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BY-NC-ND 3.0 license Open Access Published by De Gruyter June 2, 2014

Halogenokomplexe von Osmium(III) mit Pyridin, Pyrazin, Pyrimidin und einigen Methylhomologen.

Halogeno-Complexes of Osmium(III) with Pyridine, Pyrazine, Pyrimidine and Some Methyl-Homologes

  • A. Scheffler and W. Preetz

The preparation of mer-[OsX3B3], X = Cl, Br, I; B = pyridine, 3-resp. 4-picoline, pyrimidine, pyrazine, methylpyrazine, and the chromatographic isolation of four basemixed stereoisomers mer-[OsX3(py)n(mepyz)3-n], n= 1, 2, as solid crystalline products is described. Mass spectra and ligand exchange reactions confirm the structure of these complexes. The UV and IR spectra are discussed.

Received: 1976-3-29
Revised: 1976-4-30
Published Online: 2014-6-2
Published in Print: 1976-8-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

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