Abstract
To explore options for simple, safe, and compact chemical reactors that preserve wanted metastable initial products from sequential unwanted reactions, academic and industrial researchers have tried to repurpose reciprocating piston equipment or an “engine-like” design to be used as a chemical reactor. Piston reactors offer the benefit of achieving very high temperature and pressure conditions at very short and defined residence times. Such conditions offer promise for enhanced performance for several chemical conversions. This paper provides a review of the published literature and patents in the field of piston reactors to provide an overview of the current state-of-the-art. The review covers multiple aspects of piston reactors and their applications, reactor design options and their operation, catalyst and ignition placement, tested reactions, experimental setups as well as modeling and simulation. Several research gaps are highlighted as a motivation for future research in the field. To help interested readers into the topic, basic concepts and fundamentals of piston reactors are provided.
Funding source: Qatar National Research Fund doi.org/10.13039/100008982
Award Identifier / Grant number: NPRP12S-0304-190222
Acknowledgments
We would like to thanks Dr. Herman Kuipers for the fruitful discussion and valuable comments during the entire period of the manuscript writing process. The statements made herein are solely the responsibility of the author(s).
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Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
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Research funding: This work was made possible by funding from the Qatar National Research Fund (QNRF) project no. NPRP12S-0304-190222 and co-funding by Shell Global Solutions International B.V.
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Conflict of interest statement: The authors declare no conflicts of interest regarding this article.
References
Al-Sayari, S.A. (2013). Recent developments in the partial oxidation of methane to syngas. Open Catal. J. 6: 17–28, https://doi.org/10.2174/1876214x20130729001.Search in Google Scholar
Acocella, A., Bromberg, L., Lim, E., Eethamraju, S., Green, W., Cedrone, K., and Cohn, D. (2014). Proceedings of the ASME 2014 8th international conference on energy sustainability, June 30–July 2, 2014. Boston, Massachusetts.Search in Google Scholar
Alagumalai, A. (2014). Internal combustion engines: progress and prospects. Renew. Sustain. Energy Rev. 38: 561–571, https://doi.org/10.1016/j.rser.2014.06.014.Search in Google Scholar
Anderson, D.M., Kottke, P.A., and Fedorov, A.G. (2014). Thermodynamic analysis of hydrogen production via sorption-enhanced steam methane reforming in a new class of variable volume batch-membrane reactor. Int. J. Hydrogen Energy 39: 1–13, https://doi.org/10.1016/j.ijhydene.2014.03.127.Search in Google Scholar
Anderson, D.M., Nasr, M.H., Yun, T.M., Kottke, P.A., and Fedorov, A.G. (2015). Sorption-enhanced variable-volume batch-membrane steam methane reforming at low temperature: experimental demonstration and kinetic modeling. Ind. Eng. Chem. Res. 54: 8422–8436, https://doi.org/10.1021/acs.iecr.5b01879.Search in Google Scholar
Anderson, D.M., Yun, T.M., Kottke, P.A., and Fedorov, A.G. (2017). Comprehensive analysis of sorption enhanced steam methane reforming in a variable volume membrane reactor. Ind. Eng. Chem. Res. 56: 1758–1771, https://doi.org/10.1021/acs.iecr.6b04392.Search in Google Scholar
Aramouni, N.A.K., Touma, J.G., Tarboush, B.A., Zeaiter, J., and Ahmad, M.N. (2018). Catalyst design for dry reforming of methane: analysis review. Renew. Sustain. Energy Rev. 82: 2570–2585, https://doi.org/10.1016/j.rser.2017.09.076.Search in Google Scholar
Atakan, B., Kaiser, S.A., Herzler, J., Porras, S., Banke, K., Deutschmann, O., Kasper, T., Fikri, M., Schie, R., Schr, D., et al.. (2020). Flexible energy conversion and storage via high-temperature gas-phase reactions: the piston engine as a polygeneration reactor. Renew. Sustain. Energy Rev. 113: 110264, https://doi.org/10.1016/j.rser.2020.110264.Search in Google Scholar
Banke, K., Hegner, R., Schröder, D., Schulz, C., Atakan, B., and Kaiser, S.A. (2019). Power and syngas production from partial oxidation of fuel-rich methane/DME mixtures in an HCCI engine. Fuel 243: 97–103, https://doi.org/10.1016/j.fuel.2019.01.076.Search in Google Scholar
Barber, M. and Falls, W. (1952). Internal-combustion engine production of synthesis gas, US patent 2,605,175.Search in Google Scholar
Beale, W.T. and Kopko, W.I. (2000). Free-piston internal combustion engine, US patent 6,035,637.Search in Google Scholar
Van Blarigan, P. (2001). Free-piston engine, US patent 6,199,519 B1.Search in Google Scholar
Bowman, M.J., Balan, C., Colibaba-Evulet, A., and Ramesh, N. (2008). Method and system for producing hydrogen by reforming hydrogen-containing gas, US patent 7,384,620 B2.Search in Google Scholar
Broeze, J. and Van Dijck, W. (1957). Method and reciprocating compression reactor for short period, high temperature and high pressure chemical reactions, US patent 2,814,551.Search in Google Scholar
Bromberg, L., Green, W.H., Sappok, A., Cohn, D.R., and Amrit, J. (2013). Engine reformer systems for lower cost, smaller scale manufacturing of liquid fuels, Patent WO 2013/158374 A.Search in Google Scholar
Bromberg, L., Green, W.H., Sappok, A., Cohn, D.R., and Amrit, J. (2018). Engine reformer systems for lower cost, smaller scale manufacturing of liquid fuels, US patent 9,909,491 B2.Search in Google Scholar
Bromberg, L., Sappok, A., Brisson, J.G., and Green, W.H. (2014). Engine chemical reactor with catalyst, International publication number W O 2014/209796 A l. Patent 2014/0374660 A1.Search in Google Scholar
Browne, J. (2019). A techno-economic & environmental analysis of a novel technology utilizing an internal combustion engine as a compact, inexpensive micro-reformer for a distributed gas-to-liquids system, Ph.D. thesis. New York, USA, Columbia University.Search in Google Scholar
Brownlee, R. and Uhlinger, R. (1914). Process of making carbon monoxide, hydrogen, and nitrogen, US patent 1,107,581.Search in Google Scholar
Cassidy, J.F. (1977). Emissions and total energy consumption of a multicylinder piston engine running on gasoline and a hydrogen-gasoline mixture. Technical Report 19770016170, National Aeronautics and Space Administration.Search in Google Scholar
Caton, J.A. (2015). An introduction to thermodynamic cycle simulations for internal combustion engines. John Wiley & Sons Ltd, West Sussex, United Kingdom.10.1002/9781119037576Search in Google Scholar
Chen, J., Liu, B., Gao, X., and Xu, D. (2016). Experimental and numerical investigation of hetero-/homogeneous combustion-based HCCI of methane-air mixtures in free-piston micro-engines. Energy Convers. Manag. 119: 227–238, https://doi.org/10.1016/j.enconman.2016.04.055.Search in Google Scholar
Damm, D.L. and Fedorov, A.G. (2008). Comparative assessment of batch reactors for scalable hydrogen production. Ind. Eng. Chem. Res. 47: 4665–4674, https://doi.org/10.1021/ie800294y.Search in Google Scholar
Damm, D.L. and Fedorov, A.G. (2009). Batch reactors for hydrogen production: theoretical analysis and experimental characterization. Ind. Eng. Chem. Res. 48: 5610–5623, https://doi.org/10.1021/ie8015126.Search in Google Scholar
Eastman, D., Scarsdale, B., Barber, E.M., Wappinger, F.N.Y., Reybolds, B., and Montclair (1952). Process for the manufacture of synthesis gas, US patent 2,591,687.Search in Google Scholar
Evans, E., Ford, H., and Moore, N. (1955). Partial oxidation and pyrolysis of saturated hydrocarbons, US patent 2,727,933.Search in Google Scholar
Ezdin, B.S., Yatsenko, D.A., Kalyada, V.V., Ichshenko, A.B., Zarvin, A.E., Nikiforov, A.A., and Snytnikov, P.V. (2020). Pyrolysis of a mixture of monosilane and alkanes in a compression reactor to produce nanodispersed silicon carbide. Chem. Eng. J. 381: 122642, https://doi.org/10.1016/j.cej.2019.122642.Search in Google Scholar
Federov, A. and Damm, D. (2016). Hydrogen-generating reactors and methods, US patent 9,403,143 B2.Search in Google Scholar
Geicor, R.C. (1994). Method of producting carbon black. ACM SIGGRAPH Comput. Graph. 28: 131–134.Search in Google Scholar
Glouchenkov, M. and Kronberg, A. (1999). Pulsed compression: advanced technology for synthesis gas production. Technical Report, Energy Conversion Technologies.Search in Google Scholar
Glouchenkov, M., and Kronberg, A. (2006). Pulsed compression technology: a breakthrough in the production of hydrogen. 16th world hydrogen energy conference 2006, Lyon, France, pp. 1–7.Search in Google Scholar
Glushenkov, M. (1997). Apparatus for pulse compression of gases, Patent RU2097121C1.Search in Google Scholar
Glushenkov, M., Kronberg, A., Knoke, T., and Kenig, E.Y. (2018). Isobaric expansion engines: new opportunities in energy conversion for heat engines, pumps and compressors. Energies 11: 154, https://doi.org/10.3390/en11010154.Search in Google Scholar
Goldsborough, S.S., Hochgreb, S., Vanhove, G., Wooldridge, M.S., Curran, H.J., and Sung, C.J. (2017). Advances in rapid compression machine studies of low- and intermediate-temperature autoignition phenomena. Prog. Energy Combust. Sci. 63: 1–78, https://doi.org/10.1016/j.pecs.2017.05.002.Search in Google Scholar
Gossler, H. and Deutschmann, O. (2015a). Numerical optimization and reaction flow analysis of syngas production via partial oxidation of natural gas in internal combustion engines. Int. J. Hydrogen Energy 40: 11046–11058, https://doi.org/10.1016/j.ijhydene.2015.06.125.Search in Google Scholar
Gossler, H. and Deutschmann, O. (2015b). Syngas production in piston engines – operating conditions proposed by numerical optimization. Proceedings of the European combustion meeting. Budapest, Hungary, pp. 1–5.Search in Google Scholar
Gossler, H., Drost, S., Porras, S., Schießl, R., Maas, U., and Deutschmann, O. (2019). The internal combustion engine as a CO2 reformer. Combust. Flame 207: 186–195, https://doi.org/10.1016/j.combustflame.2019.05.031.Search in Google Scholar
Gudlavalleti, S., Michael, B., Balan, C., Singh Bhaisora, S., Colibaba-Evulet, A., and Ramesh, N. (2009). Method and article for producing hydrogen gas, US patent 7,572,432 B2.Search in Google Scholar
Guo, X., Fang, G., Li, G., Ma, H., Fan, H., Yu, L., Ma, C., Wu, X., Deng, D., Wei, M., et al.. (2014). Direct, nonoxidative conversion of methane to ethylene, aromatics, and hydrogen. Science 344: 616–619, https://doi.org/10.1126/science.1253150.Search in Google Scholar PubMed
Hashemi, H., Christensen, J.M., Gersen, S., Levinsky, H., Klippenstein, S.J., and Glarborg, P. (2016). High-pressure oxidation of methane. Combust. Flame 172: 349–364, https://doi.org/10.1016/j.combustflame.2016.07.016.Search in Google Scholar
Hausser, F. (1910). Process of making nitric acid, US patent 961,350.Search in Google Scholar
Hausser, F. (1911). Process of making nitric oxide, US patent 1,000,732.Search in Google Scholar
Hegner, R. and Atakan, B. (2017). A polygeneration process concept for HCCI-engines – modeling product gas purification and exergy losses. Int. J. Hydrogen Energy 42: 1287–1297, https://doi.org/10.1016/j.ijhydene.2016.09.050.Search in Google Scholar
Hegner, R., Werler, M., Schießl, R., Maas, U., and Atakan, B. (2017). Fuel-rich HCCI engines as chemical reactors for polygeneration: a modeling and experimental study on product species and thermodynamics. Energy Fuels 31: 14079–14088, https://doi.org/10.1021/acs.energyfuels.7b02150.Search in Google Scholar
Herwig, O. (1958). Internal combustion engine for the production Oo synthesis gas, US patent 2,846,297.Search in Google Scholar
Hirsch, J.H. (1951). Production of gas comprising hydrogen and carbon monoxide, US patent 2,578,475.Search in Google Scholar
Holmen, A. (2009). Direct conversion of methane to fuels and chemicals. Catal. Today 142: 2–8, https://doi.org/10.1016/j.cattod.2009.01.004.Search in Google Scholar
Humphery, H.A. (1922). Apparatus for producing nitric oxide, US patent 1,429,035.Search in Google Scholar
Iulianelli, A., Ribeirinha, P., Mendes, A., and Basile, A. (2014). Methanol steam reforming for hydrogen generation via conventional and membrane reactors: a review. Renew. Sustain. Energy Rev. 29: 355–368, https://doi.org/10.1016/j.rser.2013.08.032.Search in Google Scholar
Karim, G.A. and Moore, N.P.W. (1990a). Examination of rich mixture operation of a dual fuel engine. Technical Paper 901500, SAE Technical Papers.10.4271/901500Search in Google Scholar
Karim, G.A. and Moore, N.P.W. (1990b). The production of hydrogen by the partial oxidation of methane in a dual fuel engine. Technical Paper 901501, SAE Technical Papers.10.4271/901501Search in Google Scholar
Karim, G.A. and Wierzba, I. (2008). The production of hydrogen through the uncatalyzed partial oxidation of methane in an internal combustion engine. Int. J. Hydrogen Energy 33: 2105–2110, https://doi.org/10.1016/j.ijhydene.2008.01.051.Search in Google Scholar
Kosaka, K. and Ueno, Z. (1977). Method and apparatus for generating reformed gas containing hydrogen and carbon monoxide from hydrocarbon fuel, US patent 4,059,076.Search in Google Scholar
Kronberg, A. (2012). Pulsed compression reactor for nanoparticles manufacturing. Energy Conversion Technologies, Available at: <http://www.encontech.nl/papers/Nanoparticlesmanufacturing.pdf>.Search in Google Scholar
Kruis, F.E., Fissan, H., and Peled, A. (1998). Synthesis of nanoparticles in the gas phase for electronic, optical and magnetic applications – a review. J. Aerosol Sci. 29: 511–535, https://doi.org/10.1016/s0021-8502(97)10032-5.Search in Google Scholar
Lagally, C., Reynolds, C., Grieshop, A., Kandlikar, M., and Rogak, S.N. (2012). Carbon nanotube and fullerene emissions from spark-ignited engines. Aerosol. Sci. Technol. 46: 156–164, https://doi.org/10.1080/02786826.2011.617399.Search in Google Scholar
Lewis, G. (2017). Carbon nanotube production method to stimulate soil microorganisms and plant growth produced from the emissions of internal combustion, US patent 9,717,186 B2.Search in Google Scholar
Lim, E.G., Dames, E.E., Cedrone, K.D., Acocella, A.J., Needham, T.R., Arce, A., Cohn, D.R., Bromberg, L., Cheng, W.K., and Green, W.H. (2016). The engine reformer: syngas production in an engine for compact gas-to-Liquids synthesis. Can. J. Chem. Eng. 94: 623–635, https://doi.org/10.1002/cjce.22443.Search in Google Scholar
Lim, M.S., Hong, M.S., and Chun, Y.N. (2009). Production of synthesis gas from methane using compression ignition reformer. Kor. J. Chem. Eng. 26: 1022–1027, https://doi.org/10.1007/s11814-009-0170-2.Search in Google Scholar
Lissianski, V.V. and Klingbeil, A.E. (2019). System for generating an improved H2:CO ratio in syngas and an associated method thereof, US patent 10,465,631 B2.Search in Google Scholar
Longwell, P.A., Reamer, H.H., Wilburn, N.P., and Sage, B.H. (1958). Ballistic piston for investigating gas phase reactions. Ind. Eng. Chem. 50: 603–610, https://doi.org/10.1021/ie50580a027.Search in Google Scholar
López, E.J. and Nigro, N.M. (2010). Validation of a 0D/1D computational code for the design of several kind of internal combustion engines. Lat. Am. Appl. Res. 40: 175–184.Search in Google Scholar
Lowther, F.E. and Bohon, W.M. (1990). Integrated product generation and catalytic product synthesis in an engine-reactor, US patent 4,965,052. US patent 4,965,052.Search in Google Scholar
Lunsford, J.H. (2000). Catalytic conversion of methane to more useful chemicals and fuels: a challenge for the 21st century. Catal. Today 63: 165–174, https://doi.org/10.1016/s0920-5861(00)00456-9.Search in Google Scholar
Martin, M.D. (1978). Gaseous automotive fuels from steam reformed liquid hydrocarbons. Technical Paper 780457, SAE Technical Papers.10.4271/780457Search in Google Scholar
Matsumura, Y. and Nakamori, T. (2004). Steam reforming of methane over nickel catalysts at low reaction temperature. Appl. Catal. Gen. 258: 107–114, https://doi.org/10.1016/j.apcata.2003.08.009.Search in Google Scholar
McCall, D.M., Lalk, T.R., Davison, R.R., and Hariss, W.B. (1985). Performance and emissions characteristics of a spark ignition engine Fueled with Dissociated and steam-reformed methanol. Technical Paper 852106, SAE Technical Papers.10.4271/852106Search in Google Scholar
Mcmillian, M.H. and Lawson, S.A. (2006). Experimental and modeling study of hydrogen/syngas production and particulate emissions from a natural gas-fueled partial oxidation engine. Int. J. Hydrogen Energy 31: 847–860, https://doi.org/10.1016/j.ijhydene.2005.08.013.Search in Google Scholar
Merchant, S.S., Goldsmith, C.F., Vandeputte, A.G., Burke, M.P., Klippenstein, S.J., and Green, W.H. (2015). Understanding low-temperature first-stage ignition delay: propane. Combust. Flame 162: 3658–3673, https://doi.org/10.1016/j.combustflame.2015.07.005.Search in Google Scholar
Mikalsen, R. and Roskilly, A.P. (2010). The control of a free-piston engine generator. Part 1: fundamental analyses. Appl. Energy 87: 1273–1280, https://doi.org/10.1016/j.apenergy.2009.06.036.Search in Google Scholar
Milan, J.B. (1951). Engine generation of synthesis gas, US patent 2,543,791.Search in Google Scholar
Mittal, G. and Sung, C.J. (2007). A rapid compression machine for chemical kinetics studies at elevated pressures and temperatures. Combust. Sci. Technol. 179: 497–530, https://doi.org/10.1080/00102200600671898.Search in Google Scholar
Morrison, P.W. and Reimer, J.A. (1989). Silane pyrolysis in a piston reactor. AIChE J. 35: 793–802, https://doi.org/10.1002/aic.690350510.Search in Google Scholar
Morsy, M.H. (2014). Modeling study on the production of hydrogen/syngas via partial oxidation using a homogeneous charge compression ignition engine fueled with natural gas. Int. J. Hydrogen Energy 39: 1096–1104, https://doi.org/10.1016/j.ijhydene.2013.10.160.Search in Google Scholar
Muradov, N. (2015). Low-carbon production of hydrogen from fossil fuels. In: Compendium of hydrogen energy. Woodhead Publishing, Cambridge, pp. 489–522.10.1016/B978-1-78242-361-4.00017-0Search in Google Scholar
Narayanaswamy, K. and Najt, P.M. (2013). Technique for production of ammonia on technique for production of ammonia on demand in a three way catalyst for a passive selective catalytic reduction system, US patent 8,424,289 B2.Search in Google Scholar
Nikolaevich, Y.V. (2018). Apparatus for producing silicon nanopowders by monosilane adiabatic compression, Patent RU2705958C1.Search in Google Scholar
Oberdorfer, P.E. and Winch, R.F. (1961). Chemicals from methane in a high compression engine. Ind. Eng. Chem. 53: 41–44, https://doi.org/10.1021/ie50613a029.Search in Google Scholar
Odell, W. (1947). Method of oxidizing hydrogen sulfide, US patent 2,415,904.Search in Google Scholar
Oertel, M., Schmitz, J., Weirich, W., Jendryssek‐Neumann, D., and Schulten, R. (1987). Steam reforming of natural gas with intergrated hydrogen separation for hydrogen production. Chem. Eng. Technol. 10: 248–255, https://doi.org/10.1002/ceat.270100130.Search in Google Scholar
Pescara, R.P. (1928). Motor compressor apparatus, US patent 1,666,630.Search in Google Scholar
Pitchai, R. and Klier, K. (1986). Partial oxidation of methane. Catal. Rev. 28: 13–88, https://doi.org/10.1080/03602458608068085.Search in Google Scholar
Porras, S., Kaczmarek, D., Herzler, J., Drost, S., Werler, M., Kasper, T., Fikri, M., Schießl, R., Atakan, B., Schulz, C., et al.. (2020). An experimental and modeling study on the reactivity of extremely fuel-rich methane/dimethyl ether mixtures. Combust. Flame 212: 107–122, https://doi.org/10.1016/j.combustflame.2019.09.036.Search in Google Scholar
Pozdnyakov, G.A., Yakovlev, V.N., and Saprykin, A.I. (2014). Production of nanosized silicon powders by monosilane decomposition in an adiabatic process. Dokl. Phys. Chem. 456: 67–70, https://doi.org/10.1134/s0012501614050029.Search in Google Scholar
Pozdnyakov, G.A., Yakovlev, V.N., and Saprykin, A.I. (2017). Production of nanosized silicon carbide powders by adiabatic compression. Dokl. Phys. Chem. 476: 165–168, https://doi.org/10.1134/s0012501617090044.Search in Google Scholar
Pulkrabek, W.W. (2004). Engineering fundamentals of the internal combustion engine, 2nd ed. Pearson, Prentice-Hall, Englewood Cliffs, NJ.10.1115/1.1669459Search in Google Scholar
Retailliau, E. (1956). Gas manufacture, US patent 2,748,179.Search in Google Scholar
Roestenberg, T., Glushenkov, M., Kronberg, A., and Van Der Meer, T. (2010a). On the controllability and run-away possibility of a totally free piston, pulsed compression reactor. Chem. Eng. Sci. 65: 4916–4922, https://doi.org/10.1016/j.ces.2010.05.034.Search in Google Scholar
Roestenberg, T., Glushenkov, M., Kronberg, A., Verbeek, A.A., and Van Der Meer, T. (2010b). Partial oxidation of methane in the pulsed compression reactor: experiments and simulation. World Acad. Sci. Eng. Technol. 43: 445–449.Search in Google Scholar
Roestenberg, T., Glushenkov, M.J., Kronberg, A.E., Verbeek, A.A., and Van Der Meer, T. (2011). Experimental study and simulation of syngas generation from methane in the pulsed compression reactor. Fuel 90: 1875–1883, https://doi.org/10.1016/j.fuel.2010.11.002.Search in Google Scholar
Roestenberg, T., Custers, B., Glushenkov, M., Kronberg, A., and Van Der Meer, T. (2012). Steam reforming of methane by rapid compression – expansion. Fuel 94: 298–304, https://doi.org/10.1016/j.fuel.2011.10.034.Search in Google Scholar
Ruble, R.J. and Beacon, N.Y. (1949). Preparation of gas mixtures, US patent 2,484,249.Search in Google Scholar
Saprykin, A.I., Pozdnyakov, G.A., and Yakovlev, V.N. (2013). Method of producing nanosize silicon structures, Patent RU2547016C2.Search in Google Scholar
Schobert, H. (2014). Production of acetylene and acetylene-based chemicals from coal. Chem. Rev. 114: 1743–1760, https://doi.org/10.1021/cr400276u.Search in Google Scholar PubMed
Scott, J. (1959). Free floating piston reactor, US patent 2,898,199.Search in Google Scholar
Scull, N., Kim, C., and Foster, D.E. (1986). Comparison of unburned fuel and aldehyde emissions from a methanol-fueled stratified charge and homogeneous charge engine. SAE Technical Paper 861543, SAE Technical Papers.10.4271/861543Search in Google Scholar
Shmelev, V. (2019). An internal combustion alternator with both free piston and cylinder. Eng. Sci. Technol. Int. J. 22: 947–955, https://doi.org/10.1016/j.jestch.2019.01.009.Search in Google Scholar
Shmelev, V.M. (2006). Nitric oxide production in a multistage-compression chemical reactor. Theor. Found. Chem. Eng. 40: 526–534, https://doi.org/10.1134/s0040579506050101.Search in Google Scholar
Shmelev, V.M. and Nikolaev, V.M. (2008). Partial oxidation of methane in a multistage-compression chemical reactor. Theor. Found. Chem. Eng. 42: 19–25, https://doi.org/10.1134/s004057950801003x.Search in Google Scholar
Shudo, T., Shima, Y., and Fujii, T. (2009). Production of dimethyl ether and hydrogen by methanol reforming for an HCCI engine system with waste heat recovery – continuous control of fuel ignitability and utilization of exhaust gas heat. Int. J. Hydrogen Energy 34: 7638–7647, https://doi.org/10.1016/j.ijhydene.2009.06.077.Search in Google Scholar
Smith, G., Golden, D., Frenklach, M., Moriarty, N., Eiteneer, B., Goldenberg, M., Bowman, C., Hanson, R., Song, S., Gardiner, W., et al.. (n.d.). GRI-Mech, Available at: <http://combustion.berkeley.edu/gri-mech/> (Accessed 23 March 2021).Search in Google Scholar
Stirlen, E.D. (1941). Production of sulphur from hydrogen sulphide, US patent 2,258,305.Search in Google Scholar
Sung, C.J. and Curran, H.J. (2014). Using rapid compression machines for chemical kinetics studies. Prog. Energy Combust. Sci. 44: 1–18, https://doi.org/10.1016/j.pecs.2014.04.001.Search in Google Scholar
Suzuki, S. and Mori, S. (2017a). Flame synthesis of carbon nanotube through a diesel engine using normal dodecane/ethanol mixing fuel as a feedstock. J. Chem. Eng. Jpn. 50: 178–185, https://doi.org/10.1252/jcej.16we183.Search in Google Scholar
Suzuki, S. and Mori, S. (2017b). Carbon nanotube-like materials in the exhaust from a diesel engine using gas oil/ethanol mixing fuel with catalysts and sulfur. J. Air Waste Manag. Assoc. 67: 873–880, https://doi.org/10.1080/10962247.2017.1296503.Search in Google Scholar PubMed
Suzuki, S. and Mori, S. (2018). Synthesis of carbon nanotubes from biofuel as a carbon source through a diesel engine. Diam. Relat. Mater. 82: 79–86, https://doi.org/10.1016/j.diamond.2018.01.003.Search in Google Scholar
Swanson, J.J., Febo, R., Boies, A.M., and Kittelson, D.B. (2016). Fuel sulfur and iron additives contribute to the formation of carbon nanotube-like structures in an internal combustion engine. Environ. Sci. Technol. Lett. 3: 364–368, https://doi.org/10.1021/acs.estlett.6b00313.Search in Google Scholar
Usman, M., Wan Daud, W.M.A., and Abbas, H.F. (2015). Dry reforming of methane: influence of process parameters – a review. Renew. Sustain. Energy Rev. 45: 710–744, https://doi.org/10.1016/j.rser.2015.02.026.Search in Google Scholar
Van Dijck, W. (1957). Reciprocating compression-reactor for short period, high temperature and high pressure chemical reactions, US patent 2,814,552.Search in Google Scholar
Vernon, P.D.F., Green, M.L.H., Cheetham, A.K., and Ashcroft, A.T. (1990). Partial oxidation of methane to synthesis gas. Catal. Lett. 6: 181–186, https://doi.org/10.1007/bf00774718.Search in Google Scholar
Volez, F.L. and Lowther, F. (1986). Process for producing acetylene using a homogeneous mixture, US patent 4,570,028.Search in Google Scholar
Vons, V.A., De Smet, L.C.P.M., Munao, D., Evirgen, A., Kelder, E.M., and Schmidt-Ott, A. (2011). Silicon nanoparticles produced by spark discharge. J. Nanoparticle Res. 13: 4867–4879, https://doi.org/10.1007/s11051-011-0466-0.Search in Google Scholar
Wang, Z., Shuai, S.J., Wang, J.X., Tian, G.H., and An, X.L. (2006). Modeling of HCCI combustion: from 0D to 3D. SAE 2006 world congress & exhibition, USA, pp. 1–20.10.4271/2006-01-1364Search in Google Scholar
Wärtsilä Corporation. (2006). The world’s most powerful engine enters service. Wärtsilä Corporation, Available at: <https://www.wartsila.com/dnk/media/news/12-09-2006-the-world’s-most-powerful-engine>.Search in Google Scholar
Wiemann, S., Hegner, R., Atakan, B., Schulz, C., and Kaiser, S.A. (2018). Combined production of power and syngas in an internal combustion engine – experiments and simulations in SI and HCCI mode. Fuel 215: 40–45, https://doi.org/10.1016/j.fuel.2017.11.002.Search in Google Scholar
Woschni, G. (1968). A universally applicable equation for the instantaneous heat transfer coefficient in the internal combustion engine. SAE Trans. 76: 3065–3083.10.4271/670931Search in Google Scholar
Wulff, R.G. (1932). Method of producing acetylene by compression, US patent 1,880,307.Search in Google Scholar
Wulff, R.G. (1934). Method of producing acetylene by compression of natural gas, US patent 1,966,779.Search in Google Scholar
Yang, Y.C., Lim, M.S., and Chun, Y.N. (2009). The syngas production by partial oxidation using a homogeneous charge compression ignition engine. Fuel Process. Technol. 90: 553–557, https://doi.org/10.1016/j.fuproc.2009.01.002.Search in Google Scholar
Yu, Y., Vanhove, G., Griffiths, J.F., De Ferrieìres, S., and Pauwels, J.F. (2013). Influence of EGR and syngas components on the autoignition of natural gas in a rapid compression machine: a detailed experimental study. Energy Fuels 27: 3988–3996, https://doi.org/10.1021/ef400336x.Search in Google Scholar
Yun, T.M., Kottke, P.A., Anderson, D.M., and Fedorov, A.G. (2015). Experimental investigation of hydrogen production by variable volume membrane batch reactors with modulated liquid fuel introduction. Int. J. Hydrogen Energy 40: 2601–2612, https://doi.org/10.1016/j.ijhydene.2014.12.116.Search in Google Scholar
Zimmermann, H., and Walzl, R. (2009). Ethylene. In: Ullmann’s encyclopedia of industrial chemistry. Wiley, Weinheim, Germany, pp. 465–529.10.1002/14356007.a10_045.pub3Search in Google Scholar
Zywietz, U., Evlyukhin, A.B., Reinhardt, C., and Chichkov, B.N. (2014). Laser printing of silicon nanoparticles with resonant optical electric and magnetic responses. Nat. Commun. 5: 1–7, https://doi.org/10.1038/ncomms4402.Search in Google Scholar PubMed
Supplementary Material
The online version of this article offers supplementary material (https://doi.org/10.1515/revce-2020-0116).
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