The anharmonic force constants of ozone up to fourth order have been determined from recently published spectroscopic data of 16O3 and 18O3. For the first time all experimental data presently available have been used in a least squares fit. Compared with recent work, the correct formula for the Darling-Dennison resonance parameter γ has been used now. The nonuniqueness of the solution is discussed. In addition, isotopic rules for various spectroscopic parameters are derived.
Received: 1976-2-5
Published Online: 2014-6-2
Published in Print: 1976-4-1
© 1946 – 2014: Verlag der Zeitschrift für Naturforschung
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