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Licensed Unlicensed Requires Authentication Published by De Gruyter July 6, 2016

Ozonation in water treatment: the generation, basic properties of ozone and its practical application

  • Chaohai Wei

    Chaohai Wei obtained his Bachelor’s degree in Applied Chemistry from China University of Geosciences and his Master’s degree in Environmental Engineering from Harbin Institute of Technology. He completed his PhD in Chemical Engineering at South China University of Technology (SCUT) and was promoted as a professor in SCUT by 1999. Prof. Wei has presided over 103 research projects and published over 390 peer-reviewed papers. Profoundly, he has designed over 30 practical projects serving for actual wastewater treatment plants. His research interests are pollution control theories in industrial wastewater and river basin, particularly focusing on novel reactors and processes for wastewater treatment, energy saving and energy recovery from wastewater treatment, and integration and optimization of wastewater treatment systems.

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    , Fengzhen Zhang

    Fengzhen Zhang graduated from Shenzhen University with a Master’s degree in Applied Chemistry in 2013 and from Northwest University for Nationalities with a Bachelor’s degree in Chemical Engineering and Technology in 2010. He joined South China University of Technology as a doctoral candidate in 2013 under Prof. Wei’s supervision. His research interests focus on catalytic ozonation of industrial wastewater and high-performance ozonation reactor. He has obtained a National Scholarship for Postgraduates and is the winner of Environmental Science: Processes & Impacts oral prize during the 8th National Conference on Environmental Chemistry.

    , Yun Hu

    Yun Hu obtained her PhD degree in Applied Chemistry from Osaka Prefecture University in 2006. She was elected as an Outstanding Young Teacher in the Hundred Talents Program by South China University of Technology (SCUT) in 2007, after 2 years serving as Research Fellow in Japan Society for the Promotion of Science. She is now a professor in SCUT, concentrating on the pollution control and resource recovery from contaminated water or air by means of photocatalysis and adsorption. Prof. Hu has published over 50 papers, including two recent research articles in Applied Catalysis B: Environmental.

    , Chunhua Feng

    Chunhua Feng graduated with a PhD degree in Chemical Engineering from Hong Kong University of Science and Technology in 2007. Dr. Feng is now a professor at School of Environment and Engineering, South China University of Technology (SCUT), China. He is serving as an associate director for Center of Environment Science, SCUT. He was elected in Program for New Century excellent talents in University, Ministry of Education, China (2012). His research interests lie in energy/resource recovery from wastes and bioelectrochemical technology for wastewater treatment.

    and Haizhen Wu

    Haizhen Wu obtained her PhD degree in Biological Engineering from South China University of Technology (SCUT) in 2008. She is currently an associate professor in School of Bioscience and Bioengineering, SCUT. Her research interests are concentrated on the biodegradation of pollutants in contaminated soil as well as wastewater, the identification of functional micro-organisms and the development of high-performance bio-reactors. She has published more than 40 peer-reviewed papers and presided twice over the National Natural Science Foundations of China.

Abstract

The widespread applications of ozone technologies are established on the basis of large-scale manufacture of ozone generator and chemical reactivity of ozone. It is hence necessary to summarize the principles of ozone generation and to analyze the physicochemical properties of ozone, which are of fundamental significance to indicate its technical developments and practical applications. This review presents a summary concerning ozone generation mechanisms, the physicochemical properties of ozone, as well as the applications of ozone in water treatment. Ozone can be produced by phosphorus contact, silent discharge, photochemical reactions, and electrochemical reactions, principally proceeding by the reaction of oxygen atom with oxygen molecule. There are side reactions to the generation of ozone, however, which are responsible for ozone depletion including thermal decomposition and quenching reactions by reactive species. The solubility of ozone in water is much higher than that of oxygen, suggesting that it may be reliably applied in water and wastewater treatment. Based on the resonance structures of ozone, one oxygen atom in ozone molecule is electron-deficient displaying electrophilic property, whereas one oxygen atom is electron-rich holding nucleophilic property. The superior chemical reactivity of ozone can also be indirectly revealed by radical-mediated reactions initiated from homogenous and heterogeneous catalytic decomposition of ozone. Owing to the reliable generation of ozone and its robust reactive properties, it is worthy to thoroughly elaborate the applications of ozone reaction in drinking water disinfection and pre- or post-treatment of industrial wastewater including cyanide wastewater, coking wastewater, dyeing wastewater, and municipal wastewater. The structural characteristics of ozone reactors and energy requirement of applied technologies are evaluated. In addition, future directions concerning the development of ozone generation, ozone reactivity, and industrial wastewater ozonation have been proposed.

Award Identifier / Grant number: U1201234

Award Identifier / Grant number: 51278199

Award Identifier / Grant number: 21037001

Funding statement: We gratefully acknowledge the financial support from the National Natural Science Foundation of China (nos. U1201234, 51278199, 21037001) and the Research Project of Production, Education and Research of Guangdong Province, China (nos. 2012B091100450, 2013ZP0017).

About the authors

Chaohai Wei

Chaohai Wei obtained his Bachelor’s degree in Applied Chemistry from China University of Geosciences and his Master’s degree in Environmental Engineering from Harbin Institute of Technology. He completed his PhD in Chemical Engineering at South China University of Technology (SCUT) and was promoted as a professor in SCUT by 1999. Prof. Wei has presided over 103 research projects and published over 390 peer-reviewed papers. Profoundly, he has designed over 30 practical projects serving for actual wastewater treatment plants. His research interests are pollution control theories in industrial wastewater and river basin, particularly focusing on novel reactors and processes for wastewater treatment, energy saving and energy recovery from wastewater treatment, and integration and optimization of wastewater treatment systems.

Fengzhen Zhang

Fengzhen Zhang graduated from Shenzhen University with a Master’s degree in Applied Chemistry in 2013 and from Northwest University for Nationalities with a Bachelor’s degree in Chemical Engineering and Technology in 2010. He joined South China University of Technology as a doctoral candidate in 2013 under Prof. Wei’s supervision. His research interests focus on catalytic ozonation of industrial wastewater and high-performance ozonation reactor. He has obtained a National Scholarship for Postgraduates and is the winner of Environmental Science: Processes & Impacts oral prize during the 8th National Conference on Environmental Chemistry.

Yun Hu

Yun Hu obtained her PhD degree in Applied Chemistry from Osaka Prefecture University in 2006. She was elected as an Outstanding Young Teacher in the Hundred Talents Program by South China University of Technology (SCUT) in 2007, after 2 years serving as Research Fellow in Japan Society for the Promotion of Science. She is now a professor in SCUT, concentrating on the pollution control and resource recovery from contaminated water or air by means of photocatalysis and adsorption. Prof. Hu has published over 50 papers, including two recent research articles in Applied Catalysis B: Environmental.

Chunhua Feng

Chunhua Feng graduated with a PhD degree in Chemical Engineering from Hong Kong University of Science and Technology in 2007. Dr. Feng is now a professor at School of Environment and Engineering, South China University of Technology (SCUT), China. He is serving as an associate director for Center of Environment Science, SCUT. He was elected in Program for New Century excellent talents in University, Ministry of Education, China (2012). His research interests lie in energy/resource recovery from wastes and bioelectrochemical technology for wastewater treatment.

Haizhen Wu

Haizhen Wu obtained her PhD degree in Biological Engineering from South China University of Technology (SCUT) in 2008. She is currently an associate professor in School of Bioscience and Bioengineering, SCUT. Her research interests are concentrated on the biodegradation of pollutants in contaminated soil as well as wastewater, the identification of functional micro-organisms and the development of high-performance bio-reactors. She has published more than 40 peer-reviewed papers and presided twice over the National Natural Science Foundations of China.

Acknowledgments

We gratefully acknowledge the financial support from the National Natural Science Foundation of China (nos. U1201234, 51278199, 21037001) and the Research Project of Production, Education and Research of Guangdong Province, China (nos. 2012B091100450, 2013ZP0017).

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Received: 2016-2-10
Accepted: 2016-5-18
Published Online: 2016-7-6
Published in Print: 2017-2-1

©2017 Walter de Gruyter GmbH, Berlin/Boston

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