] H. Migge: J. Mater. Res. 6 (1991) 2381. DOI:10.1557/jmr.1991.238110.1557/jmr.1991.2381Search in Google Scholar

[47] H. Migge, J. Grzanna: J. Mater. Res. 9 (1994) 125. DOI:10.1557/JMR.1994.012510.1557/JMR.1994.0125Search in Google Scholar

[48] O. Kubaschewski, C.B. Alcock: Metallurgical Thermochemistry, Pergamon Press, Oxford, New York (1979). DOI:10.1002/9781118618974.ch110.1002/9781118618974.ch1Search in Google Scholar

[49] A.T. Dinsdale: Calphad 15 (1991) 317. DOI:10.1016/0364-5916(91)90030-N10.1016/0364-5916(91)90030-NSearch in Google Scholar

[50] B. Sundman, B. Jansson, J.O. Andersson: Calphad 9 (1985) 153. DOI:10.1016/0364-5916(85)90021-510.1016/0364-5916(85)90021-5Search in Google Scholar

Received: 2020-06-18
Accepted: 2021-02-17
Published Online: 2021-05-12
Published in Print: 2021-05-31

© 2021 Walter de Gruyter GmbH, Berlin/Boston, Germany

Downloaded on 19.3.2024 from https://www.degruyter.com/document/doi/10.1515/ijmr-2020-7951/html
Scroll to top button