Determination of a High Potential Barrier Hindering Internal Rotation from the Ground State Spectrum The Methylbarrier of cis-Propanal

J. A. Hardy; A. P. Cox; E. Fliege; H. Dreizler

doi:10.1515/zna-1982-0910

Open Access Published by De Gruyter June 2, 2014

Determination of a High Potential Barrier Hindering Internal Rotation from the Ground State Spectrum The Methylbarrier of cis-Propanal

The Methylbarrier of cis-Propanal

J. A. Hardy , A. P. Cox , E. Fliege and H. Dreizler

From the journal Zeitschrift für Naturforschung A

https://doi.org/10.1515/zna-1982-0910

Abstract

The barrier hindering internal rotation of the methyl group was determined by analysing the splittings of rotational lines in the ground state. So model errors are minimized. The assignment was checked by double resonances and a centrifugal distortion analysis.

Received: 1982-5-21

Published Online: 2014-6-2

Published in Print: 1982-9-1

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Determination of a High Potential Barrier Hindering Internal Rotation from the Ground State Spectrum The Methylbarrier of cis-Propanal

The Methylbarrier of cis-Propanal

Abstract

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