Skip to content
Licensed Unlicensed Requires Authentication Published online by De Gruyter August 12, 2022

Corrosion inhibition relevance of semicarbazides: electronic structure, reactivity and coordination chemistry

  • Chandrabhan Verma

    Chandrabhan Verma works at the IRC for Advanced Materials, KFUPM, Dhahran, Saudi Arabia. He is a member of the American Chemical Society (ACS). His research is mainly focused on the synthesis and designing of environmental friendly corrosion inhibitors useful for several industrial applications. Dr. Verma is the author of several research and review articles and has edited many books. He has a total citation of more than 7400. Dr. Verma has received many awards.

    EMAIL logo
    , Mumtaz A. Quraishi

    Mumtaz A. Quraishi is a chair professor at IRC for Advanced Materials, KFUPM, Saudi Arabia. Before joining KFUPM, he was an institute professor at IIT-BHU, Varanasi, India. He also served as head (chairman) of Department of Chemistry IIT BHU. He has a teaching experience of more than 35 years. Dr Quraishi is a fellow of RSC and ACS. He has published more than 400 papers having a total citation of more than 28000. He has also authored and edited many books.

    and Kyong Yop Rhee

    Dr. Kyong Yop Rhee is a professor of mechanical engineering at Kyung Hee University (South Korea) since 1999. His main research interests are nanocomposites, surface treatment, fracture, and composite materials. He has published more than 451 scientific papers and has led 67 R&D projects. His current h-index is 63. He earned his BS and MS degrees in mechanical engineering from Seoul National University (South Korea) and his PhD in mechanical engineering from Georgia Institute of Technology.

    EMAIL logo

Abstract

Semicarbazide (OC(NH2)(N2H3)) and thiosemicarbazide (SC(NH2)(N2H3)) are well-known for their coordination complex formation ability. They contain nonbonding electrons in the form of heteroatoms (N, O and S) and π-electrons in the form of >C=O and >C=S through they strongly coordinate with the metal atoms and ions. Because of their association with this property, the Semicarbazide (SC), thiosemicarbazide (TSC) and their derivatives are widely used for different applications. They serve as building blocks for synthesis of various industrially and biologically useful chemicals. The SC, TSC and they derivatives are also serve as strong aqueous phase corrosion inhibitors. In the present reports, the coordination ability and corrosion protection tendency of Semicarbazide (SC), thiosemicarbazide (TSC) and their derivatives is surveyed and described. These compounds are widely used as inhibitors for different metals and alloys. Through their electron rich sites they adsorb on the metal surface and build corrosion protective film. Their adsorption mostly followed the Langmuir adsorption isotherm. Through their adsorption they increase the value of charge transfer resistance and decrease the value of corrosion current density. Computational studies adopted in the literature indicate that SC, TSC and their derivatives adsorb flatly and spontaneously using charge transfer mechanism.


Corresponding authors: Chandrabhan Verma, Interdisciplinary Research Center for Advanced Materials, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi Arabia, E-mail: ; and Kyong Yop Rhee, Department of Mechanical Engineering (BK21 Four), College of Engineering, Kyung Hee University, Yongin, Republic of Korea, E-mail:

About the authors

Chandrabhan Verma

Chandrabhan Verma works at the IRC for Advanced Materials, KFUPM, Dhahran, Saudi Arabia. He is a member of the American Chemical Society (ACS). His research is mainly focused on the synthesis and designing of environmental friendly corrosion inhibitors useful for several industrial applications. Dr. Verma is the author of several research and review articles and has edited many books. He has a total citation of more than 7400. Dr. Verma has received many awards.

Mumtaz A. Quraishi

Mumtaz A. Quraishi is a chair professor at IRC for Advanced Materials, KFUPM, Saudi Arabia. Before joining KFUPM, he was an institute professor at IIT-BHU, Varanasi, India. He also served as head (chairman) of Department of Chemistry IIT BHU. He has a teaching experience of more than 35 years. Dr Quraishi is a fellow of RSC and ACS. He has published more than 400 papers having a total citation of more than 28000. He has also authored and edited many books.

Kyong Yop Rhee

Dr. Kyong Yop Rhee is a professor of mechanical engineering at Kyung Hee University (South Korea) since 1999. His main research interests are nanocomposites, surface treatment, fracture, and composite materials. He has published more than 451 scientific papers and has led 67 R&D projects. His current h-index is 63. He earned his BS and MS degrees in mechanical engineering from Seoul National University (South Korea) and his PhD in mechanical engineering from Georgia Institute of Technology.

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: None declared.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

References

Abd El-Maksoud, S. and Fouda, A. (2005). Some pyridine derivatives as corrosion inhibitors for carbon steel in acidic medium. Mater. Chem. Phys. 93: 84–90, https://doi.org/10.1016/j.matchemphys.2005.02.020.Search in Google Scholar

Abd El-Nabey, B., Khamis, E., Shaban, M., Thompson, G., and Dawson, J. (1986). Impedance studies of the inhibition of the corrosion of mild steel in 0.1 m sulphuric acid with 10% methanol by thiosemicarbazide derivatives. Surf. Coating. Technol. 28: 67–82, https://doi.org/10.1016/0257-8972(86)90118-0.Search in Google Scholar

Acharya, P.T., Bhavsar, Z.A., Jethava, D.J., Patel, D.B., and Patel, H.D. (2021). A review on development of bio-active thiosemicarbazide derivatives: recent advances. J. Mol. Struct. 1226: 129268, https://doi.org/10.1016/j.molstruc.2020.129268.Search in Google Scholar

Ahmed, A.I. and Basahel, S. (1988). Inhibition of the acid corrosion of aluminium with some morpholine and thiosemicarbazide derivatives. Anti-corrosion Methods & Mater. 35: 4–8, https://doi.org/10.1108/eb020680.Search in Google Scholar

A Jawad, Q., S Zinad, D., Dawood Salim, R., A Al-Amiery, A., Sumer Gaaz, T., Takriff, M.S., and H Kadhum, A.A. (2019). Synthesis, characterization, and corrosion inhibition potential of novel thiosemicarbazone on mild steel in sulfuric acid environment. Coatings 9: 729, https://doi.org/10.3390/coatings9110729.Search in Google Scholar

Al-Amiery, A.A., Kadhum, A.A.H., Kadihum, A., Mohamad, A.B., How, C.K., and Junaedi, S. (2014). Inhibition of mild steel corrosion in sulfuric acid solution by new Schiff base. Materials 7: 787–804, https://doi.org/10.3390/ma7020787.Search in Google Scholar PubMed PubMed Central

Al-Ola, K.A.A. and Al-Nami, S.Y. (2011). 1-Benzoyl-4-phenyl-3-thiosemicarbazide as corrosion inhibitor for carbon steel in Hˆ sub 3ˆ POˆ sub 4ˆ solution. Mod. Appl. Sci. 5: 193.Search in Google Scholar

Al-Shihry, S.S., Sayed, A.R., and Abd El-lateef, H.M. (2020). Design and assessment of a novel poly (urethane-semicarbazides) containing thiadiazoles on the backbone of the polymers as inhibitors for steel pipelines corrosion in CO2-saturated oilfield water. J. Mol. Struct. 1201: 127223, https://doi.org/10.1016/j.molstruc.2019.127223.Search in Google Scholar

Al-Uqaily, R.A.H. (2015). Inhibition by 1-methyl isoquinoline for mild steel corrosion in 1 M HCl media. Am. Acad. Sci. Res. J. Eng., Technol., Sci. 14: 55–63.Search in Google Scholar

Alamiery, A. (2021). Short report of mild steel corrosion in 0.5 MH2so4 by 4-ethyl-1-(4-oxo-4-phenylbutanoyl) thiosemicarbazide. J. Tribol. 30: 90–99.Search in Google Scholar

Alamiery, A., Mahmoudi, E., and Allami, T. (2021). Corrosion inhibition of low-carbon steel in hydrochloric acid environment using a Schiff base derived from pyrrole: gravimetric and computational studies. Int. J. Corrosion Scale Inhib. 10: 749–765.Search in Google Scholar

Alamiery, A.A. (2021). Anticorrosion effect of thiosemicarbazide derivative on mild steel in 1 M hydrochloric acid and 0.5 M sulfuric acid: gravimetrical and theoretical studies. Mater. Sci. Energy Technol. 4: 263–273, https://doi.org/10.1016/j.mset.2021.07.004.Search in Google Scholar

Alamiery, A.A., Wan Isahak, W.N.R., and Takriff, M.S. (2021). Inhibition of mild steel corrosion by 4-benzyl-1-(4-oxo-4-phenylbutanoyl) thiosemicarbazide: gravimetrical, adsorption and theoretical studies. Lubricants 9: 93, https://doi.org/10.3390/lubricants9090093.Search in Google Scholar

Alamri, A.H. (2020). Experimental and theoretical insights into the synergistic effect of iodide ions and 1-acetyl-3-thiosemicarbazide on the corrosion protection of C1018 carbon steel in 1 M HCl. Materials 13: 5013, https://doi.org/10.3390/ma13215013.Search in Google Scholar PubMed PubMed Central

Alaoui, K., Dkhireche, N., Touhami, M.E., and El Kacimi, Y. (2020). Chapter 5: review of application of imidazole and imidazole derivatives as corrosion inhibitors of metals. In: New challenges and industrial applications for corrosion prevention and control. IGI Global, Pennsylvania, United States, pp. 101–131.10.4018/978-1-7998-2775-7.ch005Search in Google Scholar

Albuquerque, M.A., de Oliveira, M.C., and Echevarria, A. (2017). Anticorrosive activity of 2-hydroxybenzaldehyde-thiosemicarbazone for AISI 1020 carbon steel in acid medium. Int. J. Electrochem. Sci. 12: 852–860, https://doi.org/10.20964/2017.02.14.Search in Google Scholar

Alfalah, M.G.K., Abdulrazzaq, M., Saraçoğlu, M., and Kandemirli, F. (2020). 4-Naphthyl-3-thiosemicarbazide as corrosion inhibitor for copper in sea water (3.5% sodium chloride). Eurasian J. Sci. Eng. Technol. 1: 27–34.Search in Google Scholar

Ameer, M., Khamis, E., and Al-Senani, G. (2000). Adsorption studies of the effect of thiosemicarbazides on the corrosion of steel in phosphoric acid. Adsorpt. Sci. Technol. 18: 177–194, https://doi.org/10.1260/0263617001493378.Search in Google Scholar

Angst, U.M. (2018). Challenges and opportunities in corrosion of steel in concrete. Mater. Struct. 51: 1–20, https://doi.org/10.1617/s11527-017-1131-6.Search in Google Scholar

Arion, V., Revenco, M., Gradinaru, J., Simonov, Y., Kravtsov, V., Gerbeleu, N., Saint-Aman, E., and Adams, F. (2001). Mixed macrocyclic coordination compounds containing thiosemicarbazide and crown-ether moieties (synthesis, structure and properties). Rev. Inorg. Chem. 21: 1–42, https://doi.org/10.1515/revic.2001.21.1-2.1.Search in Google Scholar

Ateya, B., Abo-Elkhair, B., and Abdel-Hamid, I. (1976). Thiosemicarbazide as an inhibitor for the acid corrosion of iron. Corrosion Sci. 16: 163–169, https://doi.org/10.1016/0010-938x(76)90057-3.Search in Google Scholar

Badr, G. (2009). The role of some thiosemicarbazide derivatives as corrosion inhibitors for C-steel in acidic media. Corrosion Sci. 51: 2529–2536, https://doi.org/10.1016/j.corsci.2009.06.017.Search in Google Scholar

Bimoussa, A., Koumya, Y., Oubella, A., Kaddouri, Y., Fawzi, M., Laamari, Y., Abouelfida, A., Itto, M.Y.A., Touzani, R., and Benyaich, A. (2021). Synthesis, experimental and theoretical studies of sesquiterpenic thiosemicarbazone and semicarbazone as organic corrosion inhibitors for stainless steel 321 in H2SO4 1 M. J. Mol. Struct. 1253: 132276, doi:https://doi.org/10.1016/j.molstruc.2021.132276.Search in Google Scholar

Brycki, B.E., Kowalczyk, I.H., Szulc, A., Kaczerewska, O., and Pakiet, M. (2018). Organic corrosion inhibitors. Corrosion Inhibitors. Principles and Recent Applications 3: 33.Search in Google Scholar

Chauhan, D.S., Ansari, K., Sorour, A., Quraishi, M., Lgaz, H., and Salghi, R. (2018). Thiosemicarbazide and thiocarbohydrazide functionalized chitosan as ecofriendly corrosion inhibitors for carbon steel in hydrochloric acid solution. Int. J. Biol. Macromol. 107: 1747–1757, https://doi.org/10.1016/j.ijbiomac.2017.10.050.Search in Google Scholar PubMed

Chauhan, D.S., Verma, C., and Quraishi, M. (2021). Molecular structural aspects of organic corrosion inhibitors: experimental and computational insights. J. Mol. Struct. 1227: 129374, https://doi.org/10.1016/j.molstruc.2020.129374.Search in Google Scholar

Ebenso, E.E., Isabirye, D.A., and Eddy, N.O. (2010). Adsorption and quantum chemical studies on the inhibition potentials of some thiosemicarbazides for the corrosion of mild steel in acidic medium. Int. J. Mol. Sci. 11: 2473–2498, https://doi.org/10.3390/ijms11062473.Search in Google Scholar

El-Asmy, A.A., Babaqi, A.S., and Al-Hubaishi, A.A. (1987). Ligational, corrosion inhibition and antimicrobial properties of 4-phenyl-1-benzenesulphonyl-3-thiosemicarbazide. Transit. Met. Chem. 12: 428–431, https://doi.org/10.1007/bf01171656.Search in Google Scholar

El-Gammal, O.A., Fouda, A.E.-A.S., and Nabih, D.M. (2020). Novel Mn2+, Fe3+, Co2+, Ni2+ and Cu2+ complexes of potential OS donor thiosemicarbazide: design, structural elucidation, anticorrosion potential study and antibacterial activity. J. Mol. Struct. 1204: 127495, https://doi.org/10.1016/j.molstruc.2019.127495.Search in Google Scholar

El-Ghamry, H.A., Fawzy, A., Farghaly, T.A., Bawazeer, T.M., Alqarni, N., Alkhatib, F.M., and Gaber, M. (2022). Evaluation of the efficiency of divalent cobalt and copper chelates based on isatin derivatives and thiosemicarbazide ligands as inhibitors for the corrosion of Sabic iron in acidic medium. Arab. J. Chem. 15: 103522, https://doi.org/10.1016/j.arabjc.2021.103522.Search in Google Scholar

El-Shafei, A., Moussa, M., and El-Far, A. (2001). The corrosion inhibition character of thiosemicarbazide and its derivatives for C-steel in hydrochloric acid solution. Mater. Chem. Phys. 70: 175–180, https://doi.org/10.1016/s0254-0584(00)00496-x.Search in Google Scholar

Eldesoky, A.M., Hassan, H.M., Ali, I.H., Mohamed, M.E., and Bondock, S. (2018). Electrochemical and theoretical study on the role of thiosemicarbazide derivatives as corrosion inhibitors for C-steel in HCl solution. Int. J. Emerg. Trends Eng. Dev. 8: 74–96, https://doi.org/10.26808/rs.ed.i8v5.05.Search in Google Scholar

Fouda, A. and Elasmy, A. (1987). Efficiency of some phenylthiosemicarbazide derivatives in retarding the dissolution of Al in NaOH solution. Monatshefte für Chemie/Chem. Mon. 118: 709–716, https://doi.org/10.1007/bf00809220.Search in Google Scholar

Fouda, A., Moussa, M., Taha, F., and Elneanaa, A. (1986). The role of some thiosemicarbazide derivatives in the corrosion inhibition of aluminium in hydrochloric acid. Corrosion Sci. 26: 719–726, https://doi.org/10.1016/0010-938x(86)90035-1.Search in Google Scholar

Fouda, A.E.-A.S., Mostafa, H.A., and Abu-Elnader, H.M. (1989). Phenyl semicarbazide derivatives as corrosion inhibitors for aluminium in hydrochloric acid solution. Monatshefte für Chemie/Chem. Mon. 120: 501–507, https://doi.org/10.1007/bf00810836.Search in Google Scholar

Fouda, A., Elshafei, A., Elasklany, A., and Madkour, L. (1995a). Inhibitory effect of some carbazides on corrosion of aluminium in hydrochloric acid and sodium hydroxide solutions. Mater. Werkst. 26: 342–346, https://doi.org/10.1002/mawe.19950260612.Search in Google Scholar

Fouda, A., Madkour, L., El-Shafei, A., and Abd El-Maksoud, S. (1995b). Corrosion inhibitors for zinc in 2 M HCl solution. Bull. Kor. Chem. Soc. 16: 454.Search in Google Scholar

Goulart, C.M., Esteves-Souza, A., Martinez-Huitle, C.A., Rodrigues, C.J.F., Maciel, M.A.M., and Echevarria, A. (2013). Experimental and theoretical evaluation of semicarbazones and thiosemicarbazones as organic corrosion inhibitors. Corrosion Sci. 67: 281–291, https://doi.org/10.1016/j.corsci.2012.10.029.Search in Google Scholar

Groysman, A. (2017a). Corrosion problems and solutions in oil refining and petrochemical industry. Springer, Switzerland.10.1007/978-3-319-45256-2Search in Google Scholar

Groysman, A. (2017b). Corrosion problems and solutions in oil, gas, refining and petrochemical industry. Koroze a Ochrana Materialu 61: 100–117, https://doi.org/10.1515/kom-2017-0013.Search in Google Scholar

Gürten, A.A., Kayakırılmaz, K., and Erbil, M. (2007). The effect of thiosemicarbazide on corrosion resistance of steel reinforcement in concrete. Construct. Build. Mater. 21: 669–676, https://doi.org/10.1016/j.conbuildmat.2005.12.010.Search in Google Scholar

He, Y., Yang, R., Zhou, Y., Ma, L., Zhang, L., and Chen, Z. (2016). Water-soluble thiosemicarbazide-imidazole derivative as an efficient inhibitor protecting P110 carbon steel from CO2 corrosion. Anti-corrosion Methods & Mater. 63: 437–444, https://doi.org/10.1108/acmm-01-2015-1485.Search in Google Scholar

Hossain, S. and Almarshad, A. (2006). Inhibiting effect of thiosemicarbazide on cold rolled carbon steel. Corrosion Eng. Sci. Technol. 41: 77–81, https://doi.org/10.1179/174327806x93947.Search in Google Scholar

Hosseini, S., Bahrami, M., and Dorehgiraee, A. (2012). Inhibition investigation and determination of some quantum chemical parameters of 1-(4-(dimethylamino) benzylidene) thiosemicarbazide on steel alloys in sulfuric acid medium. Mater. Corros. 63: 627–635, https://doi.org/10.1002/maco.201106123.Search in Google Scholar

Issaadi, S., Douadi, T., Zouaoui, A., Chafaa, S., Khan, M.A., and Bouet, G. (2011). Novel thiophene symmetrical Schiff base compounds as corrosion inhibitor for mild steel in acidic media. Corrosion Sci. 53: 1484–1488, https://doi.org/10.1016/j.corsci.2011.01.022.Search in Google Scholar

Ita, B. and Offiong, O. (1999). Corrosion inhibitory properties of 4-phenylsemicarbazide and semicarbazide on mild steel in hydrochloric acid. Mater. Chem. Phys. 59: 179–184, https://doi.org/10.1016/s0254-0584(99)00016-4.Search in Google Scholar

Ituen, E., Akaranta, O., and James, A. (2017). Evaluation of performance of corrosion inhibitors using adsorption isotherm models: an overview. Chem. Sci. Int. J. 18: 1–34, https://doi.org/10.9734/csji/2017/28976.Search in Google Scholar

Jacob, K.S. and Parameswaran, G. (2010). Corrosion inhibition of mild steel in hydrochloric acid solution by Schiff base furoin thiosemicarbazone. Corrosion Sci. 52: 224–228, https://doi.org/10.1016/j.corsci.2009.09.007.Search in Google Scholar

Kandemirli, F. and Sagdinc, S. (2007). Theoretical study of corrosion inhibition of amides and thiosemicarbazones. Corrosion Sci. 49: 2118–2130, https://doi.org/10.1016/j.corsci.2006.10.026.Search in Google Scholar

Karthik, N. and Sethuraman, M.G. (2015). Improved copper corrosion resistance of epoxy-functionalized hybrid sol–gel monolayers by thiosemicarbazide. Ionics 21: 1477–1488, https://doi.org/10.1007/s11581-014-1274-1.Search in Google Scholar

Khalil, W., Abdou, M., and Ammar, I. (1990). Corrosion of mild steel in acid solutions containing thiourea and thiosemicarbazide. Mater. Werkst. 21: 230–235, https://doi.org/10.1002/mawe.19900210608.Search in Google Scholar

Krzemień, A., Więckol-Ryk, A., Smoliński, A., Koteras, A., and Więcław-Solny, L. (2016). Assessing the risk of corrosion in amine-based CO2 capture process. J. Loss Prev. Process. Ind. 43: 189–197, https://doi.org/10.1016/j.jlp.2016.05.020.Search in Google Scholar

Kumar, P. and Nityananda Shetty, A. (2015). Inhibition effect of adsorption layer of 1-phenyl-4-(4-nitrophenyl) thiosemicarbazide on the corrosion of 18 Ni 250-grade welded maraging steel in 1.0 M hydrochloric acid medium. Res. Chem. Intermed. 41: 7095–7113, https://doi.org/10.1007/s11164-014-1800-9.Search in Google Scholar

Kumar, S.L.A., Gopiraman, M., Kumar, M.S., and Sreekanth, A. (2011). 2-Acetylpyridine-N (4)-morpholine thiosemicarbazone (HAcpMTSc) as a corrosion inhibitor on mild steel in HCl. Ind. Eng. Chem. Res. 50: 7824–7832, https://doi.org/10.1021/ie200487g.Search in Google Scholar

Kumari, A., Chugh, B., Singh, G., and Singh, A.K. (2021). Corrosion inhibitors for sweet (CO2 corrosion) and sour (H2S corrosion) environments. In: Sustainable corrosion inhibitors I: fundamentals, methodologies, and industrial applications. ACS Publications, Washington, DC, pp. 189–205.10.1021/bk-2021-1403.ch009Search in Google Scholar

Lai, G. (1985). High temperature corrosion problems in the process industries. JOM 37: 14–19, https://doi.org/10.1007/bf03259690.Search in Google Scholar

Lavanya, K., Saranya, J., and Chitra, S. (2018). Recent reviews on quinoline derivatives as corrosion inhibitors. Corrosion Rev. 36: 365–371, https://doi.org/10.1515/corrrev-2017-0129.Search in Google Scholar

Lebrini, M., Robert, F., Vezin, H., and Roos, C. (2010). Electrochemical and quantum chemical studies of some indole derivatives as corrosion inhibitors for C38 steel in molar hydrochloric acid. Corrosion Sci. 52: 3367–3376, https://doi.org/10.1016/j.corsci.2010.06.009.Search in Google Scholar

Leffler, J.E. and Grunwald, E. (2013). Rates and equilibria of organic reactions: as treated by statistical, thermodynamic and extrathermodynamic methods, ISBN-10 ‏ : ‎ 0486660680. Courier Corporation, Mineola, New York.Search in Google Scholar

Lukovits, I., Shaban, A., and Kálmán, E. (2005). Thiosemicarbazides and thiosemicarbazones: non-linear quantitative structure–efficiency model of corrosion inhibition. Electrochim. Acta 50: 4128–4133, https://doi.org/10.1016/j.electacta.2005.01.029.Search in Google Scholar

Machnikova, E., Whitmire, K.H., and Hackerman, N. (2008). Corrosion inhibition of carbon steel in hydrochloric acid by furan derivatives. Electrochim. Acta 53: 6024–6032, https://doi.org/10.1016/j.electacta.2008.03.021.Search in Google Scholar

Mahgoub, F.M. and Al-Rashdi, S. (2016). Investigate the corrosion inhibition of mild steel in sulfuric acid solution by thiosemicarbazide. Open J. Phys. Chem. 6: 54, https://doi.org/10.4236/ojpc.2016.63006.Search in Google Scholar

Marcus, P. (2011). Corrosion mechanisms in theory and practice, CRC Press, Boca Raton. ISBN: 9780429143564.Search in Google Scholar

McCafferty, E. (2010). Introduction to corrosion science, Springer Science & Business Media, Springer New York, NY. ISBN: 978-1-4419-0455-3.10.1007/978-1-4419-0455-3Search in Google Scholar

Merimi, I., Touzani, R., Aouniti, A., Chetouani, A., and Hammouti, B. (2020). Pyrazole derivatives efficient organic inhibitors for corrosion in aggressive media: a comprehensive review. Int. J. Corrosion Scale Inhib. 9: 1237–1260.Search in Google Scholar

Mohan, P. and Kalaignan, G.P. (2013). 1, 4-Bis (2-nitrobenzylidene) thiosemicarbazide as effective corrosion inhibitor for mild steel. J. Mater. Sci. Technol. 29: 1096–1100, https://doi.org/10.1016/j.jmst.2013.07.006.Search in Google Scholar

Moussa, M., Fouda, A., Taha, F., and Elnenaa, A. (1988). Some thiosemicarbazide derivatives as corrosion inhibitors for aluminium in sodium hydroxide solution. Bull. Kor. Chem. Soc. 9: 191–195.Search in Google Scholar

Musa, A.Y., Kadhum, A.A.H., Mohamad, A.B., and Takriff, M.S. (2011). Molecular dynamics and quantum chemical calculation studies on 4, 4-dimethyl-3-thiosemicarbazide as corrosion inhibitor in 2.5 M H2SO4. Mater. Chem. Phys. 129: 660–665, https://doi.org/10.1016/j.matchemphys.2011.05.010.Search in Google Scholar

Muthukkumar, M., Bhuvaneswari, T., Venkatesh, G., Kamal, C., Vennila, P., Armaković, S., Armaković, S.J., Mary, Y.S., and Panicker, C.Y. (2018). Synthesis, characterization and computational studies of semicarbazide derivative. J. Mol. Liq. 272: 481–495, https://doi.org/10.1016/j.molliq.2018.09.123.Search in Google Scholar

Obot, I., Solomon, M.M., Umoren, S.A., Suleiman, R., Elanany, M., Alanazi, N.M., and Sorour, A.A. (2019). Progress in the development of sour corrosion inhibitors: past, present, and future perspectives. J. Ind. Eng. Chem. 79: 1–18, https://doi.org/10.1016/j.jiec.2019.06.046.Search in Google Scholar

Olasunkanmi, L.O., Idris, A.O., Adewole, A.H., Wahab, O.O., and Ebenso, E.E. (2020). Adsorption and corrosion inhibition potentials of salicylaldehyde-based Schiff bases of semicarbazide and p-toluidine on mild steel in acidic medium: experimental and computational studies. Surface. Interfac. 21: 100782, https://doi.org/10.1016/j.surfin.2020.100782.Search in Google Scholar

Olasunkanmi, L.O., Aniki, N.I., Adekunle, A.S., Durosinmi, L.M., Durodola, S.S., Wahab, O.O., and Ebenso, E.E. (2021). Investigating the synergism of some hydrazinecarboxamides and iodide ions as corrosion inhibitor formulations for mild steel in hydrochloric acid: experimental and computational studies. J. Mol. Liq. 343: 117600, https://doi.org/10.1016/j.molliq.2021.117600.Search in Google Scholar

Ouakki, M., Galai, M., and Cherkaoui, M. (2022). Imidazole derivatives as efficient and potential class of corrosion inhibitors for metals and alloys in aqueous electrolytes: a review. J. Mol. Liq. 345: 117815, https://doi.org/10.1016/j.molliq.2021.117815.Search in Google Scholar

Paquay, E., Clarinval, A.-M., Delvaux, A., Degrez, M., and Hurwitz, H.D. (2000). Applications of electrodialysis for acid pickling wastewater treatment. Chem. Eng. J. 79: 197–201, https://doi.org/10.1016/s1385-8947(00)00208-4.Search in Google Scholar

Prakashiah, B., Nityananda Shetty, A., and Amitha Rani, B. (2019). Improvement of anticorrosion properties of epoxy primer coating on aluminum alloy 2024-T3 by thiosemicarbazone derivatives. JOM 71: 4880–4890, https://doi.org/10.1007/s11837-019-03615-4.Search in Google Scholar

Quraishi, M., Jamal, D., and Singh, R. (2002). Inhibition of mild steel corrosion in the presence of fatty acid thiosemicarbazides. Corrosion 58: 201–207, https://doi.org/10.5006/1.3279870.Search in Google Scholar

Quraishi, M., Sardar, R., and Khan, S. (2008). An investigation of the inhibitive capability of synthesized thiosemicarbazides on the corrosion of carbon steel in acid solutions. Anti-corrosion Methods & Mater. 55: 60–65, https://doi.org/10.1108/00035590810859421.Search in Google Scholar

Raja, M., Muhamed, R.R., Muthu, S., and Suresh, M. (2017). Synthesis, spectroscopic (FT-IR, FT-Raman, NMR, UV–visible), NLO, NBO, HOMO-LUMO, Fukui function and molecular docking study of (E)-1-(5-bromo-2-hydroxybenzylidene) semicarbazide. J. Mol. Struct. 1141: 284–298, https://doi.org/10.1016/j.molstruc.2017.03.117.Search in Google Scholar

Ramya, K., Mohan, R., Anupama, K., and Joseph, A. (2015). Electrochemical and theoretical studies on the synergistic interaction and corrosion inhibition of alkyl benzimidazoles and thiosemicarbazide pair on mild steel in hydrochloric acid. Mater. Chem. Phys. 149: 632–647, https://doi.org/10.1016/j.matchemphys.2014.11.020.Search in Google Scholar

Ramya, K., Anupama, K., Shainy, K., and Joseph, A. (2017). Corrosion protection of mild steel in hydrochloric acid solution through the synergistic of alkylbenzimidazoles and semicarbazide pair – electroanalytical and computational studies. Egypt. J. Petrol. 26: 421–437, https://doi.org/10.1016/j.ejpe.2016.06.001.Search in Google Scholar

Revie, R.W. (2011). Uhlig’s corrosion handbook. John Wiley & Sons.10.1002/9780470872864Search in Google Scholar

Saha, S.K., Hens, A., Murmu, N.C., and Banerjee, P. (2016). A comparative density functional theory and molecular dynamics simulation studies of the corrosion inhibitory action of two novel N-heterocyclic organic compounds along with a few others over steel surface. J. Mol. Liq. 215: 486–495, https://doi.org/10.1016/j.molliq.2016.01.024.Search in Google Scholar

Samide, A., Turcanu, E., and Bibicu, I. (2009). Surface analysis of inhibitor films formed by N-(2-hydroxybenzilidene) thiosemicarbazide on carbon steel in acidic media. Chem. Eng. Commun. 196: 1008–1017, https://doi.org/10.1080/00986440902797881.Search in Google Scholar

Sastri, V.S. (2012). Green corrosion inhibitors: theory and practice, John Wiley & Sons, Hoboken, New Jersey, U.S. ISBN: 9781118015438.Search in Google Scholar

Schmitt, G. (2009). Global needs for knowledge dissemination, research, and development in materials deterioration and corrosion control. World Corrosion Organ. 38: 14.Search in Google Scholar

Shahabi, S., Norouzi, P., and Ganjali, M.R. (2015). Electrochemical and theoretical study of the inhibition effect of two synthesized thiosemicarbazide derivatives on carbon steel corrosion in hydrochloric acid solution. RSC Adv. 5: 20838–20847, https://doi.org/10.1039/c4ra15808c.Search in Google Scholar

Singh, A. and Chaudhary, R. (1996). Dithizone and thiosemicarbazide as inhibitors of corrosion of type 304 stainless steel in 1.0 M sulphuric acid solution. Br. Corrosion J. 31: 300–304, https://doi.org/10.1179/bcj.1996.31.4.300.Search in Google Scholar

Singh, A., Ansari, K., Quraishi, M., Kaya, S., and Banerjee, P. (2019). The effect of an N-heterocyclic compound on corrosion inhibition of J55 steel in sweet corrosive medium. New J. Chem. 43: 6303–6313, https://doi.org/10.1039/c9nj00356h.Search in Google Scholar

Singh, D., Singh, M., Chaudhary, R., and Agarwal, C. (1980). Inhibitive effects of isatin, thiosemicarbazide and isatin-3-(3-thiosemicarbazone) on the corrosion of aluminium alloys in nitric acid. J. Appl. Electrochem. 10: 587–592, https://doi.org/10.1007/bf00615480.Search in Google Scholar

Singh, M., Rastogi, R., Upadhyay, B. and Yadav, M. (2003a). Effect of substituents on corrosion inhibition efficiency of arylisothiocyanates and their condensation products with thiosemicarbazide for corrosion of copper in aqueous chloride solution, Indian J. Chem. Technol. 10(4): 414–419.Search in Google Scholar

Singh, M., Rastogi, R., Upadhyay, B., and Yadav, M. (2003b). Thiosemicarbazide, phenyl isothiocyanate and their condensation product as corrosion inhibitors of copper in aqueous chloride solutions. Mater. Chem. Phys. 80: 283–293, https://doi.org/10.1016/s0254-0584(02)00513-8.Search in Google Scholar

Tezdogan, T. and Demirel, Y.K. (2014). An overview of marine corrosion protection with a focus on cathodic protection and coatings. Brodogradnja: Teorija i praksa brodogradnje i pomorske tehnike 65: 49–59.Search in Google Scholar

Uhlig, H.H. and Revie, R.W. (1985). Corrosion and corrosion control, John Wiley & Sons, Hoboken, New Jersey, U.S. ISBN: 9780470277270.Search in Google Scholar

Valdesmartinez, J., Cabrera, L., and Gomezlara, J. (1985). Semicarbazides, thiosemicarbazides and their derivatives as ligands (3)-cordination-compounds of cobalt (II), nickel (II) and copper (II), with the 4-phenylsemicarbazone of salycylaldehyde. Afinidad 42: 487–490.Search in Google Scholar

Verma, C. and Quraishi, M. (2021). Recent progresses in Schiff bases as aqueous phase corrosion inhibitors: design and applications. Coord. Chem. Rev. 446: 214105, https://doi.org/10.1016/j.ccr.2021.214105.Search in Google Scholar

Verma, C., Olasunkanmi, L.O., Ebenso, E.E., Quraishi, M.A., and Obot, I.B. (2016). Adsorption behavior of glucosamine-based, pyrimidine-fused heterocycles as green corrosion inhibitors for mild steel: experimental and theoretical studies. J. Phys. Chem. C 120: 11598–11611, https://doi.org/10.1021/acs.jpcc.6b04429.Search in Google Scholar

Verma, C., Quraishi, M.A., Kluza, K., Makowska-Janusik, M., Olasunkanmi, L.O., and Ebenso, E.E. (2017). Corrosion inhibition of mild steel in 1M HCl by D-glucose derivatives of dihydropyrido [2, 3-d: 6, 5-d′] dipyrimidine-2, 4, 6, 8 (1H, 3H, 5H, 7H)-tetraone. Sci. Rep. 7: 1–17, https://doi.org/10.1038/srep44432.Search in Google Scholar PubMed PubMed Central

Verma, C., Olasunkanmi, L., Ebenso, E.E., and Quraishi, M. (2018). Substituents effect on corrosion inhibition performance of organic compounds in aggressive ionic solutions: a review. J. Mol. Liq. 251: 100–118, https://doi.org/10.1016/j.molliq.2017.12.055.Search in Google Scholar

Verma, C., Haque, J., Quraishi, M., and Ebenso, E.E. (2019). Aqueous phase environmental friendly organic corrosion inhibitors derived from one step multicomponent reactions: a review. J. Mol. Liq. 275: 18–40, https://doi.org/10.1016/j.molliq.2018.11.040.Search in Google Scholar

Verma, C., Ebenso, E.E., and Quraishi, M. (2020). Molecular structural aspects of organic corrosion inhibitors: influence of–CN and–NO2 substituents on designing of potential corrosion inhibitors for aqueous media. J. Mol. Liq. 316: 113874, https://doi.org/10.1016/j.molliq.2020.113874.Search in Google Scholar

Verma, C., Quraishi, M., and Rhee, K.Y. (2022). Electronic effect vs. molecular size effect: experimental and computational based designing of potential corrosion inhibitors. Chem. Eng. J. 430: 132645, https://doi.org/10.1016/j.cej.2021.132645.Search in Google Scholar

Wazzan, N.A. (2015). DFT calculations of thiosemicarbazide, arylisothiocynates, and 1-aryl-2, 5-dithiohydrazodicarbonamides as corrosion inhibitors of copper in an aqueous chloride solution. J. Ind. Eng. Chem. 26: 291–308, https://doi.org/10.1016/j.jiec.2014.11.043.Search in Google Scholar

Wood, M.H., Arellano, A.V., and Van Wijk, L. (2013). Corrosion related accidents in petroleum refineries. European Commission Joint Research Centre, Report no. EUR 26331. Publications Office of the European Union; 2013. JRC84661. ISBN: 978-92-79-34653-8, 978-92-79-34652-1.Search in Google Scholar

Younes, A.-K., Ghayad, I., Ömer, E.B., and Kandemirli, F. (2018). Corrosion inhibition of copper in sea water using derivatives of tetrazoles and thiosemicarbazide. Innov. Corrosion Mater. Sci. (formerly Recent Patents on Corrosion Science) 8: 60–66, https://doi.org/10.2174/2352094908666180830123952.Search in Google Scholar

Younis, A.-K., Ghayad, I.M., and Kandemirli, F. (2019). Quantum chemical study on the corrosion inhibition of copper using some thiosemicarbazides and tetrazoles. Quantum 11: 28–35.Search in Google Scholar

Zaferani, S.H., Sharifi, M., Zaarei, D., and Shishesaz, M.R. (2013). Application of eco-friendly products as corrosion inhibitors for metals in acid pickling processes – a review. J. Environ. Chem. Eng. 1: 652–657, https://doi.org/10.1016/j.jece.2013.09.019.Search in Google Scholar

Zor, S., Ozkazanc, H., Arslan, T., and Kandemirli, F. (2010). Inhibition effects of 4-phenyl-3-thiosemicarbazide on the corrosion of aluminum in 0.1 M HCl: theoretical and experimental studies. Corrosion 66: 045006–045006–7, https://doi.org/10.5006/1.3381571.Search in Google Scholar

Received: 2022-03-17
Accepted: 2022-06-10
Published Online: 2022-08-12

© 2022 Walter de Gruyter GmbH, Berlin/Boston

Downloaded on 7.2.2023 from https://www.degruyter.com/document/doi/10.1515/revce-2022-0009/html
Scroll Up Arrow