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BY-NC-ND 3.0 license Open Access Published by De Gruyter June 2, 2014

and Cyclic Hydrocarbons on y-Aluminium Oxide

IV. Energy of Adsorption and Specific Interactions of Some Unsaturated and Cyclic Hydrocarbons on γ-Aluminium Oxide°

  • Manlio Sanesi and Vittoriano Wagner

The heats of adsorption on weakly activated γ-Al2O3 of a number of linear 1-monoolefins (C4 to C9) and cyclic saturated and unsaturated hydrocarbons have been measured by gas-solid chromatography and extrapolated to zero surface coverage.

The double bond contribution to the adsorption energy is shown by comparison of the adsorption heats with those of the corresponding saturated molecules and is related to the existence of Brensted acid centers on the adsorbent surface. The effect of cyclization is also shown.

Received: 1970-2-11
Published Online: 2014-6-2
Published in Print: 1970-5-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

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