Abstract
We studied the effect of poly-N-vinylpyrrolidone (PVP) and its concentrations on the photoinduced formation of silver nanoparticles (Ag NPs) as well as Ag-polymer nanocomposites. First, the effect of PVP concentration on the photoinduced reduction of Ag nitrate (AgNO3) in solution was studied by UV-Vis absorption spectroscopy monitoring the plasmon band of Ag. Dynamic light scattering (DLS) results showed that Ag NPs formed in the presence of stabilizer up to 4 wt% were narrower; the size distribution was also narrower. The PVP also had a significant influence on the formation of polymer nanocomposites by simultaneous photoinduced synthesis of NPs and polymerization of the acrylic matrix; NPs embedded in the crosslinked polymer were well dispersed, as detected by field-emission scanning electron microscopy (FESEM), and showed an average diameter of 20 nm.
Acknowledgements
The authors would like to acknowledge the Higher Education Commission (HEC) of Pakistan for financing the PhD scholarship of Rabia Nazar.
References
[1] Chang LT, Yen CC. J. Appl. Polym. Sci. 1995, 55, 371–374.10.1002/app.1995.070550219Search in Google Scholar
[2] Shanmugam S, Viswanathan B, Varadarajan TK. J. Mol. Catal: A. 2005, 241, 52–58.10.1016/j.molcata.2005.06.063Search in Google Scholar
[3] Lin WC, Yang MC. Macromol. Rapid Commun. 2005, 26, 1942–1947.10.1002/marc.200500597Search in Google Scholar
[4] Brust M, Walker M, Bethell D, Schiffrin D, Whyman R. J. Chem. Soc., Chem. Comm. 1994, 7, 801–802.10.1039/C39940000801Search in Google Scholar
[5] Jana NR, Gearheart L, Murphy CJ. J. Phys. Chem. B. 2001, 105, 4065–4067.10.1021/jp0107964Search in Google Scholar
[6] Thomas KG, Kamat PV. Acc. Chem. Res. 2003, 36, 888–898.10.1021/ar030030hSearch in Google Scholar PubMed
[7] Gadubert VJ, Lennox RB. Langmuir 2005, 21, 6532–6539.10.1021/la050195uSearch in Google Scholar PubMed
[8] Mandal M, Ghosh SK, Kundun S, Esumi K, Pal T. Langmuir 2002, 18, 7792–7797.10.1021/la0118107Search in Google Scholar
[9] Esumi K, Matsumoto T, Seto Y, Yoshimura T. J. Colloid Interface Sci. 2005, 284, 199–203.10.1016/j.jcis.2004.09.020Search in Google Scholar PubMed
[10] Majima T, Sakamoto M, Tachikawa T, Fujitsuk M. Chem. Phys. Lett. 2006, 420, 90–94.10.1016/j.cplett.2005.12.053Search in Google Scholar
[11] Durmaz YY, Tasdelen MA, Aydogan B, Kahveci MU, Yagci Y. In New Smart Materials via Metal Mediated Macromolecular Engineering, Khosravi, E, Yagci, Y, Savelyev, Y, Eds., Springer: Netherlands, 2009, pp 329–341.10.1007/978-90-481-3278-2_22Search in Google Scholar
[12] Malina D, Sobczak A, Wzorek Z, Kowalski Z. Dig. J. Nanomater. Biostruct. 2012, 7, 1527–1534.Search in Google Scholar
[13] Carotenuto G. Appl. Organomet. Chem. 2001, 15, 344–351.10.1002/aoc.165Search in Google Scholar
[14] Bera T, Ramachandrarao P. J. Mater. Sci. 2009, 44, 2264–2270.10.1007/s10853-008-2861-1Search in Google Scholar
[15] Kan C, Wang J, Zhu H, Li H. J. Solid State Chem. 2010, 183, 858–865.10.1016/j.jssc.2010.01.021Search in Google Scholar
[16] Wang H, Qiao X, Chen J, Wang X, Ding S. Mater. Chem. Phys. 2005, 94, 449–453.10.1016/j.matchemphys.2005.05.005Search in Google Scholar
[17] Roucoux J, Schulz H, Patin H. Chem. Rev. 2002, 102, 3757–3778.10.1021/cr010350jSearch in Google Scholar PubMed
[18] Esumi K, Ishizuki N, Torigoe K, Nakamura H, Meguro K. Appl. Poly. Sci. 1992, 44, 1003–1007.10.1002/app.1992.070440609Search in Google Scholar
[19] Huang HH, Ni XP, Loy GL, Chew CH, Tan KL, Loh FC, Deng JF, Xu GQ. Langmuir 1996, 12, 909–912.10.1021/la950435dSearch in Google Scholar
[20] Mallick K, Witcomb MJ, Scurrell MS. J. Mat. Sci. 2004, 39, 4459–4463.10.1023/B:JMSC.0000034138.80116.50Search in Google Scholar
[21] Breimer MA, Yevgeny G, Sy S, Sadik OA. Nano Lett. 2001, 1, 305–308.10.1021/nl015528wSearch in Google Scholar
[22] Yang X, Lu Y. Mater. Lett. 2005, 59, 2484–2487.10.1016/j.matlet.2005.03.033Search in Google Scholar
[23] Russel TP, Emrick T, Balazs AC. Science 2006, 314, 1107–1110.10.1126/science.1130557Search in Google Scholar PubMed
[24] Thomas V, Namdeo M, Murali MY, Bajpai SK, Bajpai M. J. Macromol. Sci. Pure Appl. Chem. A 2008, 45, 107–119.10.1080/10601320701683470Search in Google Scholar
[25] Chiolerio A, Sangermano M. Mater. Sci. Eng. B. 2012, 177, 373–380.10.1016/j.mseb.2011.12.029Search in Google Scholar
[26] Chiolerio A, Roppolo I, Sangermano M. RSC Adv. 2013, 3, 3446–3452.10.1039/c3ra22159hSearch in Google Scholar
[27] Sangermano M, Chiolerio A. Nanoparticles Featuring Electromagnetic Properties: from Science to Engineering, Research Signpost: Trivandurum, India, 2012, pp 85–8104.Search in Google Scholar
[28] Sangermano M, Yagci Y, Rizza G. Macromolecules 2007, 40, 8827–8829.10.1021/ma702051gSearch in Google Scholar
[29] Yagci Y, Sangermano M, Rizza G. Polymer 2008, 49, 5195–5198.10.1016/j.polymer.2008.09.068Search in Google Scholar
[30] Sangermano M, Roppolo I, Alves Camara VH, Dizman C, Ates S, Torun L, Yagci Y. Macromol. Mater. Eng. 2011, 296, 820–825.10.1002/mame.201000440Search in Google Scholar
[31] Nazar R, Ronchetti S, Roppolo I, Sangermano S, Bongiovanni R. Macromol. Mater. Eng. 2014, 300, 226–233.10.1002/mame.201400204Search in Google Scholar
[32] Vescovo L, Sangermano M, Scarazzini R, Kortaberria G, Mondragon I. Macromol. Chem. Phys. 2010, 211, 1933–1939.10.1002/macp.201000138Search in Google Scholar
[33] Papp S, Patakfalvi R, Dékánya I. Croatica Chemica Acta Ccaca 2007, 80, 493–502.Search in Google Scholar
[34] Kothapalle S, Koramala NK, Naresh V, Srinivasa B. Mater. Sci. Appl. 2011, 2, 1688–1696.Search in Google Scholar
[35] Priola A, Gozzelino G, Ferrero F, Malucelli G. Polymer 1993, 34, 3653–3657.10.1016/0032-3861(93)90050-KSearch in Google Scholar
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