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BY-NC-ND 3.0 license Open Access Published by De Gruyter June 2, 2014

Orientation of the Absorption and Emission Transition Moments of Methine Dyes

  • Z. Salamon , A. Skibiński and K. Celnik

Abstract

The emission anisotropics of the fluorescence of the prolate molecules 2[4(N,N-dimethyloamino)-α styrylo]benzothiazol and 2[4(N,N-dimethyloamino)α styrylojbenzoksazol in solvents of different viscosities were measured, yielding information about the rotational motion of the molecules.

The non-linear dependence of 1/r on T/η was confirmed. On the basis of a comparison of experimental and quantum chemical calculations the orientation of the transition moments of the dye molecules is proposed.

Received: 1982-4-13
Published Online: 2014-6-2
Published in Print: 1982-9-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

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