Skip to content
BY-NC-ND 3.0 license Open Access Published by De Gruyter Open Access May 26, 2016

High temperature superconductivity in sulfur hydride under ultrahigh pressure: A complex superconducting phase beyond conventional BCS

  • Annette Bussmann-Holder , Jürgen Köhler , M.-H. Whangbo , Antonio Bianconi and Arndt Simon

Abstract

The recent report of superconductivity under high pressure at the record transition temperature of Tc =203 K in pressurized H2S has been identified as conventional in view of the observation of an isotope effect upon deuteration. Here it is demonstrated that conventional theories of superconductivity in the sense of BCS or Eliashberg formalisms cannot account for the pressure dependence of the isotope coefficient. The only way out of the dilemma is a multi-band approach of superconductivity where already small interband coupling suffices to achieve the high values of Tc together with the anomalous pressure dependent isotope coefficient. In addition, it is shown that anharmonicity of the hydrogen bonds vanishes under pressure whereas anharmonic phonon modes related to sulfur are still active.

References

[1] E. Zurek, R. Hoffmann, N. W. Ashcroft, A. R. Oganov, and A. O. Lyakhov, Proceedings of the National Academy of Sciences 106, 2009, 17640. 10.1073/pnas.0908262106Search in Google Scholar PubMed PubMed Central

[2] N.W. Ashcroft Physical Review Letters 92, 2004. 187002. 10.1103/PhysRevLett.92.187002Search in Google Scholar PubMed

[3] N.W. Ashcroft Symmetry and higher superconductivity in the lower elements. In (A. Bianconi, ed.) Symmetry and Heterogeneity in High Temperature Superconductors. vol. 214 of NATO Science Series II:Mathematics, Physics and Chemistry, 3-20, 2006. 10.1007/1-4020-3989-1_1Search in Google Scholar

[4] E. Babaev, A. Sudbo, N.W. Ashcroft, Nature 431, 2004, 666. 10.1038/nature02910Search in Google Scholar PubMed

[5] H. Shimizu, H. Yamaguchi, S. Sasaki, A. Honda, S. Endo, and M. Kobayashi, Phys. Rev. B 51, 1995, 9391. 10.1103/PhysRevB.51.9391Search in Google Scholar PubMed

[6] T. Ikeda, Phys. Rev. B 64, 2001, 104103. 10.1103/PhysRevB.64.104103Search in Google Scholar

[7] J. S. Loveday, R. J. Nelmes, S. Klotz, J. M. Besson, and G. Hamel, Phys. Rev. Lett. 85, 2000, 1024. Search in Google Scholar

[8] Y. Li, J. Hao, H. Liu, Y. Li, Y. Ma, The Journal of Chemical Physics 140, 2014, 174712. 10.1063/1.4874158Search in Google Scholar PubMed

[9] D. Duan, Y. Liu, F. Tian, D. Li, X. Huang, Z. Zhao, H. Yu, B. Liu, W. Tian, and T. Cui, Scientific Reports 4, 2014, 6968 http://dx.doi.org/10.1038/srep06968 10.1038/srep06968Search in Google Scholar PubMed PubMed Central

[10] A. P. Drozdov, M. I. Eremets, I. A. Troyan, V. Ksenofontov & S. I. Shylin, Nature 525, 2015, 73-76. 10.1038/nature14964Search in Google Scholar PubMed

[11] D. A. Papaconstantopoulos, B. M. Klein, M. J. Mehl, and W. E. Pickett, Physical Review B 91, 2015, 184511 http://dx.doi.org/ 10.1103/physrevb.91.184511 10.1103/PhysRevB.91.184511Search in Google Scholar

[12] I. Errea, M. Calandra, C.J. Pickard, J. Nelson, R.J. Needs, Y. Li, H. Liu, Y. Zhang, Y. Ma, F. Mauri, Phys. Rev. Lett. 114, 2015, 157004. 10.1103/PhysRevLett.114.157004Search in Google Scholar

[13] E. Cartlidge, Nature 524, 2015, 277. 10.1038/nature.2015.18191Search in Google Scholar

[14] A.P. Durajski, R. Szczesniak, Y. Li, Physica C 515, 2014, 1. Search in Google Scholar

[15] N. Bernstein, C.S. Hellberg, M.D. Johannes, I.I.Mazin, M.J. Mehl, Phys. Rev. B 91, 2015, 060511. 10.1103/PhysRevB.91.060511Search in Google Scholar

[16] “Superconductivity in Complex Systems”, (A. Bussmann- Holder. K.A. Muller eds) A. Bianconi, V.H Crespi, S, Deng, T. Egami, A. Furrer, O. Gunnarson et al. (A. Bussmann-Holder. K.A. Muller eds) Springer Series Structure and Bonding 114, Springer Verlag Berlin Heidelberg 2005 doi: 10.1007/b12231 10.1007/b12231Search in Google Scholar

[17] A. Bianconi, Solid State Communications 91, 1994, 1. 10.1016/0038-1098(94)90831-1Search in Google Scholar

[18] G. Campi, A. Bianconi, N. Poccia, et al. Nature 525, 2015, 359 10.1038/nature14987Search in Google Scholar PubMed

[19] J. P. Franck, J. Jung, M. A-K. Mohamed, S. Gygax, and G. I. Sproule, Phys. Rev. B 44, 1991, 5318; 10.1103/PhysRevB.44.5318Search in Google Scholar PubMed

[20] J. P. Franck, S. Harker, and J. H. Brewer, Phys. Rev. Lett. 71, 1993, 283 10.1103/PhysRevLett.71.283Search in Google Scholar PubMed

[21] A. Perali, D. Innocenti, A. Valletta, and A. Bianconi, Supercond. Sci. Technol. 25, 2012, 124002 10.1088/0953-2048/25/12/124002Search in Google Scholar

[22] Annette Bussmann-Holder, Hugo Keller, J. Phys.: Condensed Matter 24, 2012, 233201. 10.1088/0953-8984/24/23/233201Search in Google Scholar PubMed

[23] R. Khasanov, M. Bendele, A. Bussmann-Holder, and H. Keller, Phys. Rev. B 82, 2010, 212505. 10.1103/PhysRevB.82.212505Search in Google Scholar

[24] For a review see H. Keller, in ref. 16, p. 143 (2005). Search in Google Scholar

[25] A. Bianconi, M. Missori, H. Oyanagi, H. Yamaguchi, D.H. Ha, Y. Nishiara, S Della Longa EPL (Europhysics Letters) 31, 1995, 411. 10.1209/0295-5075/31/7/012Search in Google Scholar

[26] A. Bianconi, A. Valletta, A. Perali, N. L. Saini Solid State Communications 102, 1997, 369. 10.1016/S0038-1098(97)00011-2Search in Google Scholar

[27] A. Bianconi, D. Di Castro, S. Agrestini, G. Campi, N. L. Saini, A. Saccone, S. De Negri, M. Giovannini. Journal of Physics: Condensed Matter 13 (2001) 7383. 10.1088/0953-8984/13/33/318Search in Google Scholar

[28] A. Bussmann-Holder and A. Bianconi, Phys. Rev. B 67, 2003, 132509 10.1103/PhysRevB.67.132509Search in Google Scholar

[29] L. Simonelli, V. Palmisano, M. Fratini, M. Filippi, P. Parisiades, D. Lampakis, E. Liarokapis, and A. Bianconi, Phys. Rev. B 80, 2009, 014520 . 10.1103/PhysRevB.80.014520Search in Google Scholar

[30] S. Deng, A. Simon, J. Köhler, J. Supercond. 16, 2003, 477. 10.1023/A:1023804600927Search in Google Scholar

[31] D. Innocenti and A. Bianconi, J. Supercond. Nov. Magn. 26, 2013, 1319 10.1007/s10948-012-1857-xSearch in Google Scholar

[32] V.A. Moskalenko, Fiz. Metal. Metalloved. 8, 1959, 503. Search in Google Scholar

[33] H. Suhl, B.T. Matthias, L.R. Walker, Phys. Rev. Lett. 3, 1959, 552. 10.1103/PhysRevLett.3.552Search in Google Scholar

[34] G. M. Eliashberg, Sov. Phys. JETP 11, 1960, 696 Search in Google Scholar

[35] G. M. Eliashberg, Sov. Phys. JETP 12, 1961, 1000. Search in Google Scholar

[36] P. B. Allen, R. C. Dynes, Phys. Rev. B 12, 1975, 905. 10.1103/PhysRevB.12.905Search in Google Scholar

[37] M. Einaga, M. Sakata, T. Ishikawa, K. Shimizu, M. Eremets, A. Drozdov, I. Troyan, N. Hirao, Y. Ohishi, Nature Physics (2016) doi: 10.1038/nphys3760; preprint 2015 arXiv:1509.03156. Search in Google Scholar

[38] T. Jarlborg and A. Bianconi, Sci. Rep. 6, 2016, 24816; doi: 10.1038/srep24816 10.1038/srep24816Search in Google Scholar PubMed PubMed Central

[39] A. Bianconi and T. Jarlborg, EPL (Europhys. Lett.) 112, 2015, 37001 10.1209/0295-5075/112/37001Search in Google Scholar

[40] A. Bianconi and T. Jarlborg, Novel Supercond.Materials 1, 2015, 37 10.1515/nsm-2015-0006Search in Google Scholar

[41] L. P. Gor’kov and V. Z. Kresin, Scientific Reports 6, 2016, 25608 10.1038/srep25608Search in Google Scholar PubMed PubMed Central

[42] S. Deng, J. Köhler, and A. Simon, Angew. Chem. 45, 2006, 599 10.1002/anie.200502673Search in Google Scholar PubMed

[43] R. Caivano, M. Fratini, N. Poccia, et al.. Superconductor Science and Technology 22, 2008, 014004 10.1088/0953-2048/22/1/014004Search in Google Scholar

[44] A. Simon, Phil. Trans. R. Soc. A 373, 2015, 20140192 10.1098/rsta.2014.0192Search in Google Scholar PubMed

[45] E. E. Gordon, K. Xu, H. Xiang, A. Bussmann-Holder, R. K. Kremer, A. Simon, J. Köhler and M.-H. Whangbo, Angew. Chem. Int. Ed. Engl. 55, 2016, 1. 10.1002/anie.201511347Search in Google Scholar PubMed

[46] A. Bussmann-Holder and A. R. Bishop, Phys. Rev. B 44, 1991, 2853. 10.1103/PhysRevB.44.2853Search in Google Scholar PubMed

[47] K. Kuroki, T. Higashida, and R. Arita, Phys. Rev. B 72, 2005, 212509 10.1103/PhysRevB.72.212509Search in Google Scholar

[48] A. Bianconi, Journal of Superconductivity 18, 2005, 625 10.1007/s10948-005-0047-5Search in Google Scholar

[49] A. Bianconi, Iranian Journal of Physics Research 6, 2006, 139 Search in Google Scholar

[50] M. J. S. Dewar, Angew. Chem. Int. Ed. Engl. 26, 1987, 1273. Search in Google Scholar

[51] J. A. Morrone, Lin Lin, and R. Car, J. Chem. Phys. 130, 2009, 204511. 10.1063/1.3142828Search in Google Scholar PubMed

[52] A. Bussmann-Holder, J. Phys.: Condens. Matter 24, 2012, 273202 doi:10.1088/0953-8984/24/27/273202]. 10.1088/0953-8984/24/27/273202Search in Google Scholar PubMed

[53] A. Bianconi International Journal of Modern Physics B 14, 2000, 3289 10.1142/S0217979200003769Search in Google Scholar

[54] K.I. Kugel, A.L. Rakhmanov, A.O. Sboychakov, et al. Physical Review B 78, 2008, 165124. 10.1103/PhysRevB.78.155113Search in Google Scholar

[55] G. Campi, A. Bianconi, Journal of Superconductivity and Novel Magnetism 29, 2016, 627. doi: 10.1007/s10948-015-3326-9. 10.1007/s10948-015-3326-9Search in Google Scholar

[56] A. Bianconi, N. Poccia, A. O. Sboychakov, A. L. Rakhmanov, and K. I. Kugel, Superconductor Science and Technology 28, 2015, 024005 doi:10.1088/0953-2048/28/2/024005. 10.1088/0953-2048/28/2/024005Search in Google Scholar

[57] G. Campi, D. Innocenti, and A. Bianconi, Journal of Superconductivity and NovelMagnetism28, 2015,1355 doi: 10.1007/s10948- 015-2955-3. Search in Google Scholar

Received: 2016-5-3
Accepted: 2016-5-13
Published Online: 2016-5-26

©2016 Annette Bussmann-Holder et al.

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Downloaded on 29.11.2023 from https://www.degruyter.com/document/doi/10.1515/nsm-2016-0004/html
Scroll to top button