Accessible Requires Authentication Published by Oldenbourg Wissenschaftsverlag October 24, 2014

Temperature- and moisture-dependency of CsLiB6O10. A new phase, β-CsLiB6O10

Natalia A. Sennova, Gerhard Cordier, Barbara Albert, Stanislav K. Filatov, Rimma S. Bubnova, Ludmila I. Isaenko, Lyubov I. Gubenko, Jan-Peter Klöckner and Marc H. Prosenc

Abstract

The structural behavior of the non-linear optical, nanoporous compound CsLiB6O10 was studied in a wide temperature range. Both the highly anisotropic thermal expansion of the borate with temperature variation and the deterioration of its crystals were investigated. The electron density distribution was analyzed in detail. A reversible, partial transition to a new modification, β-CsLiB6O10, was observed during cooling crystalline and moist samples of CsLiB6O10 to –25 °C. The crystal structure of the new phase is described.


Corresponding author: Natalia A. Sennova, Eduard-Zintl-Institut für Anorganische und Physikalische Chemie, Technische Universität Darmstadt, Germany; and Department of Crystallography, St. Petersburg State University, Russia, E-mail:

Acknowledgments

The authors are grateful to Dr. K. Hofmann and H. Wolf (Eduard-Zintl-Institute, TU Darmstadt), Dr. M. Hinterstein (DESY, Hamburg), Dr. M. G. Fofanova.

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Supplemental Material

The online version of this article (DOI: 10.1515/zkri-2014-1758) offers supplementary material, available to authorized users.

Received: 2014-4-11
Accepted: 2014-8-29
Published Online: 2014-10-24
Published in Print: 2014-11-1

©2014 by De Gruyter