Internal mobility ratios of the cations in the molten binary system (Na, TI)NO3 have been measured with the Klemm method. From these values and available data on the densities and electric conductivities, the internal mobilities, b, of Na+ and Tl+ ions have been calculated. The Chemla effect occurs at high xTI (xTI: mole fraction of TINO3). At low xTI, bTI sharply decreases with decreasing xTI, which may be attributed to the free space effect.
Received: 1986-12-15
Published Online: 2014-6-2
Published in Print: 1987-4-1
© 1946 – 2014: Verlag der Zeitschrift für Naturforschung
This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.