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BY-NC-ND 3.0 license Open Access Published by De Gruyter June 2, 2014

Einige neue Iridium-Komplexe von Phosphor-yliden /Some New Iridium Complexes of Phosphorus Ylides

T. E. Fraser, H.-J. Fuller and H. Schmidbaur

Abstract

From the iridium complexes [(1,5-C8H12)IrCl]2, [(C8H14)2IrCl]2 and [(C6H5)3P]2lr(CO)Cl, and the ylides (CH3)3P = CH2 and (CH3)3P = N-P(CH3)2 = CH2, a number of organoiridium compounds has been synthesized. Whereas with (CH3)3P = CH2 the transylidation reaction is very slow and simple addition with formation of sparingly soluble products prevails, the double ylide forms cyclic complexes quite readily. These ylide chelates were characterized by analytical and spectroscopic data.

Received: 1979-6-18
Published Online: 2014-6-2
Published in Print: 1979-9-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

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