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Licensed Unlicensed Requires Authentication Published by De Gruyter May 16, 2022

Surface properties of dicationic ionic liquids and correlation with biological activity

Marta Wojcieszak, Damian Krystian Kaczmarek, Klaudia Krzyźlak, Amelia Siarkiewicz, Tomasz Klejdysz and Katarzyna Materna

Abstract

The surface activity of dicationic ionic liquids is described in this paper. The basic interfacial parameters including critical micelle concentration (CMC), surface tension at the CMC (γCMC), the adsorption efficiency (pC20), surface excess (Γmax), the minimum surface occupied by a single molecule (Amin), and Gibbs energy (ΔG0ads) were investigated and compared. Basically, we wanted to extend our previous study on dicationic ionic liquids with bis-ammonium cation. Knowing that, the compounds obtained are effective in limiting the feeding of adult and larvae confused flour beetle (T. confusum), it was decided to correlate the deterrent activity with the surface properties of analyzed dicationic ionic liquids. Accordingly, it was found that the deterrent activity of the studied compounds increases with increasing wetting ability.


Corresponding author: Ms Ph.D. student Marta Wojcieszak, Poznan University of Technology, Institute of Chemical Technology and Engineering, ul. Berdychowo 4, 60-965 Poznań, Poland, E-mail:
Parts of this work have been presented at the European Detergents Conference (EDC) 2021 in Berlin.

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: This work was funded by the Ministry of Education and Science in Poland (0912/SBAD/2108).

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Received: 2022-02-28
Accepted: 2022-04-05
Published Online: 2022-05-16
Published in Print: 2022-07-26

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