Skip to content
BY-NC-ND 3.0 license Open Access Published by De Gruyter June 2, 2014

Self-Diffusion in Compressed Dimethylether: The Influence of Dipole-Dipole Interaction and Hydrogen Bonding Upon Translational Diffusivity in Simple Fluids

  • A. Heinrich-Schramm , W. E. Price and H.-D. Lüdemann

Abstract

Self-diffusion coefficients of dimethylether have been measured as a function of temperature (185-458 K) and pressure (up to 200 MPa) by pulse-gradient field spin-echo NMR. Calculated activation volumes (ΔV*) fall from 15 (10-6 m3/mole) at the highest temperature to 7 (10-6 m3/mole) at the lowest. This trend is in keeping with values for other non-associating liquids. Comparison with self diffusion data for propane and ethanol reveals that the translational diffusivity in dimethylether is influenced by the substance's modest dipole moment (1.3 Debye). The effect is small but measur­able and becomes more pronounced at lower temperatures.

Received: 1994-10-5
Published Online: 2014-6-2
Published in Print: 1995-3-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Downloaded on 5.2.2023 from https://www.degruyter.com/document/doi/10.1515/zna-1995-2-305/html
Scroll Up Arrow