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Licensed Unlicensed Requires Authentication Published by De Gruyter (O) April 22, 2020

Synthesis and crystal structures of two layered Cu(I) and Ag(I) iodidometalates

  • Natalie Dehnhardt , Chantsalmaa Berthold , Kevin Dollberg , Frank Tambornino and Johanna Heine EMAIL logo

Abstract

Cu(I) and Ag(I) iodidometalates have been investigated for both their rich structural chemistry, as well as for useful properties like luminescence. Here, we present the synthesis and crystal structure of (BzA)[MI2] · 0.5 H2O (BzA = benzylammonium; M=Cu (1), Ag (2)). The two compounds are isostructural and show a previously unknown layered anion motif that can be described as a 44 net constructed via corner-sharing of M2I6 subunits, built from two edge-sharing MI4 tetrahedra.


Dedicated to: Prof. Ulrich Müller on the occasion of his 80th birthday.


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Supplementary Material

The online version of this article offers supplementary material (https://doi.org/10.1515/zkri-2020-0021).


Received: 2020-02-28
Accepted: 2020-04-02
Published Online: 2020-04-22
Published in Print: 2020-09-25

©2020 Walter de Gruyter GmbH, Berlin/Boston

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